Methane to higher hydrocarbons via halogenation

Activation of methane with a halogen followed by the metathesis of methyl halide is a novel route from methane to higher hydrocarbons or oxygenates. Thermodynamic analysis revealed that bromine is the most suitable halogen for this goal. Analysis of the published data on the reaction kinetics in a CSTR enabled us to judge on the effects of temperature, reactor residence time and the feed concentrations of bromine and methane to the conversion of methane and the selectivity towards mono or dibromomethane. The analysis indicated that high dibromomethane selectivity is attainable (over 90%) accompanied by high methane conversions. The metathesis of dibromomethane can provide an alternative route to the conversion of methane (natural gas) economically with smaller installations than the current syn-gas route.     

Unusual swelling behavior of polymer-clay nanocomposite hydrogels

The swelling behavior and the elastic properties of nanocomposite hydrogels have been investigated. The hydrogels were prepared by free-radical polymerization of the monomers acrylamide (AAm), N,N-dimethylacrylamide (DMA), and N-isopropylacrylamide (NIPA) in aqueous clay suspensions at 21 °C. Laponite with a radius of gyration in distilled water of 20 nm was used as clay particles in the hydrogel preparation. The reactions with AAm monomer were carried out in the presence of the chemical crosslinker N,N′-methylenebis(acrylamide) (BAAm). It was found that the volume of nanocomposite hydrogels immersed in water rapidly increases and attains a maximum value after about one day. Surprisingly, further increase in the swelling time results in the deswelling of the gels until they reach a limiting swelling ratio after about 5 days. This unusual swelling behavior is observable only when the clay concentration in the hydrogel is above the overlap threshold c^∗. Swelling measurements combined with the elasticity tests show that the effective crosslink density first decreases, but then increases with increasing time of swelling of the hydrogels. The results were explained in terms of the rearrangements of the highly entangled polymer chains and clay particles during the gel volume change.     

Graphene oxide-containing isocyanate-based polyimide foams: Enhanced thermal stability and flame retardancy

Isocyanate-based graphene oxide-containing polyimide foams were synthesized by a semi-prepolymer method. In this method, while the first solution containing pre-polymer was derived from pyromellitic dianhydride and excess polymethylene polyphenylene isocyanate (PM200), the second solution contains dianhydride derivatives, water, catalysts, surfactants, and graphene oxide. PIFs were prepared with 0%, 0.25%, 0.50%, 0.75%, and 1% graphene oxide by weight, respectively. PIFs exhibited a minimum side reaction and urea generation was not seen for all PIFs instead of imide bonding. The addition of graphene oxide (GO) leads to a more close-packed structure. Therefore, crosslinking density and thermal stability of graphene oxide-containing polyimide foams increased. Upon the addition of 1% GO, almost seven times higher compression strength was obtained compared to neat PIFs. Also, LOI values supported the theory that thermally stable and flame retardant PIFs can be synthesized via the isocyanate-based process with GO.     

Estimating crown diameters in urban forests with Unmanned Aerial System-based photogrammetric point clouds

Field measurements are the main source of information when determining stand parameters, which are essential to produce an effective forest management plan. However, conducting terrestrial measurements is neither time- nor cost-efficient in most cases. In recent years, the advent of sophisticated remote sensing technologies has enabled the extraction of accurate and robust information about the physical characteristics of trees. Crown diameter is one of the most important stand parameters that should be measured or estimated. This study proposes a Polynomial Fitting Based (PFB) methodology to estimate crown diameters of urban trees with Unmanned Aerial System (UAS)-based data. Crown diameters estimated with the PFB methodology were compared not only to a reference data but also to those estimated based on five widely used image segmentation algorithms, which were the Mean Shift Segmentation (MSS), Morphological Profiles Based Segmentation (MPBS), Multiresolution Segmentation (MRS), Seeded Region Growing Segmentation (SRGS) and Watershed Segmentation (WS). Quantitative investigations revealed that the PFB approach outperformed the other segmentation-based approaches. The PFB approach estimated the crown diameters with root-mean-square errors (RMSE) ranging from 0.69 m to 0.92 m. The PFB methodology was found to be a practical and robust approach for the estimation of crown diameters, which plays a very significant role in effective forest management.     

Design and analysis of an aging‐aware energy management system for islanded grids using mixed‐integer quadratic programming

The rapid increase of renewable energy sources made coordinated control of the distributed and intermittent generation units a more demanded task. Matching demand and supply is particularly challenging in islanded microgrids. In this study, we have demonstrated a mixed‐integer quadratic programming (MIQP) method to achieve efficient use of sources within an islanded microgrid. A unique objective function involving fuel consumption of diesel generator, degradation in a lithium‐ion battery energy storage system, carbon emissions, load shifting, and curtailment of the renewable sources is constructed, and an optimal operating point is pursued using the MIQP approach. A systematic and extensive methodology for building the objective function is given in a sequential and explicit manner with an emphasis on a novel model‐based battery aging formulation. Performance of the designed system and a sensitivity analysis of resulting battery dispatch, diesel generator usage, and storage aging against a range of optimization parameters are presented by considering real‐world specifications of the Semakau Island, an island in the vicinity of Singapore.     

A study on performance of solid oxide fuel cell‐organic Rankine cycle combined system

This study presents an energetic performance analysis for a combined power generation system consisting of a solid oxide fuel cell (SOFC) and an organic Rankine cycle (ORC). In order to simulate the SOFC–ORC combined system under steady‐state conditions, a mathematical model is developed. The developed model is used to determine the potential effects caused by the changes of the design parameters on the energetic performance of the combined system. As design parameters, turbine inlet pressure, condenser temperature, fuel utilization, current density, compressor pressure ratio, and cell operating temperature are taken into account. In this regard, the electrical power and First Law efficiency are estimated by parametrical analysis and discussed comprehensively. Results of these analyses show that the efficiency is increased about 14–25% by recovering SOFC waste heat through ORC based on investigated design parameter conditions. Copyright © 2008 John Wiley & Sons, Ltd.