We present a generalized variational model of an isolated vortex, valid in the anisotropic case when the external magnetic field is along one of the symmetry directions. We discuss the effects of the field anisotropy on the core and magnetic pinning of individual vortices. 相似文献
The aim of the paper is to present a sound, strongly complete and decidable probabilistic temporal logic that can model reasoning about evidence. The formal system developed here is actually a solution of a problem proposed by Halpern and Pucella (J Artif Intell Res 26:1–34, 2006). 相似文献
The quantitative investigation of the radical scavenging properties of polyaniline (PANI) upon reaction with excess of the stable DPPH radical (a 4:1 ratio of DPPH to aniline units in the polymer) was carried out using 15N and 13C solid state NMR spectroscopy. During the process the polyaniline was oxidised so that the imine content increased from 45 to 65%. The extent of oxidation measured by NMR was confirmed by N1s XPS analysis. However, within a 30 min reaction time, about 85% of the DPPH radicals were scavenged as monitored by the decay in its EPR signal. This is about 20 times greater than the fraction of DPPH required to oxidize PANI from an imine content of 45-65%. An identification of further redox processes is required to explain the high degree of radical scavenging. At the same time, there was no evidence of significant chemical binding or trapping of DPPH in the PANI structure. 相似文献
The electrochemical reduction of 2-hydroxy-5-[(4-sulfophenyl)azo]benzoic acid, 2-hydroxy-5-[(3-sulfophenyl)azo]benzoic acid, 2-hydroxy-5-[(2-sulfophenyl)azo]benzoic acid and 2-hydroxy-5-azo-benzoic acid has been carried out in aqueous solutions at glassy carbon electrode using cyclic voltammetry and chronoamperometry. The position of sulfo substituent relative to azo bridge as well as pH of the solution have significant impact on the electrochemical behavior of these compounds. It has been proposed that these compounds are reduced predominantly as hydrazone tautomers resulting in corresponding hydrazo compounds. The overall electrochemical reduction follows DISP2 mechanism, ultimately leading to the 5-amino salicylic acid and sulfanilic acid. The rate determining step is the homogenous redox reaction between intermediate hydrazo compound and 5-amino salicylic acid quinoneimine. The mechanism is proposed in which activated complex of 5-amino salicylic acid quinoneimine and intermediate hydrazo compound is formed with the simultaneous loss of one proton. 相似文献
In this paper, we describe the first practical application of two methods, which bridge the gap between the non-expert user
and machine learning models. The first is a method for explaining classifiers’ predictions, which provides the user with additional
information about the decision-making process of a classifier. The second is a reliability estimation methodology for regression
predictions, which helps the users to decide to what extent to trust a particular prediction. Both methods are successfully
applied to a novel breast cancer recurrence prediction data set and the results are evaluated by expert oncologists. 相似文献
We investigated intrinsic noise in plasmonic sensors caused by adsorption and desorption of gaseous analytes on the sensor
surface. We analyzed a general situation when there is a larger number of different analyte species. We applied our model
to calculate various analyte mixtures, including some environmental pollutants, toxic and dangerous substances. The spectral
density of mean square refractive index fluctuations follows a dependence similar to that of generation-recombination noise
in photodetectors, flat at lower frequencies and sharply decreasing at higher. Some of the calculated noise levels are well
within the detection range of conventional surface plasmon resonance sensors. An AD noise peak is observed in temperature
dependence of mean square refractive index fluctuations, thus sensor operating temperature may be optimized to obtain larger
signal to noise ratio. A significant property of AD noise is its rise with the decreasing plasmon sensor area, which means
that it will be even more pronounced in modern nanoplasmonic devices. Our consideration is valid both for conventional surface
plasmon resonance devices and for general nanoplasmonic devices. 相似文献
Dynamic range of the scene can be significantly wider than the dynamic range of an image because of limitations of A/D conversion. In such a situation, numerous details of the scene cannot be adequately shown on the image. Standard industrial digital cameras are equipped with an auto-exposure function that automatically sets both the aperture value and cameras exposure time. When measuring a scene with atypical distribution of light and dark elements, the indicated auto-exposure time may not be optimal. The aim of work was to improve, with minimal cost, the performance of standard industrial digital cameras. We propose a low complexity method for creating HDR-like image using three images captured with different exposure times. The proposed method consists of three algorithms: (1) algorithm for estimating whether the auto-exposure time is optimal, (2) algorithm which determines exposure times for two additional images (one with shorter and another with longer than auto-exposure time), and (3) algorithm for HDR-like imaging based on fusion of three previously obtained images. Method is implemented on FPGA inserted into standard industrial digital camera. Results show that the proposed approach produces high quality HDR-like scene-mapped 8-bit images with minimal computational cost. All improvements may be noticed through the performance evaluation.