"牺牲"阳极法合成乙醇钽研究

研究了“牺牲“阳极法电化学合成乙醇钽过程中,添加剂种类与浓度、电解液温度、阴阳极极距和电流密度的影响.选取最佳合成条件为:四甲基氯化铵0.04 mol/L,温度为电解液的沸腾温度,极距约2 cm,电流密度220 A/m2.电合成的混合液经常压蒸馏和减压蒸馏,得到产品用红外光谱、拉曼光谱和元素分析进行表征,确定了产品为乙醇钽.电合成的电流效率大于95%,产品蒸馏时钽的直收率82.8%.     

硫化矿细菌浸出的菌种选育研究进展基金项目

综述了浸出硫化矿的自养菌种筛选与改良的研究进展.指出必须对现有菌种的氧化特性、微生态关系及其群落演替进行深入研究和建立有效的常规育种方法--主要为诱变法,同时结合此法以积累有遗传标志的原材料;指出高温菌种的筛选和基因工程育种是今后的研究方向.     

广东梅州浸矿细菌的选育及对金属硫化矿的浸出

从中国南方典型矿区——广东梅州玉水生物提铜示范基地酸性矿水中分离得到一株金属硫化矿浸出微生物YS-1.对菌株YS-1的形态、生理生化特征、16S rDNA种系序列以及对黄铁矿和铁闪锌矿的浸出等进行了研究.结果表明：细菌长1.0～2.5μm,直径0.4～0.6μm,能运动,革兰氏染色显阴性,最适宜生长的pH和温度分别为2.0和30℃,能利用亚铁盐、单质硫和硫代硫酸钠,不能利用有机能源,与嗜酸氧化亚铁硫杆菌的16S rDNA种系序列同源性达到98%,对铁闪锌矿和黄铁矿的浸出率分别为14.38%和3.8%.     

内配炭锰矿粉团块比电阻的研究

用有机粘结剂成型锰矿粉和焦粉制备内配炭团块，试验研究表明，团块的常温和高温比电阻比块状炉料大，电炉冶炼时有利于电极深插，稳定生产过程。在１８００ｋＶＡ锰铁电炉上配加５０％团块进行生产实践，取得单位电耗下降２０％，锰回收率提高６．９％的显著效果。     

Microbial leaching of marmatite by Acidithiobacillusferrooxidans and Acidithiobacillus thiooxidans

1 Introduction Microbial leaching of metals from sulfide minerals has been practiced over hundreds of years without realizing that microorganisms were involved. Copper, zinc, gold, etc can be recovered from sulfide ores by microbial leaching[1?5]. Zinc s…     

矿物资源加工与生物工程特色信息服务系统的设计及实现

对学术信息服务而言,共享是交流的基础,交流是服务的保障,服务需要建立在一个平台之上。一个开放互连的平台是连接学术科研和生产应用的金桥,是促进学术及学科发展、科技成果转化、科工贸对接的技术基础。该平台能否为学术服务,如何实施服务,以及为学术服务的深度及广度等内容,都与平台的设计与构建过程相关,文章论述了一个学术信息服务平台的设计思路。并对实施过程中的关键问题作了说明。     

Stochastic simulation of growth curves of Acidithiobacillus ferrooxidans

To reveal the low growth rate of Acidithiobacillus ferrooxidans, a stochastic growth model was proposed to analyze growth curves of these bacteria in a batch culture. An algorithm was applied to simulate the bacteria population during lag and exponential phase. The results show that the model moderately fits the experimental data. Further, the mean growth constant （K） of growth curves is obtained by fitting the logarithm of the simulating population data versus the generation numbers with the different initial population number （N0） and initial mean activity of population （A0）. When No is 300 and 700 respectively, the discrepancy of K value is only 0.91%, however, A0 is 0.34 and 0.38 respectively, the discrepancy of K value is 19.53%. It suggests that the effect of A0 on the lag phase exceeds No, though both parameters could shorten the lag phase by increasing their values.     

Electrochemical oxidation of pyrrhotute in aqueous solution

The anodic surface oxidation of natural pyrrhotite in 0.3 mol/L KCI and HCI solution （pH 4.0） and 0.1 mol/L Na2B4O7 solution （pH 9.18） respectively was investigated by using cyclic voltammetry, Tafel plot, and chronoamperometry. In 0.3 mol/L KCl and HCl solution （pH 4.0）, at potential less than 0.5 V（vs SHE）, the production of anodic oxidation on pyrrhotite surface can not maintain a stable phase to form a passive film. In 0.1 mol/L Na2B4O7 solution （pH 9.18）, when the electrode potential increases to more than 0.5 V （vs SHE）, part of S is oxidized to sulfate, making the passive film somewhat porous, but elemental S and metal oxidates Fe（OH）3 still remain on the electrode surface, and the passive film can not be broken down totally. According to PARCalc Tafel analysis, the corresponding corrosion current density （J0） is 5.34 μA/cm^2 , which is also the exchange current density of the oxidation reaction on pyrrhotite electrode surface in 0. 1 mol/L Na2B4O7 solution （pH 9. 18）. The electrochemical dynamics equation of the oxidation was determined.