Synthesis and characterization of polyaniline films using Fenton reagent

The chemical oxidation of aniline to form polyaniline (PANI) films and powder samples was made using Fenton reagent as an oxidizing agent in aqueous sulfuric acid medium. The PANI films were monitored by using the quartz crystal microbalance and the electronic absorption techniques. The optimum concentration was determined and the results were justified by measuring the UV–vis absorption spectra for the in situ PANI films. The conductivity for the PANI films and powder samples, prepared in different conditions, was measured. Also, the IR spectra, X‐ray and the thermogravimetric analysis for the PANI powder formed in the bulk were measured and compared with the polymer prepared using ammonium peroxydisulfate. A preliminary investigation to the dielectric properties of the polymer powder was measured and discussed. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Influence of Neotyphodium coenophialum on copper concentration in tall fescue

Poor performance of livestock that graze tall fescue (Festuca arundinacea Schreb.) has been associated with the endophyte fungus Neotyphodium coenophialum [Morgan-Jones and Gams] Glenn, Bacon, and Hanlin). Recent evidence suggests lowered Cu status and a depression of Cu-related immune function in steers that graze endophyte-infected (E+) tall fescue. Greenhouse and field studies investigated relationships between the endophyte and Cu concentrations in tall fescue. Seventeen infected 'Kenhy' clones were divided, and one plant of each pair was treated three times with Benomyl to remove the endophyte (E-). Plants were watered with nutrient solution in a greenhouse for 6 mo before sampling. Copper concentrations were greater (P < .001) in E- than in E+ clones (3.4 vs 2.8 microg/g; SE, .06). In the second greenhouse experiment, genetically similar E+ and E- 'Kentucky'-31 (KY-31) and 'Georgia Jessup' were grown from seed and fertilized with nutrient solution to produce mature plants. Copper concentrations were higher (P < .05) in E- than in E+ tall fescue (8.6 vs 7.6 microg/g; SE, .3). In a field plot experiment in Texas, E+ and E- KY-31 were grown with 0, 50, and 100% replacement of potential evapotranspiration. By September, Cu concentrations were higher (P < .05) in E- than in E+ tall fescue (7.3 vs 6.6 microg/g; SE, .2). In pasture experiments, KY-31 E+ (> 70% infection level) and E- (< 5% infection level) tall fescue were grown in Virginia at two locations with three rates of N fertilizer. Copper concentrations were higher (P < .05) in E- than in E+ tall fescue (4.8 vs 4.5 microg/g; SE, .1) and increased (P < .01) linearly in response to N. Our data demonstrate that the presence of the endophyte is associated with lower Cu concentrations in tall fescue, which may contribute to lowered Cu status in animals and thus contribute to the etiology of fescue toxicity.     

Governance and Climate Vulnerability Index

Water resources in the Middle East are under enormous stress, due to an increase in population growth and the extensive use of water resources, which exceeds the water demand in this regional bloc. Moreover, climatic changes pose another dimension of stress on water resources; these changes have significant environmental, social, and economic effects. In fact, the governance of these countries has the tendency of increasing this stress or decreasing it, depending on its performance and efficiency in applying policies, legislation and managerial plans towards decreasing the poverty and the vulnerability of the countries specially those suffering from poverty. In this paper, the vulnerability of five countries-Israel, Jordan, Lebanon, Palestine and Syria??will be assessed based on the extent of climate changes and the type of climate governance and their effects on water resources. This paper will introduce a new index, which will be called the Governance and Climate Vulnerability Index (GCVI). The index will measure the vulnerability of each country vis-à-vis water-related issues, while taking into account governance and climatic indicators. The vulnerability of these countries will also be ranked, for purposes of comparison. This paper concludes with the recommendation for governments to develop appropriate water resources management and to improve their environmental policies, including raising awareness on multiple levels. These strategies are expected to lead to decreased vulnerability to climatic changes.     

Dominant Mechanisms for Metal Removal from Acidic Aqueous Solutions by Cement Kiln Dust

Copper and zinc ions were removed from synthetic acidic aqueous solutions onto cement kiln dust (CKD) particles in a single component system. The objectives of this study were to: distinguish between adsorption and precipitation when both mechanisms are occurring simultaneously; define their individual contributions; and consequently, specify the dominant mechanism. This was achieved by conducting a new experimental procedure for the precipitation phase that depended on CKD leachate in combination with a derivation of a simultaneous adsorption-precipitation equation. High removal efficiencies, approaching 100?%, of the Cu and Zn ions, were attained. Precipitation was the dominant mechanism for removing low concentrations of these metals, while adsorption appears to be more significant in removal of high metal concentrations.     

Spectral efficiency (SE) enhancement of NOMA system through iterative power assignment

Wireless Networks - This paper studies enhancing non-orthogonal multiple access (NOMA) spectral efficiency (SE) through optimizing the assigned power to each NOMA user depending on their channel...