Granulation of a hardmetal powder for spark plasma sintering

A fluidized bed granulation method, pressure swing granulation (PSG), was applied to granulation of a hardmetal powder without pressing lubricants for making the upstream process of spark plasma sintering (SPS) more efficient.

The properties of the granules were examined and compared with those of spray dried granules and extruded ones under the present system using a sieve.

Spherical granules between 0.15 and 0.84 mm in diameter difficult to obtain by the spray drying were obtained with high yield. The flowability of the granules was far better than that of spray dried granules and similar to that of extruded ones. Iron contamination and oxidization during pressure swing granulation were tolerable to the real production.     

High-strength–high-modulus polyimide fibers II. Spinning and properties of fibers

The polyimides based on 3,3′,4,4′-biphenyltetracarboxylic dianhydride (BPDA) described in Part I of this series were dissolved in p-chlorophenol and spun into fibers using a coagulating bath of ethanol. The fibers as spun had in general low tenacities and low moduli, but a heat treatment at 300–500°C under tension produced a remarkable increase in strength and modulus, and fibers with a tensile strength of 26 g/den (3.1 GPa) and an initial modulus higher than 1,000 g/den (120 GPa) could be obtained. Thus, the annealed fibers of polyimides are comparable to aramid fibers in mechanical properties. To heating in air and in the saturated steam, the polyimide fibers showed higher resistance than the aramid fibers. The polyimide fibers surpassed the aramid fibers in resistance to acid treatment and ultraviolet (UV) irradiation, but were inferior in resistance to alkali treatment. The annealed fibers of polyimides displayed distinct X-ray diffraction patterns. The chain repeat distance of 20.5 Å determined on the fibers of polyimide prepared from BPDA and o-tolidine, and 20.6 Å determined on the fibers of polyimide derived from BPDA and 3,4′-diaminodiphenyl ether are reasonable when the dimensions of monomeric units and the shapes of the molecular chains are considered. The X-ray reflections of both polyimide fibers were indexed satisfactorily on the basis of postulated unit cells.     

Calcium oxide/carbon dioxide reactivity in a packed bed reactor of a chemical heat pump for high-temperature gas reactors

The thermal performance of a chemical heat pump that uses a calcium oxide/carbon dioxide reaction system was discussed as a heat storage system for utilizing heat output from high temperature gas reactors (HTGR). Calcium oxide/carbon dioxide reactivity for the heat pump was measured using a packed bed reactor containing 1.0 kg of reactant. The reactor was capable of storing heat at 900 °C by decarbonation of calcium carbonate and generating up to 997 °C by carbonation of calcium oxide. The amount of stored heat in the reactor was 800–900 kJ kg⁻¹. The output temperature of the reactor could be controlled by regulating the carbonation pressure. The thermal storage performance of the reactor was superior to that of conventional sensible heat storage systems. A heat pump using this CaO/CO₂ reactor is expected to contribute to thermal load leveling and to realize highly efficient utilization of HTGR output due to the high heat storage density and high-quality temperature output of the heat pump.     

Detection of back-side pit on a ferrous plate by magnetic flux leakage method with analyzing magnetic field vector

We have developed a magnetic flux leakage (MFL) system using magnetic resistive (MR) sensors for detecting two dimensional magnetic field components, and an induction coil that generates low magnetic field strengths and extremely low frequencies. The signal at each scanned measurement point (i) was divided by the signal strength M_mes,i and phase α_i by a lock-in amplifier. Using the strength M_mes,i and phase α_i, we calculated the imaginary part of the signal using the common phase β. By optimization of the common phase β to the imaginary part, the analyzed scanning data curve was shown to be effective in estimating the size (depth and diameter) of back-side pits on a ferrous plate. Comparing the two dimensional magnetic field components of leakage, the imaginary part of the y-component parallel to the induced magnetic field was found to be suitable for detecting the back-side pits.     

Buffer-trapping effects on current slump in AlGaN/GaN HEMTs

Two-dimensional transient analyses of GaN MESFETs and AlGaN/GaN HEMTs are performed in which a deep donor and a deep acceptor are considered in a semi-insulating buffer layer. Calculated transient characteristics are compared between the two FETs, and it is shown that the deep levels affect the results essentially in a similar way. Quasi-pulsed I–V curves are derived from the transient characteristics, and are compared with steady-state I–V curves. It is shown that so-called current slump is more pronounced when the deep-acceptor density in the buffer layer is higher and when an off-state drain voltage is higher, because trapping effects become more significant. It is suggested that to minimize current slump in GaN-based FETs, an acceptor density in a semi-insulating GaN layer should be made low.     

Nanoparticle formation in H2O/N2 and H2O/Ar mixtures under irradiation by 20 MeV protons and positive corona discharge

To investigate the contribution of ions to gas nucleation, we have performed experiments on the formation of water droplets in H₂O/N₂ and H₂O/Ar gas mixtures by irradiation with a 20 MeV proton beam and by positive corona discharge. The size of the formed nanoparticles was measured using a differential mobility analyzer equipped with a Faraday cup electrometer. Using the proton beam, droplets around 10 nm in diameter were observed for both positively and negatively charged particles, but none were found when the corona discharge was used. This implies the importance of the presence of both positive and negative ions for the formation of nanosize droplets, which attract each other by Coulomb interactions, enhancing the collision frequency and leading to the formation of the 10 nm droplets.     

Simulation of Lag Phenomena and Pulsed I-V Curves of Compound Semiconductor FETs as Affected by Impact Ionization

Turn-on characteristics of GaAs MESFETs are simulated when the gate and the drain voltages are changed abruptly, and quasi-pulsed I-V curves are derived from them. It is discussed how the slow current transients (lag phenomena) and the pulsed I-V curves are affected by the existence of substrate traps and surface states. It is also discussed how the characteristics are influenced by impact ionization of carriers.     

A 13-year-old male with a funnel chest treated by sternal elevation

To identify stage-specific molecules that might be important in pathogenicity, we focused on synchronizing Entamoeba histolytica HM1:1MSS axenic cultures by serum deprivation. By growing trophozoites in medium containing 2% serum for 16 h and then replacing with complete medium, we found that most of the trophozoites were in the G0/G1 phase of the cell cycle. Subsequently, the distribution of trophozoites in G0/G1, S and G2/M phases was studied for up to 24 h and it was observed that after 8 h, the trophozoites began to come out of the quiescent G0/G1 phase and the S and G2/M populations increased, indicating that certain serum factors regulate induction of cell division. It will be important to investigate these factors to find serum substitutes for cultivation media.     

A case of survival for 50 months after resection of cerebellar metastasis of squamous cell lung carcinoma

The patient was a 64-year-old male with squamous cell carcinoma of the left lung, associated with intrapulmonary metastasis. Eleven months after lobectomy, a single metastasis occurred in the left cerebellum. This was resected, and radiation therapy was performed. Fifty months after the resection, the patient is still alive without recurrence. Based on the present case, we consider that, in the case of single brain metastasis, surgical therapy is desirable because long-term survival can be expected with surgical resection even for a cerebellar metastasis.     

Analysis of carrier-blocking effect in AlGaAs/GaAs HBT's withinsulating external collector and design criteria for collector-up HBT's

Two-dimensional simulations of cutoff frequencies for AlGaAs/GaAs HBT's with perfectly insulating external collector are made, and the results are compared with those for a case with semi-insulating external collector and for a case with normal n^- external collector. It is found that in the case with perfectly insulating external collector, minority carriers injected into the base from the emitter are partially blocked by the insulating layer and accumulate in the external base region. These carriers increase the effective base delay time, resulting in remarkable degradation of the cutoff frequency. In relation to this effect, a collector-up HBT is also simulated, and the design criteria for it are discussed. It is concluded that the effective emitter width should be made narrower than the collector width