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1.
Summary
Novel through-spaceπ-conjugated polymer based on poly(p-henyleneethynylene)/poly(p-phenylenebutadiynylene) hybrids containing a [2.2]paracyclophane unit in the main chain was synthesized by copper-catalyzed
alkyne coupling reaction. The structure of the polymer was supported by 1H NMR and IR spectra. The obtained polymer was soluble in common organic solvents such as THF, CH2C12, CHC13 and toluene. The number-average of molecular weight of the polymer was estimated to be 63000 by GPC. The polymer emitted
a bluish green light in solution and in the solid state.
Received:24 September 2002/Revised version: 19 November 2002/Accepted: 19 November 2002
Correspondence to Yoshiki Chujo 相似文献
2.
Hamdy F.M. Mohamed K. Ito Y. Kobayashi N. Takimoto Y. Takeoka A. Ohira 《Polymer》2008,49(13-14):3091-3097
The mechanism of gas permeation in Nafion membranes for polymer electrolyte fuel cells has been investigated from the viewpoint of free volume. Three different samples, a membrane with ionic exchange capacity (IEC) = 0.92 meq/g, and recast samples with IEC = 0.92 and 1.00 meq/g were used after drying. Free volume was quantified using the positron annihilation lifetime (PAL) technique and gas permeabilities were measured for O2 and H2 as functions of temperature and relative humidity. Good linear correlations between the logarithm of the permeabilities at different temperatures and reciprocal free volume indicate that gas permeation in dry Nafion is governed by the free volume. Nevertheless permeabilities are much smaller than the corresponding flexible chain polymer with a similar free volume size due to stiff chains of the perfluoroethylene backbone. In highly hydrated Nafion above 60% relative humidity, where the O2 permeability varies oppositely to the free volume, gas permeation proved to be controlled by the gradual increase in overall flexibility of the Nafion–water system. 相似文献
3.
Moritoshi Yasunaga Noriyuki Aibe Yoshiki Yamaguchi Yorihisa Yamamoto Takaaki Awano Ikuo Yoshihara 《Artificial Life and Robotics》2008,12(1-2):219-222
Watching and tracking an object while seeing a much wider view is one of advantages of the eye system. We proposed and developed
a tracking camera system that mimics the eyes by using double-lens modules. In the system, a wide view is captured through
the wide-lens module, while the target in it is tracked and magnified through the telescopic lens module. Electronic circuits
for tracking control are implemented onto the reconfigurable VLSI or FPGA in order to embed the parallelism in the tracking
algorithm into the hardware. A successfully developed FPGA-based prototype performs high-speed tracking at the video-rate.
This work was present in part at the 12th International Symposium on Artificial Life and Robotics, Oita, Japan, January 25–27,
2007 相似文献
4.
Summary Giant hybrid liposomes of polymerizable lipid and cholesterol were prepared by the hydration method and were polymerized by UV irradiation. The obtained giant liposomes were freeze-dried and washed with chloroform to skeletonize the frame structure of the polymerized membrane. The skeletonized liposomes were directly confirmed by scanning electron microscopy. The single-layered and fully spherical liposome frame were easily confirmed by the stereo-pair of the obtained micrographs. 相似文献
5.
Development of flexible displays using back‐channel‐etched In–Sn–Zn–O thin‐film transistors and air‐stable inverted organic light‐emitting diodes
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Mitsuru Nakata Genichi Motomura Yoshiki Nakajima Tatsuya Takei Hiroshi Tsuji Hirohiko Fukagawa Takahisa Shimizu Toshimitsu Tsuzuki Yoshihide Fujisaki Toshihiro Yamamoto 《Journal of the Society for Information Display》2016,24(1):3-11
We developed flexible displays using back‐channel‐etched In–Sn–Zn–O (ITZO) thin‐film transistors (TFTs) and air‐stable inverted organic light‐emitting diodes (iOLEDs). The TFTs fabricated on a polyimide film exhibited high mobility (32.9 cm2/Vs) and stability by utilization of a solution‐processed organic passivation layer. ITZO was also used as an electron injection layer (EIL) in the iOLEDs instead of conventional air‐sensitive materials. The iOLED with ITZO as an EIL exhibited higher efficiency and a lower driving voltage than that of conventional iOLEDs. Our approach of the simultaneous formation of ITZO film as both of a channel layer in TFTs and of an EIL in iOLEDs offers simple fabrication process. 相似文献
6.
Ryu Nakadate Yoshiki MatsunagaJorge Solis Atsuo Takanishi Eiichi MinagawaMotoaki Sugawara Kiyomi Niki 《Mechanism and Machine Theory》2011,46(8):1066-1083
The ultrasound diagnosis of the carotid artery is one of the most common non-invasive methods to detect early stage heart and cerebrovascular diseases. However, the precision and repetitiveness of the probe positioning depend exclusively on the operator's skills and dexterity. For this purpose, we propose the development of a robot assisted system to enhance the accuracy and repetitiveness of the probe positioning to measure the wave intensity (WI) index. In this paper, the Waseda-Tokyo Women's Medical-Aloka Blood Flow Measurement Robot System No. 2 Refined (WTA-2R) is presented. The WTA-2R consists of a conventional ultrasound diagnosis system, a 6-DOFs parallel link slave manipulator, a 6-DOFs serial link passive arm, and a master device. Experiments were carried out to verify its effectiveness in terms of accuracy and required time to perform the task. From the experimental results, the positioning accuracy and reduction of required time were confirmed. 相似文献
7.
Yoshiki Nakajima Tatsuya Takei Toshimitsu Tsuzuki Mitsunori Suzuki Hirohiko Fukagawa Toshihiro Yamamoto Shizuo Tokito 《Journal of the Society for Information Display》2009,17(8):629-634
Abstract— A 5.8‐in. wide‐QQVGA flexible color active‐matrix organic light‐emitting‐diode (AMOLED) display consisting of organic thin‐film transistors (OTFTs) and phosphorescent OLEDs was fabricated on a plastic film. To reduce the operating voltage of the OTFTs, Ta2O5 with a high dielectric constant was employed as a gate insulator. Pentacene was used for the semiconductor layer of the OTFTs. This layer was patterned by photolithography and dry‐etched using a dual protection layer of poly p‐xylylene and SiO2 film. Uniform transistor performance was achieved in the OTFT backplane with QQVGA pixels. The RGB emission layers of the pixels were formed by vacuum deposition of phosphorescent small molecules. The resulting display could clearly show color moving images even when it was bent and operated at a low driving voltage (below 15 V). 相似文献
8.
Nobuyuki?KobayashiEmail author Tsubasa?Wago Yoshiki?Sugawara 《Multibody System Dynamics》2011,26(3):265-281
A method of reducing the system matrices of a planar flexible beam described by an absolute nodal coordinate formulation (ANCF)
is presented. In this method, we focus that the bending stiffness matrix expressed by adopting a continuum mechanics approach
to the ANCF beam element is constant when the axial strain is not very large. This feature allows to apply the Craig–Bampton
method to the equation of motion that is composed of the independent coordinates when the constraint forces are eliminated.
Four numerical examples that compare the proposed method and the conventional ANCF are demonstrated to verify the performance
and accuracy of the proposed method. From these examples, it is verified that the proposed method can describe the large deformation
effects such as dynamic stiffening due to the centrifugal force, as well as the conventional ANCF does. The use of this method
also reduces the computing time, while maintaining an acceptable degree of accuracy for the expression characteristics of
the conventional ANCF when the modal truncation number is adequately employed. This reduction in CPU time particularly pronounced
in the case of a large element number and small modal truncation number; the reduction can be verified not only in the case
of small deformation but also in the case of a fair bit large deformation. 相似文献
9.
Using the value chain model which provides a process view, this longitudinal case study and simulation modeling analysis of
a Canadian third-party logistics (TPL) supply chain provides some empirical support for the enabling role of RFID technology
in effecting warehouse process innovation and optimization for the focal TPL firm. However, the findings of our study also
reveal the RFID technology implementation costs as the key inhibitor of RFID widespread adoption and usage among suppliers.
This, in turn, precluded the focal TPL firm from implementing the best optimum RFID solution to create better business value
from the RFID project. 相似文献
10.
Masaharu Komori Fumi Takeoka Jungchul Kang Yukihiko Kimura 《Artificial Life and Robotics》2011,16(2):162-164
The range of speed or torque of motors is limited to some degree. Industrial vehicles working in factories are required to
output a large force when they carry loads, and also to move with high velocity when they move to their destination. However,
it is impossible to realize both those requirements if a conventional reduction device is used. Velocity variation devices
using gears are widely used to change the velocity ratio between the input and output shafts. However, the motion transmission
from the input shaft to the output shaft is interrupted during the velocity ratio variation process. In order to solve this
problem, a velocity variation method that can transmit motion continuously is proposed, in which a motion transmitting element
is used. In this report, a motion transmitting element using the geometrical analysis method is proposed, a method of expressing
the curve using dispersed points is proposed, and a method of calculating the inclination and the distances along the curve
is developed. Based on the proposed methods, the geometrical form of the transmitting element is analyzed. 相似文献