Joint Determination of the State Dimension and Autoregressive Order for Models with Markov Regime Switching

Abstract. This paper is concerned with the problem of joint determination of the state dimension and autoregressive order of models with Markov‐switching parameters. A model selection procedure is proposed which is based on optimization of complexity‐penalized likelihood criteria. The efficacy of the procedure is evaluated by means of Monte Carlo experiments.     

The hurdle effect of osmotic pretreatment and high‐pressure cold pasteurisation on the shelf‐life extension of fresh‐cut tomatoes

Tomatoes are perishable products due to the activity of microorganisms and endogenous enzymes. The objective was to produce cut tomatoes with extended shelf life, using the combined hurdle effect of osmotic pretreatment (OD) and high pressure (HP), instead of a conventional one‐step thermal process. Samples were processed in a multicomponent osmotic solution at 35 °C, subsequently cold‐pasteurised in pack at 600 MPa and stored at 5–15 °C. Quality deterioration during isothermal and nonisothermal storage was kinetically modelled. Both OD process and OD‐HP combined process caused an increase in lycopene content that was well retained. Texture, colour and flavour of treated samples were evaluated as similar to fresh, with OD‐HP samples showing better retention during storage. Being microbiologically stable, shelf life of OD‐HP samples was limited by sensory deterioration, whereas OD samples were rejected due to eventual microbial growth. Shelf life of OD and OD‐HP samples was estimated at 77 and 181 days, respectively, at 5 °C.     

Harmonic distortion assessment for a single-phase grid-connected photovoltaic system

Nowadays, grid-connected photovoltaic (PV) systems constitute an emerging technology. This has given rise to concerns about their contribution to harmonic distortion levels in utility grids. Valuable insight into the electrical behavior of such a system, including its impact on power quality, can be obtained through extensive simulation studies. In this paper, models are developed with a focus on not only accurate but also fast simulation of grid-connected PV systems. First, time-consuming processes are identified and discussed. These are mainly associated with the semiconductor power switching devices and the non-linear characteristics of the system components (isolation transformer, PV generator). Next, models are developed in order to increase simulation speed by avoiding time-consuming procedures. The validity of the approach is ascertained by comparing simulation results with published measurements. A case study is then performed in order to obtain current and voltage waveforms and, subsequently, harmonic distortion levels. Further simulations are carried out using different values for various system parameters in order to make an assessment of their impact in terms of waveform distortion.     

BDD anodic oxidation as tertiary wastewater treatment for the removal of emerging micro‐pollutants,pathogens and organic matter

This work reports for the first time the removal of 17α‐ethynylestradiol (EE2), a synthetic estrogen hormone, from secondary treated effluents by electrochemical oxidation. Experiments were conducted in a single compartment reactor comprising a boron‐doped diamond (BDD) anode and a zirconium cathode. EE2, in the range 100–800 µg L^?1, was spiked in the post‐chlorination effluent of a municipal treatment plant and oxidized at 0.9–2.6 mA cm^?2 current density. Complete degradation of 100 µg L^?1 EE2 was achieved in 7 min at 2.1 mA cm^?2 and inherent conditions, while the addition of 0.1 mol L^?1 NaCl achieved removal in just a few seconds. The process was then tested in the pre‐chlorination effluent at 2.1 mA cm^?2 and inherent conditions; complete E. coli killing and EE2 removal occurred in just 1.5 and 3.5 min, respectively, while overall estrogenicity (assessed by the YES assay) and residual organic matter (in terms of chemical oxygen demand (COD)) decreased by 50% and 85% after 30 min, respectively. These results clearly show the potential of BBD electrochemical oxidation to serve as an efficient tertiary wastewater treatment. Copyright © 2011 Society of Chemical Industry     

Diffusion-Induced Void Evolution in Core–Shell Nanowires: Elaborated View on the Nanoscale Kirkendall Effect

In 2006, our group reported the fabrication of ultra-long single-crystal ZnAl₂O₄ spinel nanotubes, starting from ZnO/Al₂O₃ core–shell nanowires, involving the nanoscale Kirkendall effect. In this feature paper, we introduce our up-to-date results on the design of porous and hollow 1D nanostructures following this solid-state interfacial reaction route. In particular, we present our recent understandings on void evolution induced by the unbalanced diffusion. We first give a short introduction on the distinctions of core–shell nanowires in interfacial nanoreactions, in contrast to other systems. Then we discuss the roles of desorption, stress, and/or defects on void evolution and nanotube formation. Our results demonstrate that the stress- and defects-engineered diffusion mechanism can be used to specifically design hollow nanostructures, which will open up a new window in exploitation of the Kirkendall effect at the nanoscale.     

Structural analysis of W7-X: From design to assembly and operation

The Wendelstein 7-X (W7-X) modular stellarator is in the assembly phase at the Max-Planck-Institut für Plasmaphysik in Greifswald, Germany. The design of the “basic machine”, i.e. without in-vessel components, diagnostics and periphery, is largely completed, structural parameters such as bolt preload, initial conditions for contact elements, etc. are defined, and most of the components are manufactured and partly assembled. Therefore, the focus of structural analysis was shifted towards fast analyses of non-conformities, changes in the assembly procedure, and exploration of operational limits. Assembly-related work is expected to continue until commissioning of the machine, however, with decreasing intensity. In parallel the analysis requirements for in-vessel components, diagnostics and periphery will increase.This paper focuses on the most remarkable results, on special problems which had to be solved, on strategic issues like parameterization, complex finite element model structuring and benchmarking with alternative models in different codes, on assumptions of reasonable safety margins and expected tolerances, and on confirmation of analysis results by tests. Finally it highlights some lessons learned so far, which might be relevant also for other large fusion machines, and gives an outlook on future work.     

Melt flow control in a multistrand tundish using a turbulence inhibitor

Water modeling and mathematical simulation techniques were used to study the melt flow under the influence of turbulence inhibitors in a multistrand bloom caster tundish. Three different cases were studied: a bare tundish (BT), a tundish with two pairs of baffles and a waved impact pad (BWIP), and a tundish equipped with turbulence inhibitor and a pair of dams (TI&D). Chemical mixing of tracer turbulence diffusion was also simulated and compared with actual experimental results. The TI&D arrangement showed an improvement of the fluid flow characteristics, yielding better tracer distribution among the outlets, lower values of back mixing flow, and higher values of plug flow. A mass transfer model coupled with k-ɛ turbulence model predicted acceptably well the experimental chemical mixing of the tracer in the water model. The water modeling and the numerical simulation indicated that the TI&D arrangement retains the tracer inside the vessel for longer times, increasing the minimum residence time. These results encourage the use of turbulence-inhibiting devices in bloom and billet casters, which pursue excellence in product quality.     

Transient phenomena of RLC circuits - The photovoltaic input

The calculation and study of transient phenomena occurring when a photovoltaic (PV) source is applied to RLC circuits are presented in this paper. The method of approach adopted is based on an incremental model of the photovoltaic generator as opposed to the usual numerical integration algorithm for the solution of the governing non-linear differential equations. Such an approach is of particular advantage in many respects. On the quantitative basis, it ensures both accuracy and numerical stability even if a large time step is used. On the qualitative basis, it gives the ability to have a better insight into the response evolution and visualizes the effects that the various parameters may have on the nature of the transient response. Finally, it reveals some interesting and useful features about the transient behavior of a passive load driven by a PV generator, so that conclusions from the engineering viewpoint can be drawn.     

Energy Offset Between Silicon Quantum Structures: Interface Impact of Embedding Dielectrics as Doping Alternative

Ultrasmall silicon (Si) nanoelectronic devices require an energy shift of electronic states for n‐ and p‐conductivity. Nanocrystal self‐purification and out‐diffusion in field effect transistors cause doping to fail. Here, it is shown that silicon dioxide (SiO₂) and silicon nitride (Si₃N₄) create energy offsets of electronic states in embedded Si quantum dots (QDs) in analogy to doping. Density functional theory (DFT), interface charge transfer (ICT), and experimental verifications arrive at the same size of QDs below which the dielectric dominates their electronic properties. Large positive energy offsets of electronic states and an energy gap increase exist for Si QDs in Si₃N₄ versus SiO₂. Using DFT results, the SiO₂/QD interface coverage is estimated with nitrogen (N) to be 0.1 to 0.5 monolayers (ML) for samples annealed in N₂ versus argon (Ar). The interface impact is described as nanoscopic field effect and propose the energy offset as robust and controllable alternative to impurity doping of Si nanostructures.