Mass Transfer in Molybdenum Extraction from Aqueous Solutions Using Nanoporous Membranes

Modeling of non‐disperse solvent extraction of molybdenum(VI) with PC‐88A as extractant and a nanoporous hollow‐fiber membrane contactor as extractor was performed. Computational fluid dynamics was applied for modeling and simulation of molybdenum extraction. Concentration, pressure, and velocity distributions for molybdenum were determined. The extraction of Mo⁶⁺ was greatly influenced by the flow rate of feed solution. The extraction efficiency was reduced with higher feed flow rate and increased with the molybdenum content in the feed. The pressure drop along the shell side of the membrane extractor was found to be not significant, being one of the advantages of membrane extractors which assist in reducing the operational costs. The proposed simulation method is capable to prognosticate the performance of solvent extraction of molybdenum in membrane extractors.     

DIRECT DESIGN OF SHAPE

Designers often need to find the shape of body that achieves specified design objectives. The classic problem of this type is to find the airfoil shape that leads to the desired distribution of surface pressure. This article describes a method for solving such problems that is inexpensive, robust, and a simple extension to existing computational fluid dynamics methods; it permits the body shape to be calculated directly, by including the coordinates of the body as dependent variables in the problem formulation. The method described is applicable to many problems in thermofluids, but it is demonstrated here only for heat conduction problems.     

Black Nickel Coating and Color Anodized Layers for Solar Absorber

Solar selective absorbers are considered as an essential part of a thermal solar collector for which the optical properties are dependent upon their structure and surface morphology. In this paper, optical properties of Ni-pigmented anodized are compared with black electroless nickel coatings. The effect of heat treatment on optical properties of the coatings was also investigated. Anodized films were formed in 6 M phosphoric acid followed by a black coloration process. Scanning electron microscope was used to study the morphology, and X-ray diffraction was employed to identify the phases present. Evaluation of optical properties was carried out by spectral reflectance. Evaluation of the optical characteristics showed that Ni-pigmented anodized and black electroless samples, after heat treatment, had the highest absorption coefficient at about 0.98 as well as the lowest emission coefficient. The ξ factor reached about 6 in heat treated Ni-pigmented anodized layer and offered optimal properties in this research.     

Preparation and functional properties of fish gelatin–chitosan blend edible films

With the goal of improving the physico-chemical performance of fish gelatin-based films, composite films were prepared with increasing concentrations of chitosan (Ch) (100G:0Ch, 80G:20Ch, 70G:30Ch, 60G:40Ch and 0G:100Ch, gelatin:Ch), and some of their main physical and functional properties were characterised. The results indicated that the addition of Ch caused significant increase (p < 0.05) in the tensile strength (TS) and elastic modulus, leading to stronger films as compared with gelatin film, but significantly (p < 0.05) decreased the elongation at break. Ch drastically reduced the water vapour permeability (WVP) and solubility of gelatin films, as this decline for the blend film with a 60:40 ratio has been of about 50% (p < 0.05). The light barrier measurements present low values of transparency at 600 nm of the gelatin–chitosan films, indicating that films are very transparent while they have excellent barrier properties against UV light. The structural properties investigated by FTIR and DSC showed a clear interaction between fish gelatin and Ch, forming a new material with enhanced mechanical properties.     

Dissimilar welding of AISI 310 austenitic stainless steel to nickel-based alloy Inconel 657

The current work was carried out to characterize welding of AISI 310 austenitic stainless steel to Inconel 657 nickel–chromium superalloy. The welds were produced using four types of filler materials; the nickel-based corresponding to Inconel 82, Inconel A, Inconel 617 and 310 austenitic stainless steels. This paper describes the selection of welding consumables for the joint. The comparative evaluation was based on hot-cracking tests (Varestraint test) and estimation of mechanical properties. According to Varestraint tests, Inconel A showed the least susceptibility to hot cracking. In tension tests, all weldments failed in the weaker parent metals (i.e., Inconel 657). Moreover, Inconel A weldment had the highest strength and total elongation. On the other hand, the weld metals failed by ductile fracture except Inconel 617, which exhibited mixed fracture mode. At last, it was concluded that Inconel A filler material offered the best compromise for the joint between Inconel 657 and 310 stainless steel.     

Formation and Characterization of Titanium Modif Aluminide Coatings on IN738LC

HISTORICALLY superalloys have been used in gasturbine applications with a protective coating to combatoxidation problems in aero engines and hot corrosionproblems in industrial and marine engines.Theprotective coatings used are predominantly of thediffusion type produced by variety of techniques suchas pack cementation,chemical vapor deposition,slurryfusion and hot dipping[1,2].The purpose of this typeof coatings is to increase the amount of Al at thesurface of a component,so that a protec…     

A novel modified lattice Boltzmann method for simulation of gas flows in wide range of Knudsen number

To cover a wide range of the flow regimes, a new relaxation time formulation by considering the rarefaction effect and the effective dynamic viscosity has been obtained. By using the modified lattice Boltzmann method (LBM), pressure driven flow through micro and nano channels has been modeled for wide range of Knudsen number, Kn, covering the slip, transition and to some extent the free molecular regimes. The results agree very well with existing empirical and numerical data. The velocity profile was predicted as well as the volumetric flow rate and for the first time, the well known Knudsen minimum effect has been captured about Kn = 1.     

The Effect of Precarburizing Treatment on Morphology of the Boride Layer

Structural steel samples were boronized with a newly introduced boronizing pack containing boric acid (H₃BO₄), cryolite (Na₃B₄O₇), aluminum and aluminum oxide (Al₂O₃). In this research, the effect of precarburizing treatment on the morphology of the boride layer was studied and compared with unprecarburized specimens. The treated specimens were characterized using SEM, x-ray diffractometry, ED AX and microhardness tester. The results indicate that the boride layers are constituted by Fe₂B in either case. It has also been found that with precarburized specimens, the thickness of boride layer has been reduced and its morphology changed to a more flat structure.