Propane oxydehydrogenation reaction on a VPO/TiO2 catalyst. Role of the nature of acid sites determined by dynamic in-situ IR studies

A VPO/TiO₂ catalyst tested in the oxydehydrogenation reaction (ODH) of propane between 300 and 400°C shows satisfactory performances (up to 80% of propene selectivity at 2% of propane conversion at 300°C or 56% of propene selectivity at 9% of propane conversion at 400°C). Addition of water or pyridine in the feed gas tends to decrease the propane conversion and enhances the propene selectivity. It is shown that water increases the number of Brönsted surface acid sites by dissociative adsorption which, in turn, enhances propene selectivity at the expense of the CO_x selectivity. These results are in good agreement with spectroscopic IR observations performed under catalytic conditions showing that the Lewis acid sites are linked to CO_xformation, whereas it seems that Brönsted sites would rather be linked to propene formation.     

Toward the Interactive 3D Modelling Applied to Ponte Rotto in Rome

We present the first step of a research aimed at automating a driven interactive 3D modeling of an existing architectural object. The method is based on oriented multi-image spherical panoramas produced by stitching techniques. The photogrammetric process has two steps: the creation of a semi-automatic process to find homolog points in two panoramas; the creation of parametric definitions for an interactive modeling creating points, segments, and surfaces based on the plotted points in the first step. By connecting these two steps, the creation of the model will be automatic, as we indicate the necessary points in just one panoramic photo. The principals of multi-view geometry and epipolar geometry were applied to simplify the calculation in the first step in order to create an automatic identification of the correspondent points in the other panorama. The epipolar geometry is described by both analytical and graphical programming, implementing in the first case a C++ application and in the second case a Rhinoceros and Grasshopper application. A case study of the Ponte Rotto in Rome (Italy) is presented.     

A systematic approach to integrate common timed security rules within a TEFSM-based system specification

Context

Formal methods are very useful in the software industry and are becoming of paramount importance in practical engineering techniques. They involve the design and modeling of various system aspects expressed usually through different paradigms. These different formalisms make the verification of global developed systems more difficult.

Objective

In this paper, we propose to combine two modeling formalisms, in order to express both functional and security timed requirements of a system to obtain all the requirements expressed in a unique formalism.

Method

First, the system behavior is specified according to its functional requirements using Timed Extended Finite State Machine (TEFSM) formalism. Second, this model is augmented by applying a set of dedicated algorithms to integrate timed security requirements specified in Nomad language. This language is adapted to express security properties such as permissions, prohibitions and obligations with time considerations.

Results

The proposed algorithms produce a global TEFSM specification of the system that includes both its functional and security timed requirements.

Conclusion

It is concluded that it is possible to merge several requirement aspects described with different formalisms into a global specification that can be used for several purposes such as code generation, specification correctness proof, model checking or automatic test generation. In this paper, we applied our approach to a France Telecom Travel service to demonstrate its scalability and feasibility.     

Role of the nature of the acid sites in the oxydehydrogenation of propane on a VPO/TiO2 catalyst. An in situ FT-IR spectroscopy investigation

Catalytic activity and surface acidity during the oxydehydrogenation of propane over a VPO/TiO₂ catalyst were determined by a dynamic in situ FT-IR spectroscopy technique at 350°C. Pyridine was used as a probe molecule for the acidity measurements. The obtained results show that propene formation is linked to Brønsted acid sites and that water increases the number of these sites which, in turn, increases propene selectivity.     

ILB®, a Low Molecular Weight Dextran Sulphate,Restores Glutamate Homeostasis,Amino Acid Metabolism and Neurocognitive Functions in a Rat Model of Severe Traumatic Brain Injury

In a previous study, we found that administration of ILB^®, a new low molecular weight dextran sulphate, significantly improved mitochondrial functions and energy metabolism, as well as decreased oxidative/nitrosative stress, of brain tissue of rats exposed to severe traumatic brain injury (sTBI), induced by the closed-head weight-drop model of diffused TBI. Using aliquots of deproteinized brain tissue of the same animals of this former study, we here determined the concentrations of 24 amino acids of control rats, untreated sTBI rats (sacrificed at 2 and 7 days post-injury) and sTBI rats receiving a subcutaneous ILB^® administration (at the dose levels of 1, 5 and 15 mg/kg b.w.) 30 min post-impact (sacrificed at 2 and 7 days post-injury). Additionally, in a different set of experiments, new groups of control rats, untreated sTBI rats and ILB^®-treated rats (administered 30 min after sTBI at the dose levels of 1 or 5 mg/kg b.w.) were studied for their neurocognitive functions (anxiety, locomotor capacities, short- and long-term memory) at 7 days after the induction of sTBI. Compared to untreated sTBI animals, ILB^® significantly decreased whole brain glutamate (normalizing the glutamate/glutamine ratio), glycine, serine and γ-aminobutyric acid. Furthermore, ILB^® administration restored arginine metabolism (preventing nitrosative stress), levels of amino acids involved in methylation reactions (methionine, L-cystathionine, S-adenosylhomocysteine), and N-acetylaspartate homeostasis. The macroscopic evidences of the beneficial effects on brain metabolism induced by ILB^® were the relevant improvement in neurocognitive functions of the group of animals treated with ILB^® 5 mg/kg b.w., compared to the marked cognitive decline measured in untreated sTBI animals. These results demonstrate that ILB^® administration 30 min after sTBI prevents glutamate excitotoxicity and normalizes levels of amino acids involved in crucial brain metabolic functions. The ameliorations of amino acid metabolism, mitochondrial functions and energy metabolism in ILB^®-treated rats exposed to sTBI produced significant improvement in neurocognitive functions, reinforcing the concept that ILB^® is a new effective therapeutic tool for the treatment of sTBI, worth being tested in the clinical setting.     

Measuring research performance of Iraqi universities using Scopus data

Scientometrics - This study investigates the research performance of the Iraqi public and private universities using the Scopus citation database. The investigation consists of three stages. The...     

The Effect of Spray-Freeze Drying of Montmorillonite on the Morphology,Dispersion, and Crystallization in Polypropylene Nanocomposites

The spray-freeze drying (SFD) technique was applied to sonicated aqueous suspensions of spray-dried montmorillonite clay (MMT) to produce highly porous agglomerates (SFD-MMT). Both MMT (used as a reference) and SFD-MMT were subsequently incorporated in polypropylene (PP) via melt compounding to produce 2 wt % nanocomposites with and without maleic anhydride grafted polypropylene (PP-g-MA). Polypropylene nanocomposites containing SFD-MMT exhibited thinner silicate flake layers compared to large agglomerates in PP/MMT nanocomposites. SFD-MMT particles became even more finer in the presence of PP-g-MA (i.e., in PP/PP-g-MA /SFD-MMT) where it hindered PP crystallization instead of serving as nucleation sites for the PP crystallization during rapid cooling. SFD-MMT improved the thermal stability of PP/PP-g-MA by 30°C compared to only 5–8°C for MMT/nanocomposites. MMT acts as a heterogeneous nucleating agent in the nucleation-controlled PP nanocomposites, but the hindrance effect was observed for the PP/PP-g-MA with SFD-MMT. PP/PP-g-MA/SFD-MMT exhibited twice the edge surface energy as compared to PP/PP-g-MA/MMT. The incorporation of both types of MMT raised the tensile moduli of PP and PP/PP-g-MA, with no improvement in their tensile strength and a decrease in the elongation at break. The PP/PP-g-MA/SFD-MMT showed brittle failure. POLYM. ENG. SCI., 60:168–179, 2020. © 2019 Society of Plastics Engineers     

Colloidal nanometric particles of nickel deposited on γ-alumina: characteristics and catalytic properties

The present paper deals with supported nanoparticles of metallic nickel prepared by impregnation of an organometallic colloidal precursor (NiRC complex) on -alumina. The obtained supported materials (NiRCS complex) were characterized by STEM, EELS, XRD and TGA and tested in the hydrogenation reaction of benzene and styrene both in the gas and liquid phases. EELS and STEM studies showed that the metallic nickel nanoparticles of the NiRC precursor were well dispersed (1–3 nm) on the support, without size variation during the impregnation step. However, particle growth in NiRCS was observed in samples used after reaction tests. On the other hand, TGA experiments showed that the nickel phase was inserted in an organic matrix which remained in the supported material after impregnation. This organic matrix should be partly removed or totally decomposed by washing with an appropriate solvent or thermal treatment above about 250°C under N₂, H₂ or air atmosphere respectively. The supported nickel particles were active in the gas phase hydrogenation of benzene in the temperature range of 150–200°C and their activity was enhanced by partial removal of the organic matrix with an organic solvent (e.g. ethanol) or by its total thermal decomposition. They were also found very active in the gas phase hydrogenation of styrene at room temperature. Finally, the supported nickel particles exhibited good hydrogen reservoir properties in organic solvent media.     

Mémoire et émotion dans le trouble de stress post-traumatique (TSPT).

In Posttraumatic Stress Disorder (PTSD), the hypermnesis linked to the trauma produces various emotional disturbances that result in a state of increased hypersensitivity towards environmental stimuli. Accordingly, memory and emotional functions play a predominant role in the PTSD symptomatology. Through a distinctive approach to the cognitive psychopathology research, the goal of this review is to define the nature of the links between the memory and emotional processes in PTSD. The research conducted in this area, whether on explicit or implicit memory, reveals a memory bias in information specific to the trauma. In determining the workings of the cognitive mechanisms responsible for this traumatic information bias, we hope that this will provide a basis for progress to be made in the understanding of the cognitive mechanisms responsible for the repetitive mnemic symptoms of PTSD. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Antimicrobial materials based on poly(ethylene-co-vinyl alcohol) and silver acetate produced by reactive extrusion

The use of silver as an antimicrobial agent has exhibited great interest in recent years. In this research, poly(ethylene-co-vinyl alcohol) (EVOH)–silver acetate-based antimicrobial materials were prepared at high temperature by reactive extrusion. Silver acetates were used without pretreatment. The thermal reaction of silver acetates in the material and their effect on the thermal and mechanical properties of the polymer were investigated as a function of their concentration. The dispersed silver acetate salts within the EVOH matrix have displayed a significant thermal reaction. This reaction of metallic salts was partial when the extrusion temperature was fixed at 190 °C and completed at 230 °C. The antimicrobial agents also had significant effects on the properties of the matrix. Reductions of glass temperature and storage modulus were observed by the analyses. All the variations were dependent on both the concentration of silver acetate and the extrusion parameters. The antimicrobial activity was studied and demonstrated a promising potential to create an antimicrobial material in a one-step solvent free extrusion method. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47799.