Facile growth of novel morphology correlated Ag/Co-doped ZnO nanowire/flake-like composites for superior photoelectrochemical water splitting activity

In this paper, novel morphology correlation between silver nanowires (AgNWs) and cobalt (Co)-doped ZnO (Co-ZnO) flake-like thin films (nanowire/flake-like) has been proposed for enhanced photoelectrochemical (PEC) water splitting activity. Here in, high-quality AgNWs/Co-ZnO heterostructures enabled superior visible light water splitting activity compared to the pure ZnO and AgNWs/ZnO. To address the strategic effect of AgNWs coupling and transition metal (Co-2?at%) doping into the ZnO host lattice, we have carried out the X-ray diffraction, field emission scanning microscopy, X-ray photoelectron spectroscopy, UV–Vis transmittance, water contact angle and PEC analyses. In this way, PEC water splitting activity was mainly examined by linear sweep voltammetry (I-V), amperometric I-t and photoconversion efficiency (η) studies. The experimental results provide clear evidence of morphology correlation between AgNWs and Co-ZnO flake-like structures for strong visible light absorption. Specifically, AgNWs/Co-ZnO composites exhibited significant enhancement in the photocurrent density (7.0?×?10^?4 A/cm²) than AgNWs/ZnO (3.2?×?10^?4 A/cm²) and pure ZnO (1.5?×?10^?6 A/cm²). As a result, detailed AgNWs/Co-ZnO geometry has great potential for photoconversion efficiency (0.73%). In a word, the merits of controllable AgNWs/Co-ZnO heterostructure are proposed to improve the visible light harvesting and charge carrier generation for energy conversion devices.     

An efficient technique for the multilayered microwave and millimeter planar waveguides

The method of lines is extended to the multilayered inhomogenous dielectric layers by means of the additional transformation and the recurrence matrix. The computed dispersion diagrams for the multilayered planar waveguides agree very well with the results from other authors. New results for a six layer structure are given.     

Diffusion bonding of an aluminium-lithium alloy (AA8090) using aluminium-copper alloy interlayers

Diffusion bonds have been produced between sheets of an Al-Li-Cu-Mg-Zr alloy using aluminium-4% copper vapour deposited metallic interlayers. Microstructural changes occurred both in the parent alloy and in the bond interface after diffusion bonding cycles and post-bonding heat treatments were analysed. Different metallographic techniques (light microscopy, scanning and transmission electron microscopy) have been used. Diffusion bonding trials were carried out using the same alloy (AA8090), both in non-superplastic (T6) and superplastic conditions. Differences in their behaviours in relation to diffusion bonding were observed.     

拟动力实验中的数值积分方法

拟动力实验方法是目前最新的抗震实验方法，它克服了振动台实验中承载力不足、拟静力实验中无法真实模拟地震过程的缺点．本文详细论述了拟动力实验中的数值积分方法，其中包括：显式方法，隐式方法以及采用于结构技术时所需的特殊教值积分方法，并对这些方法的适用范围作了介绍．     

MIM Fe基合金的合金化强化

研究金属粉末注射成形铁基合金在强还原性氢气氛烧结条件下的合金化强化效果，结果表明，添加Ｃｕ、Ｎｉ、Ｍｏ等元素能取得显著的固溶强化效果，其中成分为Ｆｅ－２Ｎｉ－２Ｃｕ－０．４５Ｍｏ的机械性能达到σｂ＝４８３ＭＰａ，σｓ＝３４０ＭＰａ，δ＝９％和ＨＲＢ８３。     

Microstructural aspects of hypervelocity impact cratering and jetting in copper

Light and transmission electron microscopy techniques have been applied in observations of hypervelocity impact craters in two different copper targets: a 38 m grain size mill-processed target, and a 763 m grain size annealed target, the smaller grained target being impacted with a 1100 aluminium sphere and the larger grained target being impacted with a soda-lime glass sphere, at velocities near 6 km s^–1. Both target craters exhibited dynamic recrystallization near the crater wall. The jetting associated with these two craters was very different. Considerably more plastic flow and a larger rim characterized the larger grained target. No significant melt-related phenomena were observed either near the crater wall or in the jetted rim for either crater. Consequently, the principal features of crater formation involve extreme plastic flow in the solid state. Microbands were observed to occur profusely in a zone below the smaller grained mill-processed target crater while more profuse and extremely long, unidirectional bundles of microbands (which were coincident with traces of {1 1 1} planes) occurred below the annealed larger grained target crater. These observations attest to the dominant and unique role played by deformation microbands in cratering in copper, because essentially no deformation twins were observed in either target.     

Primary particle movement and change of property of cast iron by centrifugal effect in semi-solid processing

The particle distribution in semi-solid slurry under centrifugal field was simulated and the main factors such as fraction of solid, rotation speed, and holding time effecting the particle distributions are discussed. The simulation results showed that primary particles rich zone is produced in radially outer area and these results are in good agreement with the experiment. The centrifugal effect produces the primary particles distribution along the radial direction. Denser particles are concentrated in outside than inner side. For high fraction of solid samples, ‘wall’ appear in the middle of samples because of high viscosity region making particle difficult to move. Longer holding time gives denser primary particles concentrated more in outside than inner side. Higher rotation speed gives increased gradient of hardness in the radial direction. It is due to that number of primary austenite at inner side at higher rotation speed is less than that at lower rotation one. At higher rotation speed, ledeburite forms more at inner side of specimen than at the other one. It is also shown that semi-solid processing at lower fraction of solid gives higher hardness because smaller number of primary austenite, namely more ledeburite forms in microstructure. The present study gives useful information on producing material with locally changing property by semi-solid processing.     

The roles of the Trommsdorff–Norrish effect in phase separation of binary polymer mixtures induced by photopolymerization

Influence of the Trommsdorff–Norrish (T–N) effect on the phase separation of methyl methacrylate (MMA)/poly(ethyl acrylate) (PEA) mixtures undergoing photo-polymerization was examined by a combination of several experimental techniques. By FT-IR spectroscopy, it was found that the polymerization conversion explosively increases at the onset of this T–N effect. The characteristic irradiation time τ at which this effect occurs, strongly depends on the light intensity and gradually shifts to early time as the irradiation intensity increases. The shrinkage of the mixture observed in situ by laser-scanning confocal microscopy exhibits a transition at a particular irradiation time which is slightly longer than the characteristic time τ. By gel permeation chromatography (GPC), it was found that the molecular weight of the resulting PMMA was almost unchanged before τ and suddenly increases about an order of magnitude after the onset of the auto-acceleration effect. Finally, the characteristic length scales of the morphology also quickly increase with irradiation time and are eventually frozen by this T–N effect. These experimental results indicate that the Trommsdorff–Norrish effect plays an important role in the kinetic processes of polymerization-induced phase separation, suggesting an efficient tool to control the morphology of the polymerizing mixture.     

麻疯树中萜类物质的性质及研究进展

麻疯树属Jatropha L.为大戟科Euphorbiaceae植物.该属约有200余种植物,主要分布于热带和亚热带地区,在我国广东、广西、云南、贵州、福建等地区,有栽培和野生的该属植物,本文仅就近年来从该属植物中分离、鉴定的萜类化合物性质、研究进展等进行综述.