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1.
Gomes A. C. S. A. Costa L. C. Brito D. C. Frana R. J. Marques Mnica R. C. 《Polymer Bulletin》2020,77(4):1969-1981
Polymer Bulletin - In this study, we synthesized a new ion-imprinted polymer (IIP) based on introduction of amidoxime groups in acrylonitrile, complexation with Cd2+ ions and polymerization with... 相似文献
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Simone Grassi Oscar Campuzano Mnica Coll Francesca Cazzato Georgia Sarquella-Brugada Riccardo Rossi Vincenzo Arena Josep Brugada Ramon Brugada Antonio Oliva 《International journal of molecular sciences》2021,22(8)
Inherited cardiomyopathies are frequent causes of sudden cardiac death (SCD), especially in young patients. Despite at the autopsy they usually have distinctive microscopic and/or macroscopic diagnostic features, their phenotypes may be mild or ambiguous, possibly leading to misdiagnoses or missed diagnoses. In this review, the main differential diagnoses of hypertrophic cardiomyopathy (e.g., athlete’s heart, idiopathic left ventricular hypertrophy), arrhythmogenic cardiomyopathy (e.g., adipositas cordis, myocarditis) and dilated cardiomyopathy (e.g., acquired forms of dilated cardiomyopathy, left ventricular noncompaction) are discussed. Moreover, the diagnostic issues in SCD victims affected by phenotype-negative hypertrophic cardiomyopathy and the relationship between myocardial bridging and hypertrophic cardiomyopathy are analyzed. Finally, the applications/limits of virtopsy and post-mortem genetic testing in this field are discussed, with particular attention to the issues related to the assessment of the significance of the genetic variants. 相似文献
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Marcos de Carvalho Barcellos Alcino Palermo de Aguiar Mônica Regina Marques Palermo de Aguiar Luiz Claudio de Santa Maria 《Polymer Bulletin》2005,55(1-2):61-70
Summary This article deals with the handy synthesis of sulfonyl resins, which were produced by the treatment of a commercial sulfonic resin (Lewatit VPOC1812® based at divinylbenzene (DVB) and styrene (STY). The preliminary chemical modification was based on the reaction of the Lewatit VPOC1812® with thionyl chloride aiming to produce the sulfonyl chloride groups. The best conditions to obtain the sulfonyl chloride groups were: SOCl2/SO3H (molar ratio) =13 at 79 °C during 72 h. The resin chlorinated was afterward treated with urea, thiourea or guanidine. The functionalized resins with urea, thiourea or guanidine were produced with 56, 68 and 93% yield, respectively. The commercial and modified resins were characterized by apparent density, swelling degree, elemental analysis (CHNS), FTIR, optical microscopy (OM) and scanning electron microscopy (SEM). 相似文献
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Jesú s Guardiola Soler Juan J. Prieto Marqu s M nica Garcí a Ruiz Guadalupe Ramos Caicedo 《Chemical Engineering Communications》2003,190(3):285-298
The purpose of the present work is to demonstrate the reliability of a digital image processing technique. A CCD (Charge Coupled Device) is used to perform an investigation on the bubble properties of a 2D gas-solid fluidized bed, and the aim of this study is to establish a criterion in order to reject all images that could not be interpreted as bubbles. This may lead to an alteration of the information obtained. The two-dimensional fluidized bed is 20 cm wide and at least 20 cm high, and the field of view of the camera is 12.54 cm wide and 12.99 cm high. In this way, bubbles could be totally or partially placed into this field of view so that a partial image of a bubble could be analyzed as a whole bubble. With this calibration, a geometric decision criterion for the rejection of nonbubble images was developed. 相似文献
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Erika Carneiro Riqueza Alcino Palermo de Aguiar Luiz Claudio Santa Maria Mônica Regina Marques Palermo de Aguiar 《Polymer Bulletin》2002,48(4-5):407-414
Summary
The preparation of a chelating ion-exchange network based on acrylonitrile was carried out by chemical modification with hydroxylamine.
The beads of resin were synthesized by aqueous suspension copolymerization of acrylonitrile (AN), styrene (STY) and divinylbenzene
(DVB). The influence of diluent used in the suspension polymerization on the structure of the resulting copolymers was evaluated.
The diluents employed were heptane (HEP), toluene (TOL) and anisole (ANI). It was found that the AN incorporation into copolymer
structure was dependent on the diluent used. Conversion of nitrile groups into the amidoxime was conducted by treatment with
hydroxylamine under alkaline solution. The resins were characterized by apparent density, surface area, average pore diameter,
elemental analysis (CHN), FTIR and optical microscopy. Based on the results obtained, it was possible to control the porosity
by diluent employed in the synthesis and to modify chemically a resin containing nitrile groups by hydroxylamine reaction.
Received: 6 October 2001/Revised version: 2 April 2002/ Accepted: 11 April 2002 相似文献
9.
This paper deals with in situ compatibilization of PE/PS blends via Friedel-Crafts reaction, performed at the interphase. Two polyethylenes having different molecular weights, and the same PS, were used along a wide range of catalyst concentration. The influence of the graft copolymer architecture and content on the efficiency of blend compatibilization was studied. The emulsifying effect, morphological aspects and mechanical behavior were also assessed for these blends. The amount of copolymer formed increases with catalyst concentration and the short chain length fraction of the homopolymers. The high molecular weight (MW) copolymers behaved as better compatibilizers as they showed, at the cmc, greater graft copolymer concentration than the low MW ones. A substantial increase in interfacial adhesion and particle size reduction was observed, even at catalyst concentrations as low as 0.3 wt%. In correspondence, mechanical properties, like ductility and yield strength, were enhanced by the effect of this Friedel-Crafts reaction's compatibilization. 相似文献
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The effect of the in situ compatibilization on the mechanical properties of PP/PS blends was investigated. The application of Friedel-Crafts alkylation reaction to the PP/PS-blend compatibilization was assessed. Styrene/AlCl3 was used as catalyst system. The graft copolymer (PP-g-PS) formed at the interphase showed relatively high emulsifying strength. Scission reactions, occurring in parallel with grafting, were verified for PP and PS at high catalyst concentration, but no crosslinking reactions were detected. Tensile tests were performed on dog-bone specimens of the blends. Both elongation at break and toughness increased with catalyst concentration. At 0.7% AlCl3, a maximum was reached, which amounted to five times the value of the property for the uncompatibilized blend. At higher catalyst concentrations these properties decreased along with the PP molecular weight due to chain-scission reactions. On the other hand, the tensile strength did not change with the catalyst concentration. The in situ compatibilized blends showed considerable improvement in mechanical properties, but were adversely affected by chain scissions at high catalyst contents. 相似文献