Biocomposites Made from Short Abaca Fiber and Biodegradable Polyesters

Natural fiber‐reinforced biodegradable polyester composites were prepared from biodegradable polyesters and surface‐untreated or ‐treated abaca fibers (length ca. 5 mm) by melt mixing and subsequent injection molding. Poly(butylene succinate)(PBS), polyestercarbonate (PEC)/poly(lactic acid)(PLA) blend, and PLA were used as biodegradable polyesters. Esterifications using acetic anhydride and butyric anhydride, alkali treatment, and cyanoethylation were performed as surface treatments on the fiber. The flexural moduli of all the fiber‐reinforced composites increased with fiber content. The effect of the surface treatment on the flexural modulus of the fiber‐reinforced composites was not so pronounced. The flexural strength of PBS composites increased with fiber content, and esterification of the fiber by butyric anhydride gave the best result. For the PEC/PLA composites, flexural strength increased slightly with increased fiber content (0–20 wt.‐%) in the case of using untreated fiber, while it increased considerably in the case of using the fiber esterified by butyric anhydride. For the PLA composite, flexural strength did not increase with the fiber reinforcement. The result of soil‐burial tests showed that the composites using untreated fiber have a higher weight loss than both the neat resin and the composites made using acetylated fiber.

Flexural modulus of PBS composites as a function of fiber content.     

Enhanced Light Storage of SrAl2O4 Glass‐Ceramics Controlled by Selective Europium Reduction

A luminescent Eu, Dy: SrAl₂O₄ glass‐ceramics with high transparency in the visible region was successfully synthesized using the frozen sorbet technique with the control of O₂ partial pressure () for the oxidation of Eu²⁺ ions. The glass‐ceramics include Eu²⁺, Eu³⁺, and Dy³⁺ ions, and thus exhibits three characteristic types of emission bands, 4f–5d at around 520 nm (Eu²⁺ ions), 4f–4f at 610 nm (Eu³⁺ ions), and 480 nm (Dy³⁺ ions). The Eu, Dy: SrAl₂O₄ glass‐ceramics provide remarkable long‐persistent luminescence under dark condition. The glass‐ceramics also exhibits color‐changing luminescence in the visible region based on their remarkable light storage properties. The luminescent Eu, Dy: SrAl₂O₄ glass‐ceramics using the frozen sorbet technique with control of are promising materials for application in novel photonic and light storage materials.     

Resonance phenomena of a single water droplet located on a hydrophobic sheet under AC electric field

Resonance vibration of a water droplet located on the surface of a hydrophobic sheet under an AC electric field was investigated experimentally. In order to confirm the effect of the surface property of hydrophobic materials on the resonance phenomena of a water droplet, three kinds of hydrophobic materials, silicone rubber (SR), polytetrafluoroethylene (PTFE), and polydimethylsiloxane-grafted fluoropolymer (PGF) sheet were used. A single water droplet with a volume ranging from 3 to 30 /spl mu/L was placed between parallel electrodes, where a tangential electric field was formed along the surface of the hydrophobic sheet. A water droplet under the AC field vibrates strongly only at a particular frequency range. The resonance frequency, when the water droplet vibrates, decreases with increasing the volume of the water droplet. The resonance frequency on the SR sheet is lower than that on the PTFE and the PGF sheet. The resonance frequency and the magnitude of the deformation of the water droplet depend on the surface properties of the hydrophobic material.     

Rate enhancement of amines in the photopolymerization of methyl methacrylate under oxygen

The photopolymerization of methyl methacrylate was accelerated by amines such as N,N-dimethylbenzylamine, triethylamine, and diethylamine under nitrogen, in which additional initiating radicals were generated by the reaction of the amines with excited MMA. Enhanced rates were observed under oxygen for this photopolymerization in the presence of amines. Because UV spectra of the amines under oxygen indicated that the amines form charge-transfer complexes with oxygen, the rate enhancement was ascribed to photodecomposition of complexes that yield radical species. Molecular weights of polymers obtained in the photopolymerization in the presence of amines decreased under oxygen, supporting the assumed mechanism. © 1998 Society of Chemical Industry     

A study of decoupling with skeleton matrix in two‐degree‐of‐freedom generalized minimum variance control

There are many multi‐input multi‐output (MIMO) systems in chemical plants, and they have multiple time delays of different length in each input and output pair. This paper explains a two‐degree‐of‐freedom (2DOF) control system based on generalized minimum variance control (GMVC) for MIMO systems. It can improve the tracking performance with respect to the reference signals and the response properties for the disturbance. The states between the sampling period can be expressed by using the modified z transform to take account of multiple time delays. Additionally, a tracking controller is designed to decouple the plant. © 2011 Wiley Periodicals, Inc. Electr Eng Jpn, 176(1): 28–36, 2011; Published online in Wiley Online Library ( wileyonlinelibrary.com ). DOI 10.1002/eej.21046     

Design of multi‐input multi‐output minimum‐phase state control system with decoupling and feedforward compensation

This paper discusses the design of decoupling control for a multi‐input multi‐output (MIMO) linear system. A new configuration of the prepositional tandem matrix is presented as a decoupling compensator, and minimum‐phase state control is applied to the resulting decoupled system. In general, non‐minimum‐phase characteristics often accompany decoupled systems. Feedforward compensation makes the non‐minimum‐phase effect of each decoupled scalar system change to the delay time. A numerical example is given for the MIMO linear system, which conventionally results in non‐minimum‐phase systems. © 2011 Wiley Periodicals, Inc. Electr Eng Jpn, 176(2): 53–61, 2011; Published online in Wiley Online Library ( wileyonlinelibrary.com ). DOI 10.1002/eej.21117     

Shielding effect of double microelectrode tips in a scanning electrochemical microscope

Electrochemical interaction of coaxial double microelectrodes, in which a ring microelectrode was surrounded by another ring microelectrode, was investigated. Mass-transfer reactions that occurred on both inner and outer microelectrodes interfered with each other and showed a “shielding” effect depending on potentials and geometries of microelectrodes. Application of the inner microelectrode of the double microelectrodes for a probing tip of a scanning electrochemical microscope (SECM) revealed that the shielding effect by the outer microelectrode affected the electrochemistry on the inner microelectrode in the vicinity of the substrate surface. The effect was intensified above the insulator but attenuated above the conductor as the microelectrodes approached in feedback mode of the SECM. Approach to a critical interelectrode distance also intensified the shielding effect in the substrate generation/tip collection mode. An SECM line-scan using a platinum/epoxy resin-model substrate was carried out to investigate the shielding effect on current sensitivity and lateral resolution of an SECM image.     

Emission properties of Sm(III) complex having ten-coordination structure

Sammarium(III) complex having ten-coordination structure, bis-(1,10-phenanthroline)tris-(hexafluoroacetylacetonato)samarium(III) (Sm(hfa)₃(phen)₂) was prepared by chelation of tris-(hexafluoroacetylacetonato) samarium(III) (Sm(hfa)₃(H₂O)₂) with 1,10-phenantroline (phen). The characteristic ten-coordination structure of Sm(hfa)₃(phen)₂ was determined by ¹H NMR and elemental analyses. Strong deep-red emission (λ_max=643 nm) and narrow emission band (FWHM=5 nm) of Sm(hfa)₃(phen)₂ originated from electronic allowed transition from characteristics ten coordinate structure. The emission quantum yields Sm(hfa)₃(phen)₂ excited at absorption bands of ligands and Sm(III) ion were found to be 0.36 and 1.4%, respectively.     

Effective microbial production of poly(4‐hydroxybutyrate) homopolymer by Ralstonia eutropha H16

The effective microbial production of copolyesters of 3‐hydroxybutyrate (3HB) and 4‐hydroxybutyrate (4HB) with high mole fractions of 4HB units by a wild‐type strain of Ralstonia eutropha H16 was investigated in culture solutions containing 4‐hydroxybutyric acid (4HBA) and various carbon substrates in the presence of a nitrogen source such as ammonium sulfate. The addition of glucose or acetic acid to the culture solution containing 4HBA in the presence of ammonium sulfate resulted in the production of random copolymers of P(3HB‐co‐4HB) with compositions of up to 82 mol% 4HB, but the yield of copolymers was less than 7 wt% of dried cell weights. In contrast, when n‐alkanoic acids such as propionic acid, butyric acid, valeric acid and hexanoic acid, being subject to β‐oxidation metabolism in the cell, were used as the co‐substrates of 4HBA in the presence of ammonium sulfate, a mixture of copolymers with two different 4HB compositions was produced, and copolyesters with compositions of 93–100 mol% 4HB were isolated from chloroform–n‐hexane insoluble fractions in the mixture of copolymers. Especially, when this wild‐type Ralstonia eutropha H16 was cultivated in a medium containing 4HBA (15 g litre⁻¹), propionic acid (5 g litre⁻¹) and ammonium sulfate (5 g litre⁻¹), namely C/N (mol/mol) = 10, the P(4HB) homopolymer was produced at maximally 34 wt% of dry cell weight (7.8 g litre⁻¹), and the conversion yield of 4HBA to P(4HB) homopolymer resulted in values as high as 21 mol%. © 1999 Society of Chemical Industry     

Direct conversion of methane into methanol over MoO3/SiO2 catalyst in an excess amount of water vapor

Well-dispersed MoO₃ on SiO₂ showed a high activity for partial oxidation of methane (mixed with oxygen in a molar ratio of 9:1) into methanol and formaldehyde at 873 K in an excess amount of water vapor, which is attributed to the formation of silicomolybdic acid (SMA) on the catalyst surface during reaction. One of the roles of SMA for the partial oxidation of methane is proved to depress the successive oxidation of methanol and formaldehyde into carbon oxides.