The mechanism of thermal decomposition of rare earth acetate hydrates(Ln(Ac)_3·nH_2O,n=5,forLn=La;n=4,for Ln=Pr→Lu,Y,except Pm)has been studied by TG-DTG,DSC,infrared spectra,X-raydiffraction and chemical analysis.The thermal decomposition reaction consists of two stages,one is dehydrationand the other one is decompostion.The final product is oxide.It has been found that the temperature of pro-ducing anhydrous acetates decreases with increasing atomic number of rare earth elements.The activation ener-gies for dehydration and decomposition reaction of rare earth acetate hydrates have been calculated byFreeman-Carroll and Kissinger method.The dependence of activation energy Jor dehydration reaction on theatomic number of rare earth elements shows“inclined‘W’effect”.The enthalpy changes for dehydration anddecomposition reaction have been determined. 相似文献
Multicasting applications such as multimedia conferencing, online multiplayer interactive games, and distance learning are becoming increasingly popular. With multiprotocol label switching, Internet protocol networks can offer quality of service and traffic engineering capabilities. This article introduces several approaches for multisource multicast sessions in the context of IP over WDM networks and evaluates their performance in terms of blocking probability, time complexity, and memory consumption. Our simulation study shows that among all the approaches, the newly proposed approach, known as one Bidirectional Tree with Just enough bandwidth reserved on each link of the tree, achieves the best overall performance. 相似文献
We consider a new heuristic method for design of survivable wavelength-division multiplexing (WDM) networks with preconfigured protection cycles (p-cycles). Numerical studies show that the new heuristic works well for different traffic patterns, and the spare capacity obtained by the new heuristic is very close to that of the optimal solution but with much reduced computational time. 相似文献
We demonstrate a photonic monocycle pulse frequency up-conversion scheme for ultrawideband (UWB)-over-fiber applications using nonlinear polarization rotation arising in a semiconductor optical amplifier. For the first time, we have successfully realized the photonic up-conversion of UWB monocycle pulses with an optical local oscillator signal at 24 GHz in the whole -band. The up-converted UWB monocycle pulse at 24 GHz exhibits a power spectrum density fitting the UWB emission mask. After electrical down-conversion, the UWB monocycle pulse has shown low distortion induced by the optical mixing process. 相似文献
CO2 hydrogenation to CH3OH via heterogeneous catalysis is one of the most promising and available approaches for mitigation of anthropogenic CO2 issues. In this work, thermodynamic equilibria of CO2 to methanol were compared with experimental results at given conditions using a commercial Cu/ZnO/Al2O3 catalyst for CO hydrogenation to methanol. It was found that, the high pressure, low temperature, and high H2/CO2 ratio are favorable to methanol synthesis from CO2. Furthermore, the kinetic data were measured with an isothermal integral reactor under temperature between 160 and 240 °C, lower than that for CO hydrogenation to methanol reaction. Based on the single-active site and dual-active site LH mechanisms, both kinetic models can achieve full illustration of the influence of the operating conditions and the mechanisms. According to comparative analysis of the error variances of model correlations and the adsorbate coverages on the active sites, the dual-site mechanism identified to be superior to the single-site one for methanol synthesis from CO2 feedstock. Overall, this paper provides fundamental understanding of the thermodynamic and kinetic aspects of a central route for CO2 Valorisation.
We demonstrate, for the first time to the best of our knowledge, a multiwavelength fiber ring laser using a continuous-wave dual-pump fiber optical parametric amplifier (FOPA) as gain medium. In the ring cavity, two high-power pumps are injected into a spool of 1-km highly nonlinear dispersion-shifted fiber to generate the parametric gain, and a superimposed chirped fiber Bragg grating is used as the comb-like filter. Benefiting from the high and flat gain of the dual-pump FOPA, seven lasing lines around 1.55 mum with wavelength spacing of 1 nm have been obtained. Each lasing line has a linewidth of as narrow as 20 pm and an extinction ratio of > 30 dB. The proposed mechanism using a dual-pump FOPA as gain medium is a promising alternative for generating multiwavelength laser. 相似文献