Ionic liquid-based deep eutectic solvents as novel solvent-cum-catalyst media for thermal dehydrogenation of chemical hydrides

The current work explores the usage of novel synthesized Deep Eutectic Solvent (DES) as a catalyst cum solvent media for the thermal dehydrogenation of chemical hydrides, namely Ammonia Borane (AB) and Ethylene diamine bisborane (EDAB). In the first instance, the quantum chemistry based COSMO-SAC (COnductor like Screening MOdel Segment Activity Coefficient) model was used for the selection of the pertinent solvent. 1-Butyl-3-methylimidazolium methanesulfonate: Imidazole ([BMIM][MeSO₃]:[Im]) turned out to be an ideal eutectic mixture with the highest predicted solubility with amine boranes. The DES was synthesized by combining the Hydrogen Bond Acceptor (HBA), namely 1-Butyl-3-methylimidazolium methanesulfonate and Imidazole as Hydrogen Bond Donor (HBD) at a molar ratio of 1:2 and T = 70 °C. The formation of DES was confirmed by recording the NMR spectra. Further, the thermal dehydrogenation study was performed at a vacuum of 4 × 10^?2 mbar (gauge pressure) of AB/DES and EDAB/DES systems at 105 °C, where a hydrogen equivalent of 1.40 and 2.55 was produced, respectively. The residual samples were further analyzed through ¹H NMR analysis for the reaction mechanism and to confirm the role of Ionic Liquid-based DES as catalyst cum solvent media.     

SYNTHESIS AND CHARACTERIZATION OF CONTROLLED SIZES: POLYSTYRENE LATEXES

Several parameters and their limitations to prepare monodisperse polystyrene particles were discussed. Polystyrene latexes B, C and D of diameter 129.8, 142.8 and 264.5 nm, respectively, were synthesized by emulsion polymerization method. The latex D is almost monodisperse with very low polydispersity of 0.005 while B and C are having polydispersity of 0.1837 and 0.1601. The particle size and particle size distribution of the latexes were determined by a TEM and Brookhaven particle size analyzer. It was observed that the particle size of the latexes decreased with increasing initiator (ammonium persulfate) or surfactant (SDS) concentrations. The surface area of the latexes were calculated by using BET equation on the basis of the amount of nitrogen gas adsorbed at the surface of the particles to form a monolayer. It was observed that the surface area of latex D is less than B and C because of the bigger size of the particles. The average molecular weights, zeta potentials and densities of the latexes were also presented.     

Survey of GPU Based Sorting Algorithms

Parallel sorting algorithms are widely studied nowadays. After the introduction of parallel processors such as graphics processing unit (GPU) and easy to use parallel programming languages such as CUDA and OpenCL, literature on parallel sorting algorithms has become vast and richer with new ideas and techniques applied to solve the famous problem of sorting. This paper presents a survey of GPU based sorting algorithms. Four sorting algorithms have been selected for this survey: Radix sort, Merge sort, Sample sort and Quick sort. Methods used in those algorithms are described in brief. The performance of these algorithms as claimed by their authors is also presented. A comparative analysis based on the literature is depicted.     

Single pole compact narrow band pass filter using periodic ground defects

In this paper a compact narrow band pass filter has been designed. An H-shape section of microstrip is used to get the smaller band width. The parallel lines are connected to the H section. The periodic slots are made on the ground plane of the microstrip. These defects cause the circuit more compact. The filter has been designed for center frequency 4 GHz and fractional band width 3%. The design methodology has been clearly explained. To verify the proposed technique, a filter has been fabricated and tested. Amoderate matching of the results between the measured and simulated results has been observed due to some imperfection in fabrication.     

Groundwater Situation in India: Problems and Perspective

Overexploitation of groundwater and intensive irrigation in major canal commands has posed serious problems for groundwater managers in India. Depletion of water tables, saltwater encroachment, drying of aquifers, groundwater pollution, water logging and salinity, etc. are major consequences of overexploitation and intensive irrigation. It has been reported that in many parts of the country the water table is declining at the rate of 1-2 m/year. At the same time in some canal commands, the water table rise is as high as 1 m/year. Deterioration in groundwater quality by various causes is another serious issue. Increased arsenic content in shallow aquifers of West Bengal reported recently has created panic among the groundwater users. Summed together, all these issues are expected to reduce the fresh water availability for irrigation, domestic and industrial uses. If this trend continues unchecked, India is going to face a major water crisis in the near future. Realizing this, the Government of India has initiated several protective and legislative measures to overcome the groundwater management-related problems but, due to the lack of awareness and political and administrative will, none of the measures has made any significant impact. This paper highlights the critical issues and examines the various schemes related to groundwater development and management.     

Studies on effect of nanoclay on the properties of thermally sprayable EVA and EVAI coatings

Dispersion of nanoclay (NC) in polymer blend system is governed by the sequence of addition of different ingredients. In the present work nanoclay was added in different sequences to blend composition such as ethylene vinyl acetate (EVA)/low density polyethylene (LDPE) and ethylene vinyl alcohol (EVAl)/LDPE in internal mixer to get nanocomposite. It was found that sequential addition of individual polymers and nanoclay influenced mechanical properties of resulting composites. Blending sequence of PE/NC/EVA and PE/NC/EVAl gave best mechanical properties. After optimization of addition sequence, concentration of nanoclay was varied from 1 to 8% by weight in the polymer blend. The resulting composites were evaluated in terms of their mechanical properties, dispersion characteristics (XRD), water vapor transmission rate (WVTR) and water absorption (Wa). Nanocomposite containing EVA/LDPE blend with 4% nanoclay showed optimum properties. The optimized composition was applied on grit blasted mild steel specimens by flame spray technique. The coated specimens were evaluated for adhesion strength, abrasion resistance and resistance to corrosion properties.     

A modified intuitionistic fuzzy c-means clustering approach to segment human brain MRI image

Multimedia Tools and Applications - Fuzzy c-means (FCM) is one of the prominent method utilized for medical image segmentation. In literature intuitionistic fuzzy c-means (IFCM) is suggested which...     

ON THE PERFORMANCE ANALYSIS OF FLEXIBLE MAGNETIC ABRASIVE BRUSH

Magnetic abrasive finishing (MAF) of alloy steel workpiece with unbounded magnetic abrasive particles (UMAPs) indicates that the surface finish in the range of nanometer can be achieved. Important controllable four process parameters have been identified which are as current to the electromagnet, machining gap, abrasive size (mesh number), and number of cycles. Experiments have been planned using design of experiments technique. Based upon the results of response surface methodology and analysis of variance (ANOVA), it is concluded that magnetic flux density that depends on current to the electromagnet and machining gap, is most influencing parameter followed by grain size and number of cycles. The surface roughness profile generated during the MAF process has been discussed. To understand the cutting mechanism of magnetic abrasive finishing process, scanning electron microscopy (SEM) and atomic force microscopy (AFM) of the machined surfaces have been carried out. The correlation between surface finish and material removal has also been established.     

Preparation and characterization of microcapsules containing linseed oil and its use in self-healing coatings

Effectiveness of linseed oil filled microcapsules was investigated for healing of cracks generated in paint/coatings. Microcapsules were prepared by in situ polymerization of urea–formaldehyde resin to form shell over linseed oil droplets. Characteristics of these capsules were studied by FTIR, TGA/DSC, scanning electron microscope (SEM) and particle size analyzer. Mechanical stability was determined by stirring microcapsules in different solvents and resin solutions. Cracks in a paint film were successfully healed when linseed oil was released from microcapsules ruptured under simulated mechanical action. Linseed oil healed area was found to prevent corrosion of the substrate.