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1.
High-voltage atmospheric cold plasma (HVACP) treatment generates reactive gas species that induce inter- and intramolecular reactions in soybean oil. The goal of this study is to analyze the effect of HVACP treatment on the chemical structure of soybean oil in a hydrogen gas environment at atmospheric pressure. HVACP was used to treat soybean oil (15 g) for up to 6 hours by triplicate. Plasma-generated reactive gas species interact with the sample, producing three distinct fractions identified as a liquid, gel, and solid. Fatty acid profile, Fourier-transform infrared spectroscopy, proton and carbon nuclear magnetic resonance, size-exclusion chromatography, thermal properties, and peroxide value were used to characterize the chemical structure. Results indicated a lower content of polyunsaturated fatty acids, increased content of saturated fatty acids, and the presence of isomers. An insoluble portion was observed in the solid fraction and increased with treatment time up to 42% in the 6-h treated samples. Plasma species may cause two main reactions: polymerization and hydrogenation.  相似文献   
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IEEE 802.11 wireless local area networks (WLANs) have reached an important stage and become a common technology for wireless access due to its low cost, ease of deployment, and mobility support. In parallel with the extensive growth of WLANs, the development of an efficient medium access control protocol that provides both high throughput performance for data traffic and quality of service support for real‐time applications has become a major focus in WLAN research. The IEEE 802.11 Distributed Coordination Functions (DCF/EDCA) provide contention‐based distributed channel access mechanisms for stations to share the wireless medium. However, performance of these mechanisms may drop dramatically because of high collision probabilities as the number of active stations increases. In this paper, we propose an adaptive collision‐free MAC adaptation. The proposed scheme prevents collisions and allows stations to enter the collision‐free state regardless of the traffic load (saturated or unsaturated) and the number of stations on the medium. Simulation results show that the proposed scheme dramatically enhances the overall throughput and supports quality of service for real‐time services over 802.11‐based WLANs. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
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In this paper, we present a new Quality of Service (QoS) routing model for Differentiated Services (Diffserv) over Multiprotocol Label Switching (MPLS) networks. We use a pre-established multi-path model in which several MPLS label switching paths (LSPs) are established between each ingress-egress router pair in advance. Ingress routers perform per-request admission control and bulk-type resource reservation based on the resource availability on the associated LSPs. We use a utilization-based dynamic load balancing scheme to increase resource utilization across LSPs. The proposed model increases signaling and state scalability in the network core. It also provides hard QoS guarantees and minimizes admission control time. The experimental results verify the achievements of our model under various network topologies and traffic conditions.  相似文献   
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We have investigated the toxicity of dose-escalation of BCNU, etoposide and melphalan ('BEM') chemotherapy with autologous stem cell transplantation in patients with haematological malignancies. Seventy-two patients with haematological malignancies were treated with BCNU (600 mg/m2, 450 mg/m2 or 300 mg/m2), etoposide 2 g/m2 and melphalan 140 mg/m2 followed by autologous bone marrow transplantation (ABMT), n = 51, or autologous peripheral blood progenitor cell transplantation (APBPCT), n = 21. Liver and pulmonary function was monitored pretransplant and at regular intervals post-transplant. Mucositis was graded daily during in-patient stay. There was a significantly higher incidence of symptomatic pulmonary toxicity in the patients who received BCNU at 600 mg/m2 than in the other two groups, and there was a significant increase in the incidence of asymptomatic decrease in carbon monoxide (KCO) in the patients who received BCNU 450 mg/m2. There was no significant difference between the three groups in the incidence and severity of mucositis or in the incidence of transiently abnormal liver function. We conclude that etoposide at 2 g/m2 can be used without unacceptable mucositis. BCNU at 600 mg/m2 is associated with an unacceptably high incidence of lung toxicity, but at 450 mg/m2 there is minimal symptomatic lung toxicity.  相似文献   
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Bandwidth brokers (BBs) have been proposed for providing end‐to‐end quality of services (QoS) in differentiated services (Diffserv) networks. As a single entity in each domain, a BB aims at performing both intra‐ and inter‐domain resource management on behalf of its domain. There have been plenty of BB studies for intra‐domain resource management. However, how a BB can perform inter‐domain resource management in a scalable and deployable manner is still an open issue. In this work, we present the design, implementation and evaluation of an inter‐BB communication protocol that is used by each BB to communicate with its neighboring BBs for inter‐domain QoS resource management. The proposed model uses a destination‐based aggregation scheme in which reservations are aggregated as they merge through the destination region. The destination‐based aggregation improves inter‐domain state and signaling scalability. The protocol also performs traffic engineering to increase inter‐domain resource utilization. The implementation and simulation results verify the achievements of our model. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
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This study intends to produce plasma polymer thin films of γ-glycidoxypropyltrimethoxysilane (γ-GPS) on glass fibers in order to improve interfacial adhesion of glass fiber-reinforced epoxy composites. A low frequency (LF) plasma generator was used for the plasma polymerization of γ-GPS on the surface of glass fibers at different plasma powers and exposure times. X-ray photoelectron spectroscopy (XPS) and SEM analyses of plasma polymerized glass fibers were conducted to obtain some information about surface properties of glass fibers. Interlaminar shear strength (ILSS) values and interfacial shear strength (IFSS) of composites reinforced with plasma polymerized glass fiber were evaluated. The ILSS and IFSS values of non-plasma polymerized glass fiber-reinforced epoxy composite were increased 110 and 53%, respectively, after plasma polymerization of γ-GPS at a plasma power of 60 W for 30 min. The improvement of interfacial adhesion was also confirmed by SEM observations of fractured surface of the composites.  相似文献   
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Composites made from epoxy resins (ERs) are one of the important polymer groups used in different industries due to their good mechanical and thermal properties. Many attempts have been done to improve both the mechanical and the thermal properties of ER composites and to lower the cost of ER composites with addition of inexpensive fillers such as calcium carbonate, kaolin clays, silica, talc, etc. In this study novel lateritic ore (LO) filler was used in diglycidyl ether of bisphenol A‐type ER. Different addition percentages (5–20%) of both natural LO (nLO) and modified LO (mLO) into ER were tested to determine the influence on mechanical and thermal properties of newly produced composites. Surface hardness, Young's modulus, tensile strength, elongation at break, water sorption, adhesion, and thermal stability of composites were determined and were compared with pure ER. Results showed that the addition of nLO/mLO has positive effect on mechanical and thermal properties. Morphological characterization by scanning electron microscopy and structural characterization by X‐ray diffraction revealed that addition nLO/mLO distributed homogenously throughout the composites. POLYM. COMPOS. 34:1375–1381, 2013. © 2013 Society of Plastics Engineers  相似文献   
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Polymer Bulletin - Drug carrier, poly(maleic anhydride-co-vinyl acetate) (MAVA or poly[MA-co-VA]) copolymer, was traditionally synthesized by free radical chain polymerization reaction, in methyl...  相似文献   
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