全文获取类型
收费全文 | 667篇 |
免费 | 27篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 8篇 |
化学工业 | 253篇 |
金属工艺 | 26篇 |
机械仪表 | 18篇 |
建筑科学 | 37篇 |
矿业工程 | 5篇 |
能源动力 | 19篇 |
轻工业 | 51篇 |
水利工程 | 8篇 |
石油天然气 | 2篇 |
无线电 | 27篇 |
一般工业技术 | 114篇 |
冶金工业 | 30篇 |
原子能技术 | 7篇 |
自动化技术 | 90篇 |
出版年
2022年 | 24篇 |
2021年 | 32篇 |
2020年 | 9篇 |
2019年 | 5篇 |
2018年 | 19篇 |
2017年 | 23篇 |
2016年 | 24篇 |
2015年 | 13篇 |
2014年 | 29篇 |
2013年 | 57篇 |
2012年 | 24篇 |
2011年 | 43篇 |
2010年 | 19篇 |
2009年 | 46篇 |
2008年 | 26篇 |
2007年 | 27篇 |
2006年 | 18篇 |
2005年 | 20篇 |
2004年 | 16篇 |
2003年 | 20篇 |
2002年 | 12篇 |
2001年 | 16篇 |
2000年 | 10篇 |
1998年 | 2篇 |
1997年 | 4篇 |
1996年 | 7篇 |
1995年 | 5篇 |
1994年 | 7篇 |
1993年 | 4篇 |
1992年 | 7篇 |
1991年 | 2篇 |
1990年 | 5篇 |
1989年 | 5篇 |
1988年 | 7篇 |
1987年 | 9篇 |
1986年 | 6篇 |
1985年 | 9篇 |
1984年 | 11篇 |
1983年 | 11篇 |
1982年 | 9篇 |
1981年 | 9篇 |
1980年 | 9篇 |
1979年 | 6篇 |
1977年 | 3篇 |
1976年 | 6篇 |
1975年 | 2篇 |
1974年 | 4篇 |
1973年 | 3篇 |
1970年 | 2篇 |
1956年 | 2篇 |
排序方式: 共有695条查询结果,搜索用时 15 毫秒
1.
The effect of methanol, acetone, formalin and glucose on the nitrification process in the packed bed reactors has been investigated. For the utilized compounds the inhibition constant Ki was determined according to Dixon's method. The determined values were as follows: methanol Ki = 116.0 mg l?1; acetone Ki = 804.2 mg l?1; formalin Ki = 61.5 mg l?1. The value of Ki for glucose has not been determined because glucose in applied concentration up to 11,325 mg l?1 had no effect on the nitrification course. 相似文献
2.
The temperature programmed (palladium) hydride decomposition appeared very effective method for diagnosing the extent of alloying in Pd-Pt/SiO2 catalysts. Introduction of Pt to Pd catalysts moves the TPHD peak gradually towards lower temperatures and the shift in hydride decomposition peak is accompanied by a decrease in the amount of released hydrogen. The catalysts prepared the direct redox method showed much better alloy homogeneity than the samples prepared by coimpregnation. The results of probing with other techniques, i.e. catalytic probing with hydrodechlorination of CCl2F2 and XRD, were in line with TPHD data. The catalytic probing showed the presence of synergistic effect, a clear indication of Pd-Pt mixing. XRD data of post-reaction samples showed carbon incorporation into Pd-rich phase, whereas separate Pt-rich phase did not experience any bulk carbiding. 相似文献
3.
4.
Zbigniew W. Kowalski 《Journal of Materials Science》1985,20(5):1521-1555
It is the purpose of the paper to promote the ion beam sputtering technique and its biomedical applications among not only ion beam users but also other research workers, and especially, among biologists and medical doctors. The objectives of this article are threefold. Firstly, it supplies a conceptual background for discussing the main question of this work, i.e. biomedical applications of sputtering. Secondly, the title issue and some related problems, important in the biomedical use, are widely presented and discussed. Finally, clinical implication and potential applications are shown. 相似文献
5.
6.
Marta Krychowiak-Manicka Mirosawa Krauze-Baranowska Sylwia Godlewska Zbigniew Kaczyski Aleksandra Bielicka-Giedo Natalia Grzegorczyk Magdalena Narajczyk Joanna E. Frackowiak Aleksandra Krolicka 《International journal of molecular sciences》2021,22(9)
Carnivorous plants are exemplary natural sources of secondary metabolites with biological activity. However, the therapeutic antimicrobial potential of these compounds is limited due to intrinsic resistance of selected bacterial pathogens, among which Pseudomonas aeruginosa represents an extreme example. The objective of the study was to overcome the intrinsic resistance of P. aeruginosa by combining silver nanoparticles (AgNPs) with secondary metabolites from selected carnivorous plant species. We employed the broth microdilution method, the checkerboard titration technique and comprehensive phytochemical analyses to define interactions between nanoparticles and active compounds from carnivorous plants. It has been confirmed that P. aeruginosa is resistant to a broad range of secondary metabolites from carnivorous plants, i.e., naphthoquinones, flavonoids, phenolic acids (MBC = 512 µg mL−1) and only weakly sensitive to their mixtures, i.e., extracts and extracts’ fractions. However, it was shown that the antimicrobial activity of extracts and fractions with a significant level of naphthoquinone (plumbagin) was significantly enhanced by AgNPs. Our studies clearly demonstrated a crucial role of naphthoquinones in AgNPs and extract interaction, as well as depicted the potential of AgNPs to restore the bactericidal activity of naphthoquinones towards P. aeruginosa. Our findings indicate the significant potential of nanoparticles to modulate the activity of selected secondary metabolites and revisit their antimicrobial potential towards human pathogenic bacteria. 相似文献
7.
Honglin Chen Hong Yang Yevgenia Briker Craig Fairbridge Oladipo Omotoso Lianhui Ding Ying Zheng Zbigniew Ring 《Catalysis Today》2007,125(3-4):256-262
Pt supported on a carbon molecular sieve (Pt/CMS) was prepared by pyrolysis of polyfurfuryl alcohol containing pre-reduced Pt particles. The catalysts were characterized by hydrogen chemisorption, XRD, N2 adsorption/desorption and TEM. Hydrogen chemisorption showed that not all the Pt particles were exposed to H2 molecules. Oxidation treatment made Pt particles more accessible to H2. Catalyst activity was evaluated by hydrogenation of 1-hexene. Hydrogen spillover was demonstrated by diluting Pt/CMS with activated carbon or hydrogen type zeolite Y. The initial conversion of 1-hexene was increased from 86.5% to 98.5% and to 100% when Pt/CMS was diluted with activated carbon and hydrogen type zeolite, respectively. The high initial conversion was sustained for 6 h in the presence of diluents while the conversion decreased quickly for Pt/CMS alone. 相似文献
8.
The interaction of nitric oxide with Ce0.75Zr0.25O2 solid solution were investigated by means of EPR and IR spectroscopies. The influence of adsorption parameters such as adsorption temperature and pressure, presence of the O2 co-reactant on the nature and relative surface abundance of the resultant mono- and dimeric NO species was elucidated. The thermal stability of the surface nitrosyl complexes and their reactivity toward dioxygen were also examined. 相似文献
9.
Adsorption of CO onto dehydrated cobalt-exchanged ZSM-5 zeolite was studied by CW-EPR techniques. It is shown that the reversible formation of a low spin carbonyl 1{Co(CO)
n
}7 adduct upon addition of carbon monoxide at p
CO>50–60 Torr involves significant change in the spin state of Co2+ from S=3/2 to 1/2. The spin Hamiltonian parameters of the adduct g
x
=2.222, g
y
=2.184, g
z
=2.011, |A
x
|=3.8 mT, |A
y
|=3.2 mT, |A
z
|=7.9 mT were determined by a computer simulation and further discussed in terms of the possible ground state and molecular structure. It is shown that the 1{Co(CO)
n
}7 cage complex exhibits a C2v symmetry with |z
2,2A1 ground state. 相似文献
10.
Ming Li Zbigniew Twardowski Felix Mok Norbert Tam 《Journal of Applied Electrochemistry》2007,37(4):499-504
Sodium dichromate is commonly used in sodium chlorate production to maintain high current efficiency; however, it is also
a well documented carcinogen. To reduce the environmental impact, identification of a suitable alternative with similar buffering
characteristics to dichromate and without adverse effect on the electrolytic performance of sodium chlorate production is
important; sodium molybdate is a good candidate. Molybdate ion and its conjugated acid work as a buffer pair at pH 5–6, a
lower and slightly narrower pH window than the typical buffer region of dichromate. Nonetheless, the molybdate buffer works
effectively during the electrolytic process by maintaining pH at 5.9. Although the use of molybdate buffer will lower the
overpotential of hydrogen evolution reaction (HER) by 100 mV, the average off-gas oxygen content is noticeably compromised
at 3.6–4.6%, measured using a pilot cell operated at 3 kA m−2and 80 °C during a 3-day trial. The resulting current efficiency of 91 92% is significantly lower than when dichromate is
employed as the process additive (> 96%). Mixtures of different dichromate and molybdate ratio were also investigated in terms
of the resulting cathode surface potential. 相似文献