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Chaiyot Tangsathitkulchai Yuvarat Ngernyen Malee Tangsathitkulchai 《Korean Journal of Chemical Engineering》2009,26(5):1341-1352
The incorporation of oxygen functional groups onto the surface of eucalyptus activated carbon and its surface chemistry were
investigated as a function of oxidation conditions, carbon porous properties and carbon preparation method. Under all treatment
conditions of increasing time, temperature and oxidant concentration, liquid oxidation with HNO3, H2O2 and (NH4)2S2O8 and air oxidation led to the increase of acidic group concentration, with carboxylic acid showing the largest percentage
increase and air oxidation at the maximum allowable temperature of 350 °C produced the maximum content of both carboxylic
acid and total acidic group. Nitric acid oxidation of chemically activated carbon produced higher total acidic content but
a lower amount of carboxylic acid compared to the oxidized carbon from physical activation. The increased contents of acidic
groups on oxidized carbons greatly enhanced the adsorption capacity of water vapor and heavy metal ions. 相似文献
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Supunnee Junpirom Chaiyot Tangsathitkulchai Malee Tangsathitkulchai Yuvarat Ngernyen 《Korean Journal of Chemical Engineering》2008,25(4):825-832
This work presents the behavior of water adsorption in the activated carbons with different porous structure derived by varying
the level of char burn-off. Water adsorption isotherms of activated carbons prepared from longan seed at three different burn-offs
(19, 26 and 60%) were measured gravimetrically. These obtained carbons were different in terms of their pore size distribution
and also the surface functional group properties by showing an increasing of total pore volume and the concentration of surface
functional groups with increasing in the burn-off level. The water adsorption isotherms showed that the behavior and amount
of water uptake could be divided into three consecutive ranges of relative pressure, 0.0–0.3, 0.3–0.7 and 0.7–0.94, corresponding
to adsorption in ultramicropores, supermicropores, and mesopores, respectively. The isotherm data were simulated by a cluster
model proposed by Do and Do. The correlation was found to be satisfactory over the entire range of relative pressure only
with the lowest burn-off carbon which contained mainly micropores. For higher burn-off carbons, which showed increasing proportions
of mesopores, the model needed to be modified by increasing the cluster size of the adsorbed water molecules from 5 to 20
for adsorption at relative pressures greater than about 0.7. 相似文献
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Yuvarat Ngernyen Chaiyot Tangsathitkulchai Malee Tangsathitkulchai 《Korean Journal of Chemical Engineering》2006,23(6):1046-1054
This work focused on the preparation of activated carbon from eucalyptus and wattle wood by physical activation with CO2. The preparation process consisted of carbonization of the wood samples under the flow of N2 at 400°C and 60 min followed by activating the derived chars with CO2. The activation temperature was varied from 600 to 900°C and activation time from 60 to 300 min, giving char burn-off in
the range of 20/2-83%. The effect of CO2 concentration during activation was also studied. The porous properties of the resultant activated carbons were characterized
based on the analysis of N2 adsorption isotherms at −196°C. Experimental results showed that surface area, micropore volume
and total pore volume of the activated carbon increased with the increase in activation time and temperature with temperature
exerting the larger effect. The activated carbons produced from eucalyptus and wattle wood had the BET surface area ranging
from 460 to 1,490 m2/g and 430 to 1,030 m2/g, respectively. The optimum activation conditions that gave the maximum in surface area and total pore volume occurred at
900°C and 60 min for eucalyptus and 800°C and 300 min for wattle wood. Under the conditions tested, the obtained activated
carbons were dominated with micropore structure (∼80% of total pore volume). 相似文献
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