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排序方式: 共有981条查询结果,搜索用时 15 毫秒
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A. Swinnen I. Haeldermans M. vandeVen J. D'Haen G. Vanhoyland S. Aresu M. D'Olieslaeger J. Manca 《Advanced functional materials》2006,16(6):760-765
A new ordered structure of the C60 derivative PCBM ([6‐6]‐phenyl C61‐butyric acid methyl ester) is obtained in thin films based on the blend PCBM:regioregular P3HT (poly(3‐hexylthiophene)). Rapid formation of needlelike crystalline PCBM structures of a few micrometers up to 100 μm in size is demonstrated by submitting the blended thin films to an appropriate thermal treatment. These structures can grow out to a 2D network of PCBM needles and, in specific cases, to spectacular PCBM fans. Key parameters to tune the dimensions and spatial distribution of the PCBM needles are blend ratio and annealing conditions. The as‐obtained blended films and crystals are probed using atomic force microscopy, transmission electron microscopy, selected area electron diffraction, optical microscopy, and confocal fluorescence microscopy. Based on the analytical results, the growth mechanism of the PCBM structures within the film is described in terms of diffusion of PCBM towards the PCBM crystals, leaving highly crystalline P3HT behind in the surrounding matrix. 相似文献
4.
D.J. Bekers S.J.L. van Eijndhoven A.A.F. van de Ven 《Journal of Engineering Mathematics》2004,49(4):373-390
A long thin conducting stripline embedded in a dielectric and centered between two large conducting plates, i.e., the stripline environment, is considered. The stripline is modeled as infinitely long, infinitely thin, and perfectly conducting by first considering a stripline of finite length, thickness, and conductivity in a dielectric layer. Starting from Maxwell's equations and assuming that the current on the stripline is a propagating wave in length direction, asymptotic expressions for the fields inside and in the neighbourhood of the stripline are deduced. These expressions are used to model the stripline in the stripline environment, which leads to a boundary-value problem for the electric potential. This problem is solved by two different approaches, leading to integral equations for the current and for an auxiliary function describing the electric potential. A relation between the current and the auxiliary function is deduced, which is used to obtain asymptotic expressions for current and impedance. Results are compared with a numerical solution of the integral equation for the current and with results in literature. 相似文献
5.
P. R. J. M. Smits P. H. Van Lieshout A. A. F. Van De Ven 《Journal of Engineering Mathematics》1989,23(2):157-186
A variational principle for the magnetoelastic stability problem of superconductors is constructed. Independently, a pair of integral equations is derived, from which the initial and the perturbed field can be computed. The integral equations are solved for in-plane buckling of a slender pair of concentric tori, and out-of-plane buckling of a slender pair of equal coaxial tori. By using the variational principle, it is shown that both cases can become unstable when the currents on the two tori are equally directed, and the pertinent buckling values are calculated. The thus obtained buckling values are compared with the results of an alternative, mathematically less rigorous, method. A good correspondence between the two methods is found (at least as long as the two tori are not too near). 相似文献
6.
A variational principle for magneto-elastic buckling 总被引:1,自引:0,他引:1
P. H. Van Lieshout P. M. J. Rongen A. A. F. Van De Ven 《Journal of Engineering Mathematics》1987,21(3):227-252
A variational principle that can serve as the basis for a magneto-elastic stability (or buckling) problem is constructed. For the two cases of soft ferromagnetic media and superconductors, respectively, it is shown how the variational principle directly yields an explicit expression for the buckling value. The formulation starts from a specific choice for a magneto-elastic Lagrangian L (associated with the so-called Maxwell-Minkowski model for magneto-elastic interactions). For the evaluation of the principle the first and second variations of L are calculated both inside and outside the solid magneto-elastic body. Thus, a general buckling criterion, consisting of an expression for the critical field value, together with a set of constraints for the field variables occurring in the right-hand side of this expression, is constructed. Finally, more detailed formulations are given for, successively, soft ferromagnetic bodies and superconductors. Applications to specific structures, yielding explicit numerical values for the magneto-elastic buckling fields, will be given in a forthcoming paper. 相似文献
7.
Renato Cataluña Rosângela da Silva Eliana Weber de Menezes Ricardo Boeira Ivanov 《Fuel》2008,87(15-16):3362-3368
Oxygenated fuels increase fuel consumption due to their low enthalpy of combustion; however, their high antiknock index renders them suitable for use in engines with a high compression rate, increasing their thermal yield. This study evaluated the performance of biorenewable oxygenated fuels (ethanol and isoamyl alcohol) and partially renewable fuels (ETBE: ethyl tert-butyl ether, TAEE: tert-amyl ethyl ether and di-TAE: di-tert-amyl ether) with high degree of purity and in mixtures with automotive gasoline, based on tests with Otto cycle engines. Among the oxygenated fuels evaluated here, di-TAE was found to present the best characteristics of performance, both individually and in mixtures with gasoline. 相似文献
8.
ZrO2–
catalysts with different sulfur contents were analysed with thermal methods coupled with mass spectrometry after exposure
to mixtures of hexane, methylcyclopentane, and cyclohexane in argon. The reaction of the hydrocarbons led to carbonaceous
deposits, but an important part of hydrocarbon remained chemisorbed as well. Heating these samples in He atmosphere provoked
the decomposition of these deposits with evolution of CO2 and CO, and also of SO2 and SO. At the same time, COS was evidenced in the reaction products. The release of these molecules occurred below the activation
temperature of the catalysts. The behavior of the catalysts depended both on reactant molecule and sulfur content. The analyses
clearly evidenced the oxidation ability of ZrO2–SO
catalysts.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
9.
Pulp fibers can be spouted in water in a conical vessel. The entities which are spouted are fiber flocs rather than individual fibers. Synthetic fibers, which do not flocculate, cannot be spouted. For comparison, rigid spherical particles were spouted with water in the same conical vessel. Liquid spouting of rigid particles was similar to gaseous spouting. For pulp spouting, the minimum spouting velocity is proportional to the mass of fibers in the bed and inversely proportional to the diameter of the inlet. For rigid particles, the minimum spouting velocity is proportional to the height of the bed and inversely proportional to the square of the diameter of the inlet. A model for the minimum spouting velocity was developed for pulp spouting. 相似文献
10.
Alper Sarıoğlan Ömer Tunç Savaşçı Ayşe Erdem-Şenatalar Vu Thu Ha Gilbert Sapaly Younès Ben Taârit 《Catalysis Letters》2007,118(1-2):123-128
MFI type inorganic carrier was used in two different cationic forms, hydrogen and calcium respectively. MFI-supported molybdenum
and rhenium catalysts were prepared. The activities of the catalysts were compared for the aromatization reaction of methane.
Higher activity values were attained with the catalysts supported on HZSM-5. Aromatics were also observed with the catalysts
supported on CaZSM-5, despite their deficiency in acid sites. Highly dispersed rhenium is expected to be formed with the use
of the inorganic carrier in calcium form. On the other hand, lower reaction rates were observed with rhenium supported on
CaZSM-5, in spite of the improved dispersion of the active rhenium species on this catalyst. This was interpreted in terms
of the critical role of the acid sites in the conversion of methane to aromatics, compared to the improved dispersion of the
active metal. 相似文献