Superconducting properties of Pb/Ag multilayers

The electrical resistivity, ac susceptibility, critical current density, and Josephson tunneling of Pb/Ag multilayers have been measured in wide temperature ranges in order to study the proximity effect. A resistivity drop was found to occur atT _c of Pb in versusT measurement and, at low temperature, the multilayers show proximity effect. The I-V characteristic of the multilayer shows voltage steps, indicating a resistive state has occurred in the sample. The superconducting properties of the multilayer were analyzed with the bilayer theory of the proximity effect.     

Synthesis,characterization, and application of PVP/chitosan blended polymers

The purpose of this study was to research the compatibility and application of polyvinylpyrrolidone (PVP)/chitosan blended polymers. The polymers were synthesized at different weight ratios and tested using techniques such as Fourier transform infrared spectroscopy, differential scanning calorimetry, and thermogravimetric analysis to evaluate the compatibility of the blended materials. Incompatibility occurred when the quantity of chitosan exceeded 75%. The addition of PVP was beneficial for the thermal stability of chitosan, but resulted in inferior strength performance. Furthermore, the blended polymers did not show a color‐enhancement effect, but did show elevated water absorption, chlorine resistance, and colorfastness. In addition, the treated fabrics with a higher chitosan ratio in the blended polymer had antimicrobial properties. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 885–891, 2006     

Development of an integrated look-ahead dynamics-based NURBS interpolator for high precision machinery

Methodologies for planning motion trajectory of parametric interpolation such as non-uniform rational B-spline (NURBS) curves have been proposed in the past. However, most of the algorithms were developed based on the constraints of feedrate, acceleration/deceleration (acc/dec), jerk, and chord errors. The errors caused by servo dynamics were rarely included in the design process. This paper proposes an integrated look-ahead dynamics-based (ILD) algorithm which considers geometric and servo errors simultaneously. The ILD consists of three different modules: a sharp corner detection module, a jerk-limited module, and a dynamics module. The sharp corner detection module identifies sharp corners of a curve and then divides the curve into small segments. The jerk-limited module plans the feedrate profile of each segment according to the constraints of feedrate, acc/dec, jerk, and chord errors. To ensure that the contour errors are bounded within the specified value, the dynamics module further modifies the feedrate profile based on the derived contour error equation. Simulations and experiments are performed to validate the ILD algorithm. It is shown that the ILD approach improves tracking and contour accuracies significantly compared to adaptive-feedrate and curvature-feedrate algorithms.     

Measurement of static and dynamic mechanical behavior of micro and nano-scale thin metal films: using micro-cantilever beam deflection

We present the results of a novel micro-beam deflection test used to investigate the static and dynamic mechanical behavior of submicron-thick metal films. The method demonstrated in this study allows researchers to observe the motion of micro and nano-scale thin films responding to electrostatic loads, by means of laser reflection measurements at frequency rates of up to 500 Hz. Researchers fabricated a supporting frame and a novel triangular shaped “paddle” beam designed to provide uniform plane stress distribution while undergoing deflection. A simple geometric calculation, based on cantilever deflection, enabled the degree of strain to be determined, which in turn provided the Young’s modus for aluminum film of a given thickness. We also studied the dynamic behavior using the dynamic frequency response of the beam, generated by electrostatic forces under various loads and vacuum pressure conditions. Our results showed that air damping has a significant influence on the free damping behavior of specimens, and only a minor influence on damping frequency. We determined the loss angle and frequency using sweep frequency and free damping methods, which were very consistent with paddle resonant frequencies. The loss angle obtained from a simple silicon micro-beam was 2.001 × 10^−4°using the free damping method and 2.23 × 10^−4°using the sweep frequency method. The dynamic response loss mechanism measured in this experiment provides incentive for the further study of grain boundary motion and dislocation motion in thin films.     

A Statistical Control Chart for Stationary Process Data

In the statistical process control environment, a primary method to deal with autocorrelated data is the use of a residual chart. Although this methodology has the advantage that it can be applied to any autocorrelated data, it needs some modeling effort in practice. In addition, the detection capability of the residual chart is not always great. This article proposes a statistical control chart for stationary process data. It is simple to implement, and no modeling effort is required. Comparisons are made among the proposed chart, the residual chart, and other charts. When the process autocorrelation is not very strong and the mean changes are not large, the new chart performs better than the residual chart and the other charts.     

Monitoring Process Variability for Stationary Process Data

Processes that arise naturally, for example, from manufacturing or the environment, often exhibit complicated autocorrelation structures. When monitoring such a process for changes in variance, accounting for that structure is critical. While charts for monitoring the variance of processes of independent observations and some specific autocorrelated processes have been proposed in the past, the chart presented in this article can handle a general stationary process. The performance of the proposed chart was examined through simulations for the first‐order autoregressive and first‐order autoregressive‐moving average processes and demonstrated with examples. Copyright © 2014 John Wiley & Sons, Ltd.     

Unusual exfoliation of layered silicate clays by non-aqueous amine diffusion mechanism

The organic ionic exchange intercalation of smectite clays is conventionally performed in water swelling conditions. Here we report a different mechanism for modifying the smectite clays in alcohol solvents. The modification of sodium montmorillonite with poly(oxyethylene-oxypropylene)-amines (POA-amine) were compared for the differences between in water and in alcohol. In water, the intercalation of hydrophobic poly(oxypropylene)-rich amines in the silicate galleries expands the interlayer spacing up to 10 nm and even to exfoliation (featureless in X-ray diffraction pattern) with over 5 amine equivalents, where as hydrophilic poly(oxyethylene)-rich amines could only intercalate in a low spacing of 1.8 nm. On the other hand, all of the POA-amines in isopropanol afford the exfoliation with over, 3 amine equivalents. The mechanism of this unexpected exfoliation is explained by the thermodynamic formations of an imaginary membrane surrounding the clay units, followed by amine diffusion from the solvent into the clay galleries.     

Transcriptomic Analysis Suggests Auxin Regulation in Dorsal-Ventral Petal Asymmetry of Wild Progenitor Sinningia speciosa

The establishment of dorsal–ventral (DV) petal asymmetry is accompanied by differential growth of DV petal size, shape, and color differences, which enhance ornamental values. Genes involved in flower symmetry in Sinningia speciosa have been identified as CYCLOIDEA (SsCYC), but which gene regulatory network (GRN) is associated with SsCYC to establish DV petal asymmetry is still unknown. To uncover the GRN of DV petal asymmetry, we identified 630 DV differentially expressed genes (DV-DEGs) from the RNA-Seq of dorsal and ventral petals in the wild progenitor, S. speciosa ‘ES’. Validated by qRT-PCR, genes in the auxin signaling transduction pathway, SsCYC, and a major regulator of anthocyanin biosynthesis were upregulated in dorsal petals. These genes correlated with a higher endogenous auxin level in dorsal petals, with longer tube length growth through cell expansion and a purple dorsal color. Over-expression of SsCYC in Nicotiana reduced petal size by regulating cell growth, suggesting that SsCYC also controls cell expansion. This suggests that auxin and SsCYC both regulate DV petal asymmetry. Transiently over-expressed SsCYC, however, could not activate most major auxin signaling genes, suggesting that SsCYC may not trigger auxin regulation. Whether auxin can activate SsCYC or whether they act independently to regulate DV petal asymmetry remains to be explored in the future.