Photocatalytic treatment of water-soluble pesticides by photo-Fenton and TiO2 using solar energy

The technical feasibility and performance of photocatalytic degradation of four water-soluble pesticides (diuron, imidacloprid, formetanate and methomyl) have been studied at pilot scale in two well-defined systems of special interest because natural-solar UV light can be used: heterogeneous photocatalysis with titanium dioxide and homogeneous photocatalysis by photo-Fenton. The pilot plant is made up of compound parabolic collectors (CPCs) specially designed for solar photocatalytic applications. Experimental conditions allowed disappearance of pesticide and degree of mineralisation achieved in the two photocatalytic systems to be compared. In order to assure that the photocatalytic results are consistent, hydrolysis and photolysis tests have been performed with the four pesticides. The initial concentration tested with imidacloprid, formetanate and methomyl was 50 and 30 mg/l with diuron, and the catalyst concentrations were 200 mg/l and 0.05 mM with TiO₂ and iron, respectively. Total disappearance of the parent compounds and 90% mineralisation have been attained with all pesticides tested, methomyl being the most difficult to be degraded with both treatments. First-order rate constants, initial rate, time necessary for mineralising 90% of the initial TOC and hydrogen peroxide consumption were calculated in all cases, enabling comparison both of treatments and of the selected pesticide reactivity.     

Evaluation of dissection of the axilla in modified radical mastectomy

Fifty consecutive unselected patients with infiltrating carcinoma of the breast underwent radical mastectomy in two consecutive stages. The initial operation was a modified radical mastectomy, with preservation of the pectoral muscles, and the second stage, a procedure to transform the initial operation into a standard radical mastectomy. An analysis of the location and the number of the lymph nodes recovered in the two stage operation shows that a so-called modified radical mastectomy is inadequate to ensure the clearing of the axilla. Lymph nodes were recovered at the second stage of the operation in 36 patients, and seven of these patients had metastasis. Modified radical mastectomy was effective in erradicating the lymph nodes of the lower part of the axilla but inadequate for lymph nodes at levels II and III and, especially, the interpectoral lymph nodes.     

Creep and Creep Fracture in Hot-Pressed Alumina

The creep and creep fracture behavior of two hot-pressed aluminas are presented, for both flexural and tensile testing. Steady-state power-law creep is observed with a stress exponent of about 2 for each material. Three distinct fracture regimes are found. At high stress in flexure, fracture occurs by slow crack growth with a high stress dependence of the failure time. At intermediate stresses, in both flexure and tension, creep fracture occurs by multiple microcracking after modest strains. Failure times exhibit a modest stress dependence (stress exponent of 2.5 in tension and 3 in flexure), with a constant failure strain equal to 0.09. The failure times are considerably longer in flexure than in tension, because of the constraint imposed on crack growth by the bending geometry. We conclude that flexure cannot be used for creep lifetime assessment, even in simple, single-phase materials such as Al₂O₃. At low stresses, in tension, failure also exhibits a modest stress dependence but with a much higher failure strain. The material shows the onset of super-plastic behavior.     

Efficient Parallel Graph Algorithms for Coarse-Grained Multicomputers and BSP

In this paper we present deterministic parallel algorithms for the coarse-grained multicomputer (CGM) and bulk synchronous parallel (BSP) models for solving the following well-known graph problems: (1) list ranking, (2) Euler tour construction in a tree, (3) computing the connected components and spanning forest, (4) lowest common ancestor preprocessing, (5) tree contraction and expression tree evaluation, (6) computing an ear decomposition or open ear decomposition, and (7) 2-edge connectivity and biconnectivity (testing and component computation). The algorithms require O(log p) communication rounds with linear sequential work per round (p = no. processors, N = total input size). Each processor creates, during the entire algorithm, messages of total size O(log (p) (N/p)) . The algorithms assume that the local memory per processor (i.e., N/p ) is larger than p ^ε , for some fixed ε > 0 . Our results imply BSP algorithms with O(log p) supersteps, O(g log (p) (N/p)) communication time, and O(log (p) (N/p)) local computation time. It is important to observe that the number of communication rounds/ supersteps obtained in this paper is independent of the problem size, and grows only logarithmically with respect to p . With growing problem size, only the sizes of the messages grow but the total number of messages remains unchanged. Due to the considerable protocol overhead associated with each message transmission, this is an important property. The result for Problem (1) is a considerable improvement over those previously reported. The algorithms for Problems (2)—(7) are the first practically relevant parallel algorithms for these standard graph problems. Received July 5, 2000; revised April 16, 2001.     

3D characterization of intermetallics in a high pressure die cast Mg alloy using focused ion beam tomography

The degree of spatial interconnection of the Mg₁₇Al₁₂ (β-phase) intermetallic in a Mg–9Al–1Zn alloy was assessed through serial sectioning at the centre and near a corner in a casting cross-section. The three dimensional reconstructions showed that the intermetallics were profusely interconnected forming a scaffold-like network over the entire cross-section, but especially near the casting surface. The scale and degree of the interconnection appeared determined by the local concentration of large dendritic grains injected from the shot sleeve. The volume fractions of intermetallics obtained through the 3D reconstruction indicated a higher content of β-phase at the corner regions in comparison with the core. The volume fractions obtained by FIB were consistent with theoretical and experimental values obtained using other techniques.     

Gaming and Augmented Reality Come to Location-Based Services

Recently released mobile phone services include Foursquare and Gowalla, location-based social networking services with a gaming element, and Metro Paris Subway, Yelp, and Urbanspoon, which add augmented-reality features to local-search applications.     

Role of the modular domains of SR proteins in subnuclear localization and alternative splicing specificity

SR proteins are required for constitutive pre-mRNA splicing and also regulate alternative splice site selection in a concentration-dependent manner. They have a modular structure that consists of one or two RNA-recognition motifs (RRMs) and a COOH-terminal arginine/serine-rich domain (RS domain). We have analyzed the role of the individual domains of these closely related proteins in cellular distribution, subnuclear localization, and regulation of alternative splicing in vivo. We observed striking differences in the localization signals present in several human SR proteins. In contrast to earlier studies of RS domains in the Drosophila suppressor-of-white-apricot (SWAP) and Transformer (Tra) alternative splicing factors, we found that the RS domain of SF2/ASF is neither necessary nor sufficient for targeting to the nuclear speckles. Although this RS domain is a nuclear localization signal, subnuclear targeting to the speckles requires at least two of the three constituent domains of SF2/ASF, which contain additive and redundant signals. In contrast, in two SR proteins that have a single RRM (SC35 and SRp20), the RS domain is both necessary and sufficient as a targeting signal to the speckles. We also show that RRM2 of SF2/ASF plays an important role in alternative splicing specificity: deletion of this domain results in a protein that, although active in alternative splicing, has altered specificity in 5' splice site selection. These results demonstrate the modularity of SR proteins and the importance of individual domains for their cellular localization and alternative splicing function in vivo.     

Characterization of CD34+ thymic stromal cells located in the subcapsular cortex of the human thymus

In this paper we report that suspensions of human fetal thymocytes contain cells that express high levels of CD34 and Thy-1. These cells were characterized with regard to location within the thymus, phenotype, and function. Confocal laser scan analysis of frozen sections of fetal thymus with anti-CD34 and Thy-1 antibodies revealed that the double-labeled cells were located in the pericortical area. In addition, it was found that the CD34+Thy-1+ cells lacked CD45 and CD50, indicating that these cells are not of hematopoietic origin; this was confirmed by the finding that these cells could be cultured as adherent cells in a medium with cholera toxin and dexamethasone, but failed to grow in mixtures of hematopoietic growth factors. Further analysis indicated that most cultured CD34+Thy-1+ cells expressed cytokeratin (CK) 14 but lacked CK 13, suggesting that these cells are immature epithelial cells. Cultured CD34+Thy-1+ cells were able to induce differentiation of CD1-CD34+CD3-CD4-CD8- thymic precursors into CD4+CD8+ cells in a reaggregate culture in the absence of exogenous cytokines. The CD4+CD8+ cells that developed in these cultures did not express CD3, indicating that CD34+Thy-1+ thymic stromal cells are not capable of completing full T cell differentiation of thymic hematopoietic progenitor cells.