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1 INTRODUCTIONOrganic intercalatedlayeredsolidshavebeenstudiedbyscientistsindifferentfieldsformanyyearsbecauseoftheirnew physicalandchemicalpropertiessuchaselectricalproperties[1] ,mechanicalproper ties ,thermalbehavior[2 ] ,surfaceandinterfacialproperties[3] .Graphiteoxide (GO)hasbeenstudiedformany years ,itsstructuralmodel[4 6 ] ,formationprocessandkinetics[7,8] havebeenstudiedindetail.IthasbeenreportedthatGOpossessesC OHande poxidefunctionalgroups[9] whichmakegraphiteox ideeasilyabs… 相似文献
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According to control theories, mine fires can be considered as an unsteady process after the normal ventilation system is disturbed. Applied the principal of physical chemistry and thermal fluid mechanics, the parameters models of the unsteady state system have been given, such as fuel combustion rate, heat of combustion, concentration, temperature, heat losses, heat resistance, work of expansion and heat pressure difference. The results of the calculation agree approximately with the results of the test. By the computer simulation, it is shown that the main factor of producing the throttling effect is the fire rate, second is the heat resistance and the heat pressure difference. The rate of heat flow that passes through the airway wall is the maximum on the surface, and decrease with time. The heat transfer progresses only within the range of 0..5 m away from theairway wall during combus-tion for 2 hours. It‘s variable for the mass flux rate and the percentage concentration of the gas along the airway of the downstream. When the delayed time is very small, the varidtion can be neglected. Viscosity resistance is the main part of the heat resistance, second is the expansion resistance that is less than tens Pascal when Mach number is very small. Work of expansion is principally tumed into heat losses, only a very small part is consumed by the work of the heat resistance and the inertia acceleration. 相似文献
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回燃现象的非线性动力学模型 总被引:3,自引:0,他引:3
回燃是在通风受限的建筑火灾进入缺氧燃烧甚至闷烧后,由于新鲜空气的突然大量补充引热烟气急剧燃烧的现象,这种转捩现象是典型的非线性行为。利用能量平衡原理建立了建筑火灾中回燃现象的简化数学模型,并利用非线性动力学中的突变原理分析其突变机理。结果表明,回燃现象是一种典型的突变行为,具有突变的一般特性。 相似文献
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