Understanding the Corrosion Inhibition Mechanism of Mild Steel in Hydrochloric Acid by a Triazole Derivative: A Combined Experimental and Theoretical Approach

Protection of Metals and Physical Chemistry of Surfaces - The effect of an heterocycle triazole, namely (1-(4-methoxyphenyl)-1H-1,2,3-triazol-4-yl)methanol (MTM) on the corrosion of mild steel in...     

An exploration of corrosion inhibition of mild steel in sulphuric acid solution through experimental study and Monte Carlo simulations

Abstract

4-[4-(1H-imidazol-1-yl)methyl)-1H-1,2,3-triazol-1-yl]methylbenzophenone (ITBP) and 4[4-(1H-1,2,4-triazol-1-yl)methyl)-1H-1,2,3-triazol-1-yl]methylbenzophenone (TTBP) are synthesized as new heterocyclic compounds of the triazole derivative family and tested successfully as potential inhibitors for MS in 1?M H₂SO₄ corrosive medium by using gravimetric analysis, electrochemical impedance spectroscopy, potentiodynamic polarization, and energy dispersive X-ray spectroscopy (EDX). Polarization curves show that the tested inhibitors are mixed-type inhibitors. Scanning electron microscopy (SEM) affirmed the existence of an adsorbed film on the steel surface. Monte Carlo simulations were in excellent agreement with the experimental tests.

Abbreviation: PDP: Potentiodynamic Polarization; EIS: Electrochemical impedance spectroscopy; DFT: Density functional theory; MC: Monte Carlo     

On Delay Performance and Burst Assembly for Wireless Mesh and Optical Burst Switching Converged Metro Area Network

Wireless Mesh Networks (WMN) have attracted increasing attention from the research community as a high-performance and low-cost solution to last-mile broadband Internet access. On the other side, Optical Burst Switching (OBS) is a promising access technology that uses optical fiber with burst switching paradigm. In this paper, we propose a novel Metropolitan Area Network (MAN) architecture, called Optical Burst Wireless Mesh Architecture (OBWMA) which integrates WMN at the user access side and OBS at the core of the MAN. OBWMA aims to combine advantages of both WMNs and OBS networks, such as large coverage at low cost and bandwidth availability. We specify the details of the interconnection and the internetworking of WMNs and the OBS network in OBWMA. Moreover, we develop an analytical model to compute the end-to-end delay in OBWMA in order to support flow requests with delay constraints. Furthermore, we propose a Control Bridge (CB) that ensures Quality of Service (QoS) mapping at the border between the WMN and the OBS parts. Also, we propose a burst assembly scheme, called Adaptive Hybrid Burst Assembly scheme (AHBA). Simulation results using ns-2 demonstrate the feasibility of OBWMA and the validity of our analytical model.     

A generic platform for scalable access to multimedia-on-demandsystems

Access to multimedia servers is commonly done according to a client/server model where the end user at the client host retrieves multimedia objects from a multimedia server. In a distributed environment, a number of end users may need to access a number of multimedia servers through one or several communication networks. Such a scenario reveals the requirement for a distributed access platform. In addition, the demand for multimedia information is increasing beyond the capabilities of high performance storage devices. Therefore, load distribution and scalability issues must be addressed while designing and implementing the distributed access platform. This paper introduces a scalable access platform (SAP) for managing user access to multimedia-on-demand systems while optimizing resource utilization. The platform is generic and capable of integrating heterogeneous multimedia servers. SAP operation combines static replication and dynamic load distribution policies. It provides run time redirecting of client requests to multimedia servers according to the workload information dynamically collected in the system. To support multimedia-on-demand systems with differing quality-of-service (QoS) requirements, the platform also takes into account, as part of the access process, user QoS requirements and cost constraints. This paper also presents an application of the generic platform implementing a scalable movie-on-demand system, called SMoD. Performance evaluation based on simulation shows that in many cases SMoD can reduce the blocking probability of user requests, and thus can support more users than classical video-on-demand (VoD) systems. It also shows that the load is better distributed across the video servers of the system     

Novel reinforcement learning-based approaches to reduce loss probability in buffer-less OBS networks

Optical Burst Switching (OBS) is a promising switching paradigm for the next generation Internet. A buffer-less OBS network can be implemented simply and cost-effectively without the need for either wavelength converters or optical buffers which are, currently, neither cost-effective nor technologically mature. However, this type of OBS networks suffers from relatively high loss probability caused by wavelength contentions at core nodes. This could prevent or, at least, delay the adoption of OBS networks as a solution for the next generation optical Internet. To enhance the performance of buffer-less OBS networks, we propose three approaches: (a) a reactive approach, called Reinforcement Learning-Based Deflection Routing Scheme (RLDRS) that aims to resolve wavelength contentions, after they occur, using deflection routing; (b) a proactive multi-path approach, called Reinforcement Learning-Based Alternative Routing (RLAR), that aims to reduce wavelength contentions; and (c) an approach, called Integrated Reinforcement Learning-based Routing and Contention Resolution (IRLRCR), that combines RLAR and RLDRS to conjointly deal with wavelength contentions proactively and reactively. Simulation results show that both RLAR and RLDRS reduce, effectively, loss probability in buffer-less OBS networks and outperform the existing multi-path and deflection routing approaches, respectively. Moreover, simulation results show that a substantial performance improvement, in terms of loss probability, is obtained using IRLRCR.     

Throughput Gateways-Congestion Trade-Off in Designing Multi-Radio Wireless Networks

In Wireless Mesh Networks (WMNs), traffic is mainly routed by WMN Backbone (WMNB) between the mesh clients and the Internet and goes through mesh gateways. Since almost all traffic has to pass through one of the MGs, the network may be unexpectedly congested at one or more of them, even if every mesh router provides enough throughput capacity. In this paper, we address the problem of congestion of gateways while designing WMNs. We propose a simultaneous optimization of three competing objectives, namely network deployment cost, interference between network channels and congestion of gateways while guaranteeing full coverage for mesh clients. We tailor a nature inspired meta-heuristic algorithm to solve the model whereby, several trade-off solutions are provided to the network planner to choose from. A comparative experimental study with different key parameter settings is conducted to evaluate the performance of the model.     

Anti-Corrosive Properties of (1-benzyl-1H-1,2,3-triazol-4-yl) Methanol on Mild Steel Corrosion in Hydrochloric Acid Solution: Experimental and Theoretical Evidences

Protection of Metals and Physical Chemistry of Surfaces - The corrosion inhibitory effect of (1-benzyl-1H-1,2,3-triazol-4-yl) methanol (BTM) for mild steel in 1 M HCl at (298–328 K) was...     

Properties of (0.5−x)Zn-xFe2O3-0.5P2O5 glasses

Experimental determination of the properties of less studied zinc-iron-phosphate glasses was investigated. Glasses of the general composition (50−x)ZnO-xFe₂O₃-50P₂O₅, mol%, with x=0, 10, 20, 30 and 40, was chosen for these investigations. These studies included, glass forming, glass density, thermal expansion coefficient, dilatometric softening temperature, an initial test of chemical durability and vibrational properties. It is shown that an Fe/P ratio of the compositions at about 0.6 and 0.8 and the O/P ratio at 3.4 and 3.8 could be considered as chemically durable phosphate candidates.