钨在铂电极上成核动力学研究

采用循环伏安法和计时电流法研究了钨在ＫＦ－Ｂ２Ｏ３－Ｋ２ＷＯ４（６２－３７－１ｍ／ｏ）熔体中（Ｔ＝７９５℃）铂电极上成核动力学过程。实验结果表明：该过程符合扩散步骤控制的半球形三维晶核连续成核长大的动力学规律。     

SOME THERMODYNAMIC PROPERTIES IN PROCESS OF THERMAL REDUCTION OF Mg WITH HIGH AI ALLOY

本文以含高Al(Al76％,Si18.9％,Fe5.1％)的Al-Si-Fe合金为还原剂,在不同温度下进行热法还原Mg实验,测定了Mg的蒸气压为lgp_(Mg)=-8853/T+10.58.与用Si-Fe还原剂相比,在相同的p_(Mg)下,还原温度可下降约200℃。 用Bonnier法和本实验所测定的数据计算了Al-Si-Fe合金在不同温度下各组元的活度。结果表明,三元系中各组元活度均有负偏差,尤其Fe的偏差很大。另外,由以上所得的活度数据还计算了还原反应的平衡常数和热焓,分别为: lgK_[Al]=-18.40×10~4/T+117.2,ΔH=3529.5KJ     

CALCULATION OF PHASE DIAGRAM FOR PSEUDOBINARY GaAs-InAs

ＣＡＬＣＵＬＡＴＩＯＮＯＦＰＨＡＳＥＤＩＡＧＲＡＭＦＯＲＰＳＥＵＤＯＢＩＮＡＲＹＧａＡｓ－ＩｎＡｓ￥Ｑｉａｏ，Ｈｕａｎ；Ｓｈｅｎ，Ｊｉａｎｙｕｎ；Ｌｉ，Ｇｕｏｘｕｎ（ＧｅｎｅｒａｌＲｅｓｅａｒｃｈＩｎｓｔｉｔｕｔｅｆｏｒＮｏｎｆｅｒｒｏｕｓＭｅｔａｌ...     

热处理对La_(0.9)Nd_(0.1)(NiCoMnAl)_5电极性能的影响

研究了热处理对Ｌａ０．９Ｎｄ０．１（ＮｉＣｏＭｎＡｌ）５电极材料结构、成分、脱氢压力－组成等温曲线（ＰＣＴ）、循环寿命的影响。Ｘ射线衍射结果表明热处理降低了评价主相峰的半高宽（ＦＷＨＭ）平均值，即降低了晶格应力。采用ＪＳＭ－８４０能谱分析仪对热处理前后合金成分进行分析，发现热处理使得合金中的Ｌａ、Ｍｎ向晶内扩散，而Ｎｉ、Ｃｏ、Ａｌ却向晶界偏聚。测定了室温下热处理前后的合金脱氢ＰＣＴ曲线及其电极循环寿命曲线，结果表明热处理使电极放电容量有所降低，同时却又使电极循环寿命有所提高，并且还降低了合金平衡压。     

Mechanical and dielectric properties of functionalized boron nitride nanosheets/silicon nitride composites

Uniformly dispersed boron nitride nanosheets (BNNSs) reinforced silicon nitride (Si₃N₄) composites were prepared by surface modification assisted flocculation combined with SPS sintering. In order to improve the dispersibility of the BNNSs in the composites, the liquid phase stripped BNNSs are surface functionalized by a two-step covalently modification. The amino-modified BNNSs (NH₂-BNNSs) and Si₃N₄ powders have opposite surface potential, mixed evenly by electrostatic interaction during flocculation. The results showed that mechanical properties of Si₃N₄ composites were obviously enhanced by adding NH₂-BNNSs. The fracture toughness and bending strength of Si₃N₄ composites added 0.75 wt% NH₂-BNNSs were increased by 34% and 28%, respectively, compared with monolithic Si₃N₄. Toughening mechanisms are synergistic action of the torn, pull-out or bridging of BNNSs and crack deflection mechanisms with microstructural analyzes. The dielectric properties of the Si₃N₄ ceramics are also improved after the addition of NH₂-BNNSs.     

Simultaneous Photoacoustic Spectroscopy of Aerosol and Oxygen A-Band Absorption for the Calibration of Aerosol Light Absorption Measurements

ABSTRACT

The calibration of photoacoustic aerosol optical absorption measurements through simultaneous photoacoustic spectroscopy of the oxygen A-band absorption is demonstrated. While aerosol absorption shows no sharp spectral structures for size-distributed aerosols, the molecular oxygen A-band has sharp absorption lines in the near-infrared (i.e., 760–770 nm) spectral region. Line-strength, shape, and broadening of these lines are well known and molecular oxygen is ubiquitous with a constant concentration in the troposphere. Simultaneous photoacoustic spectroscopy of aerosol and molecular oxygen A-band absorption with a tunable, external cavity diode laser yields a convenient calibration for the photoacoustic measurement of aerosol absorption coefficients without the need for pressurized and potentially toxic calibration gases.     

平行分度凸轮机构的三维造型设计及其动态模拟

本文运用计算机辅助工业设计阐述了平行分度凸轮机的机构参数的选择、廓线的计算、三维造型设计及其动态模拟等ＣＡＤ的理论和方法。     

滚子齿式空间分度凸轮机构的研究

本文以微分几何和空间旋转矩阵算子理论为数学工具,应用空间曲面啮合原理,对滚子齿式空间分度凸轮机构进行了系统的研究。推导了凸轮轮廓曲面方程、啮合方程和压力角计算公式,并对凸轮曲面的曲率进行了分析,给出了主曲率、诱导主曲率等一系列计算公式,最后给出了凸轮工作曲面产生根切的判别条件。     

焦作市SO_2污染状况及防治对策

介绍了焦作市当前SO2污染的状况及污染特点.通过分析SO2的形成,指出燃煤锅炉是SO2产生的主要原因,此外,窑炉及茶炉也产生了部分SO2.在此基础上,提出了治理SO2的一个比较具体的工作流程以及相应的措施与对策.即从燃料及其燃烧过程中固硫,减少燃烧造成的SO2排放量的增加.另外,对开发新能源也会减轻焦作市SO2的污染.     

液压、气动通用逻辑回路的计算机辅助设计

本文以逻辑代数和离散数学中的立方符号法为数学工具，把计算机辅助逻辑综合的理论和方法引入到液压、气动逻辑回路设计领域，并根据液压、气动逻辑回路设计的特点，建立了一套适合于机助逻辑综合的液、气通用的数学模型，提出了建立通用数学模型的方法和规则，首次在微机上开发出了液、气通用的计算机逻辑综合软件ＣＡＬＤ