Characterization of magnetic materials using a scanning microwave microprobe

We investigated the electromagnetic properties of metals of iron, nickel, cobalt, aluminum, gold, copper, silver, and permalloy thin films on SiO(2) substrates using a near-field microwave microprobe. The electromagnetic properties of metal sheets were estimated by measuring the microwave reflection coefficient S(11) and compared with the theoretical values. We observed the hysteresis behavior of permalloy thin films on SiO(2) substrates using a near-field scanning microwave microprobes (NSMM) system. Experimental results are in good agreement with the theoretical model of transmission theory. In order to better characterize the electromagnetic properties of metals and magnetic metals instead of the usual method, we take advantage of the noncontact microprobing evaluation capabilities using a near-field microwave.     

The technology and electrical characteristics of ceramics based on hydroxylapatite

In this paper, we have examined the synthesis and structure of hydroxylapatite and methods for obtaining a dense and porous hydroxylapatite, as well as methods for producing a dense and porous HA-based ceramics. The temperature dependence of conductivity and dielectric loss tangent of hydroxylapatite were investigated.     

Characterization of the field-effect conductivity distribution in pentacene thin-film transistors by a near-field scanning microwave microscope

Direct probing of the conductivity distribution in organic materials is motivated by the need to obtain a deeper understanding of carrier behavior in organic thin-film transistors (OTFT), organic electro-luminescent devices, organic photoconductors, and organic biosensors. Here we used a near-field scanning microwave microscope to visualize conductivity profiles in OTFT channel. Applying this technique to pentacene field-effect transistors has revealed changes of the conductivity distribution in the channel arising from the development and exhaustion of an accumulated charge region. The electric field profiles, the complementary image of conductivity profiles, which are visualized by using an optical second harmonic generation method, support the results. We anticipate that direct observation by this microwave method will find wide application in measurement of carrier conductivity in organic and nonorganic materials.     

Design of an individually controlled system for an optimal thermal microenvironment

Individually controlled microenvironment has potential to satisfy more occupants in a space compared to a total volume uniform environment typically used at present. The performance of an individually controlled system comprising a convection-heated chair, an under-desk radiant heating panel, a floor radiant heating panel, an under-desk air terminal device supplying cool air, and a desk-mounted personalized ventilation as used and identified by 48 human subjects was studied using a thermal manikin at room temperatures of 20 °C, 22 °C and 26 °C. At a room air temperature of 20 °C, the maximum whole-body heating effect of the heating chair, the under-desk heating panel, and the floor heating panel corresponded to the effect of a room temperature increase of 5.2 °C, 2.8 °C, and 2.1 °C, respectively. The effect was 5.9 °C for the combination of the three heating options. The higher the room air temperature, the lower the heating effect of each heating option or heating combination. The maximum whole-body cooling effect of the tested system was only −0.8 °C at a room air temperature of 26 °C. The heating and cooling capacity of the individually controlled system were identified. These results, analyzed together with results obtained from human subject experiments, reveal that both the heating and the cooling capacity of the individually controlled system need to be increased in order to satisfy most occupants in practice.     

Performance of “ductless” personalized ventilation in conjunction with displacement ventilation: Impact of intake height

The importance of the intake positioning height above the floor level on the performance of “ductless” personalized ventilation (“ductless” PV) in conjunction with displacement ventilation (DV) was examined with regard to the quality of inhaled air and of the thermal comfort provided. A typical office room with two workstations positioned one behind the other was arranged in a full-scale room. Each workstation consisted of a table with an installed “ductless” PV system, PC, desk lamp and seated breathing thermal manikin. The “ductless” PV system sucked the clean and cool displacement air supplied over the floor at four different heights, i.e. 2, 5, 10 and 20 cm and transported it direct to the breathing level. Moreover, two displacement airflow rates were used with a supply temperature adjusted in order to maintain an exhaust air temperature of 26 °C. Two pollution sources, namely air exhaled by one of the manikins and passive pollution on the table in front of the same manikin were simulated by constant dosing of tracer gases. The results show that the positioning of a “ductless” PV intake height up to 0.2 m above the floor will not significantly influence the quality of inhaled air and thermal comfort.     

Ceiling mounted personalized ventilation system in hot and humid climate—An energy analysis

This study is to evaluate energy saving potential of ceiling mounted personalized ventilation (PV) system in conjunction with background mixing ventilation compared with mixing ventilation system alone and with mixing ventilation system when occupants are provided with individually controlled desk fans for generating additional air movement at each desk. Control strategy applied includes different number of personalized ventilation air terminal devices used and different PV airflow rates supplied. Energy calculation is based on design conditions in Singapore, representing a hot and humid climate. The results reveal that increasing room temperature can save cooling energy when the combination of PV with ceiling mounted personalized ventilation nozzles and background mixing ventilation is used. In this case the energy for transport of air increases but the total energy decreases, i.e. energy can be saved due to elevated room temperature. Comparing with mixing ventilation plus desk fans, ceiling mounted personalized ventilation cannot only realize better cooling effect but also decrease the total energy consumption.     

Characterization of rubrene polycrystalline thin film transistors fabricated using various heat-treatment conditions

We observed the crystal structure changes of rubrene (5,6,11,12-tetraphenylnaphthacene) polycrystal thin films on SiO₂/Si(100) substrates at various heat-treatment temperatures by X-ray diffraction, and a near-field microwave microprobe technique. An amorphous rubrene thin film was initially observed at heat-treatment temperature of 35 °C. After the treatment with in-situ vacuum post-annealing at 80 °C for 22 h, the rubrene thin film was transformed from the amorphous phase into a crystalline phase of orthorhombic structure. We could obtain a higher field effect mobility of 0.047 cm²/V·s and lower threshold voltage of − 4 V for the following heat-treatment process: pre-annealing at 80 °C, cooling at 40 °C, and post-annealing at 80 °C for 22 h.     

Reflectance reduction of InP wafers after high-temperature annealing

Broadband reduction of light reflection from the surface of InP wafers after high-temperature annealing in air has been observed. In the transparency region of the material, the reflection drop is accompanied by increasing transmission of light through the wafer. The spectral position of a deep minimum of the reflection coefficient can be tuned, by varying the temperature and the time of annealing, in a wide spectral range from ultraviolet to infrared. The effect is due to formation of thermal oxide layers on the surfaces of the wafer with optical parameters favorable for antireflection.     

Chemistry, biology, and QSAR studies of substituted biaryl hydroxamates and mercaptoacetamides as HDAC inhibitors-nanomolar-potency inhibitors of pancreatic cancer cell growth

The histone deacetylases (HDACs) are able to regulate gene expression, and inhibitors of the HDACs (HDACIs) hold promise in the treatment of cancer as well as a variety of neurodegenerative diseases. To investigate the potential for isoform selectivity in the inhibition of HDACs, we prepared a small series of 2,4'-diaminobiphenyl ligands functionalized at the para-amino group with an appendage containing either a hydroxamate or a mercaptoacetamide group and coupled to an amino acid residue at the ortho-amino group. A smaller series of substituted phenylthiazoles was also explored. Some of these newly synthesized ligands show low-nanomolar potency in HDAC inhibition assays and display micromolar to low-nanomolar IC(50) values in tests against five pancreatic cancer cell lines. The isoform selectivity of these ligands for class I HDACs (HDAC1-3 and 8) and class IIb HDACs (HDAC6 and 10) together with QSAR studies of their correlation with lipophilicity are presented. Of particular interest is the selectivity of the mercaptoacetamides for HDAC6.     

Influence of pulmonary ventilation rate and breathing cycle period on the risk of cross‐infection

This study examined the characteristics of the exhaled airflow pattern and breathing cycle period of human subjects and evaluated the influence of pulmonary ventilation rate and breathing cycle period on the risk of cross‐infection. Measurements with five human subjects and a breathing thermal manikin were performed, and the peak exhaled airflow velocity from the mouth and the breathing cycle period were measured. Experiments on cross‐infection between two breathing thermal manikins were then conducted in a full‐scale test room, in which the pulmonary ventilation rate and breathing cycle period were varied systematically. Both peak flow velocity and breathing cycle length varied considerably between different subjects. The breathing cycle period in a standing posture was 18.9% lower than in a sitting posture. The influence of pulmonary ventilation rate and breathing cycle period extended up to a separation distance of 1.0 m between the two manikins. Increasing the pulmonary ventilation rate of the exposed person greatly increased the risk of cross‐infection. Decreasing the breathing cycle period from the widely used “6 second” value led to a considerable increase in the risk of cross‐infection. Standing posture resulted in a higher risk of cross‐infection than sitting posture.