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As a solid state joining process, ultrasonic spot welding has been proven to be a promising technique for joining copper alloys. However, challenges still remain in employing ultrasonic spot welding to join copper alloys. This article comprehensively reviews the current state of ultrasonic spot welding of copper alloys with a number of critical issues including materials flow, plastic deformation, temperature distribution, vibration, relative motion, vertical displacement, interface friction coefficient, online monitoring technique, coupled with the macrostructure and microstructure, the mechanical properties and electrical conductivity. In addition, the future trends in this field are provided. 相似文献
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以从自然腐败的樱桃上分离的链格孢霉(Alternaria sp.)LD3.0086为指示菌,研究苯乳酸对链格孢霉的主要抑制作用靶位。应用分光光度法测定苯乳酸对链格孢霉的最小抑菌浓度,通过卡尔科弗卢尔荧光增白剂染液(calcofluor white,CFW)染色观察苯乳酸对菌丝顶端生长的破坏作用,利用扫描电子显微镜和透射电子显微镜观察链格孢霉的超微结构变化,通过测定苯乳酸作用前后链格孢霉上清液中N-乙酰葡萄糖胺质量浓度变化研究苯乳酸对菌丝细胞壁的破坏作用,应用荧光双染色法观察苯乳酸对链格孢霉菌丝细胞膜的损伤作用。结果表明,12.5 mmol/L的苯乳酸能有效抑制链格孢霉的生长;与对照组(无菌水处理)相比,苯乳酸处理后链格孢霉顶端生长细胞无明显形变,经12.5 mmol/L苯乳酸处理的链格孢霉上清液中N-乙酰葡萄糖胺质量浓度基本不变;苯乳酸处理24 h,链格孢霉菌丝细胞壁表面无明显损伤,细胞内结构发生明显变化;苯乳酸短时间(4 h)处理链格孢霉,菌丝细胞膜仍较为完整,加入苯乳酸较长时间(8 h)后细胞膜发生破裂。综合分析可知,苯乳酸对链格孢霉的主要作用靶位应不是菌丝体的细胞壁和细胞膜,而是在菌丝体内部,通过破坏菌丝内部细胞器结构或引起细胞内的生化反应,从而抑制链格孢霉的生长和繁殖,发挥抑菌活性。 相似文献
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Qinhua Wang Xiaofeng Pan Xinpin Wang Shilin Cao Lihui Chen Xiaojuan Ma Liulian Huang Yonghao Ni 《Ceramics International》2021,47(4):4398-4403
Ti3C2Tx (MXene), a new kind of 2D ceramic nanosheets, is receiving more and more attention in the fields of medicine, biology, energy, electronics, etc. However, the preparation and application of MXene in hydrogel is still in its infancy period. Here, we review the latest progress (after 2018) related to MXene hydrogels in time. Aiming at the key issue of the dispersion stability of MXene in hydrogel systems, the preparation strategy, mechanism, advantages and disadvantages of MXene hydrogels are sorted out in detail, and the potential application prospects of MXene composite hydrogel are introduced. Finally, future viewpoints are put forward for the dispersion stability challenges that need solving in the design of MXene hydrogel. 相似文献
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Biyun Fang Chuanfeng Zhang Zeliang Qi Chunyan Li Jun Ni Xiuyun Wang Jianxin Lin Chak-Tong Au Bingyu Lin Lilong Jiang 《American Institute of Chemical Engineers》2022,68(11):e17849
The design of an efficient non-noble metal catalyst is of burgeoning interest for ammonia synthesis. Herein, we report a Mo2C/CeO2 catalyst that is superior in ammonia synthesis activity. In this catalyst, molybdenum carbide coexisted with the ceria overlayers which is from the ceria support as the strong metal–support interaction. There is a high proportion of low-valent Mo species, as well as high concentration of Ce3+ and surface oxygen species. The presence of Mo2C and CeO2 overlayers not only leads to enhancement of hydrogen and nitrogen adsorption, but also facilitates the desorption and exchange of adsorbed species with the gaseous reagents. Compared with the Mo/CeO2 catalyst prepared without carbonization, the Mo2C/CeO2 catalyst is more than sevenfold higher in ammonia synthesis rate. This work not only presents an explicit example of designing Mo-based catalyst that is highly efficient for ammonia synthesis by tuning the adsorption and desorption properties of the reactant gases, but opens a perspective for other elements in ammonia synthesis. 相似文献
7.
Zhang Huawei Yang Zhi Wu Zhaoyu Hong Xiaoyu Li Zhong Xu Yulai Li Jun Ni Gaojin Xiao Xueshan 《Oxidation of Metals》2019,92(1-2):49-65
Oxidation of Metals - The isothermal oxidation behavior and oxide-scale evolution on a newly developed Ni–Fe-based superalloy were investigated. Three oxidation stages were generally... 相似文献
8.
Jialin Sun Jun Zhao Xiuying Ni Feng Gong Zuoli Li 《Journal of the European Ceramic Society》2018,38(9):3096-3103
This work investigates the critical roles of two-step sintering (TSS) and laminated structure on the sintering behavior and mechanical properties of functionally graded WC-TiC-Al2O3 nanostructured composite materials doped with Cr3C2/VC. Results show that excellent mechanical properties are achieved for tailored TSS conditions with a hardness of 27.91?±?2.3?GPa and a flexural strength of 1423.3?±?23.5?MPa. The desirable mechanical properties are attributed to the suppressed grain growth without densification deterioration. TSS is more effective in facilitating the favorable dispersion of secondary phase toughening nano-particulates in a WC matrix than conventional sintering (CS). Cr3C2/VC dopant plays an important role in maximizing and shifting the temperature range of the kinetic window for WC-Al2O3 composites. Al2O3 crack deflection, transgranular Al2O3, microcracking, WC crack bridging and plate-like WC crack deflection are the major toughening mechanisms. Residual surface compressive stress induced by the graded structure is also an appreciated contribution to the improvement of mechanical properties. 相似文献
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