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排序方式: 共有395条查询结果,搜索用时 15 毫秒
1.
Antonio Sanchez‐Solis Andres Garcia‐Rejon Mirna Estrada Antonio Martinez‐Richa Guadalupe Sanchez Octavio Manero 《Polymer International》2005,54(12):1669-1672
The production and properties of blends of poly(ethylene terephthalate) (PET) and poly(ethylene naphthalene 2,6‐dicarboxylate) (PEN) with three modified clays are reported. Octadecylammonium chloride and maleic anhydride (MAH) are used to modify the surface of the montmorillonite–Na+ clay particles (clay–Na+) to produce clay–C18 and clay–MAH, respectively, before they are mixed with the PET/PEN system. The transesterification degree, hydrophobicity and the effect of the clays on the mechanical, rheological and thermal properties are analysed. The PET–PEN/clay–C18 system does not show any improvements in the mechanical properties, which is attributed to poor exfoliation. On the other hand, in the PET–PEN/clay–MAH blends, the modified clay restricts crystallization of the matrix, as evidenced in the low value of the crystallization enthalpy. The process‐induced PET–PEN transesterification reaction is affected by the clay particles. Clay–C18 induces the largest proportion of naphthalate–ethylene–terephthalate (NET) blocks, as opposed to clay–Na+ which renders the lowest proportion. The clay readily incorporates in the bulk polymer, but receding contact‐angle measurements reveal a small influence of the particles on the surface properties of the sample. The clay–Na+ blend shows a predominant solid‐like behaviour, as evidenced by the magnitude of the storage modulus in the low‐frequency range, which reflects a high entanglement density and a substantial degree of polymer–particle interactions. Copyright © 2005 Society of Chemical Industry 相似文献
2.
B. Herreros G. Lifante A. Kling J.C. Soares M.F. da Silva P.D. Townsend P.J. Chandler J. Olivares J.M. Cabrera 《Optical Materials》1996,6(4):281-286
We present a structural study of two Nd3+/MgO codoped LiNbO3 waveguides fabricated by two different methods: ion-implantation and proton-exchange. Rutherford backscattering spectrometry in combination with channelling was used to study the influence of the waveguide fabrication method on the possible modification of the LiNbO3 crystal structure within the waveguiding layer. The results show that the ion-implanted waveguide mainly maintains the same properties as the virgin crystal, apart from a deterioration of a thin surface layer, whilst the proton-exchanged waveguide exhibits a quite different behaviour, although its surface is less damaged. 相似文献
3.
4.
Sources of nutrition information of Chilean schoolers, metropolitan region, Chile, survey 1986-1987.
The purpose of the present study was to determine the relative importance of different sources of nutrition information used by Chilean schoolers to learn the basics of nutrition. In this respect, a representative sample of 4,509 elementary and high-school children was randomly selected and stratified according to grade, sex, type of school and geographic area. Schoolers were individually interviewed in order to collect data related with socioeconomic status (SES) and sociocultural conditions, as well as to learn as to what they considered to be the most important sources of nutrition information influencing their nutritional learning, gathering the necessary data through a questionnaire especially designed for this purpose. Results indicated that 87.8% schoolers mentioned their family (mainly the mother), as the most important source of nutrition information; 10.7% said the school teacher, and 1.5%, mass media (0.8% television, 0.5% books, 0.1% magazines and 0.1% radio) without significant differences by sex, age and geographic area. The role attributed to the family (mother) was important in all SES categories, but proved to be significantly higher in the high SES group (91.9%) than in the low SES group (84.6%). The role attributed to the school teacher, in contrast, was lower (6.7%) in the high SES group than in the low SES group (13.8%) (p less than 0.001). In relation to mass media, the influence attributed to books and magazines was high in the high SES group, but television and radio were more important in the low SES group. On the other hand, significant differences found by type of school were related to SES. These findings could be useful in the establishment of food and nutrition policies, as well as in educational planning focused on the Chilean school population, considering that few studies have been carried out along these lines. 相似文献
5.
Antonio M. Ortiz Fernando Royo Teresa Olivares Jose Carlos Castillo Luis Orozco‐Barbosa 《Expert Systems》2014,31(2):154-162
ZigBee is the primary standard solution for wireless sensor networks, implementing the Ad hoc On‐Demand Distance Vector (AODV) protocol in the network layer and supported by the standard IEEE 802.15.4. This study is focused on mesh topologies and the critical problems encountered when AODV is executed in conjunction with the Carrier Sense Multiple Access with Collision Avoidance protocol. These problems are mainly related to the packet overhead required to carry out route creation. To perform preliminary experiments to be able to implement AODV in a real network, a new metric is proposed herein. This metric uses fuzzy logic to help in the decision‐making process. The objective of the fuzzy routine is to determine, during the route‐discovery process, the best node to forward request/reply packets, with the aim of reducing packet overhead and energy consumption. Moreover, minor changes are also added to the discovery procedure of AODV to improve the performance of the route‐creation process. This intelligent version of AODV has provided promising experimental results, greatly reducing the number of packets required, with the consequent energy saving while selecting the best nodes to be part of the routes. 相似文献
6.
The present study was carried out to examine if the positional distribution of medium-chain fatty acid (MCF) in dietary synthetic
fat influences lymphatic transport of dietary fat and the chemical composition of chylomicrons in rats with permanent cannulation
of thoracic duct. Four types of synthetic triacylglycerol were prepared: (i) sn-1(3) MCF-sn 2 linoleic acid, (ii) interesterified sn-1(3) MCF-sn 2 linoleic acid, (iii) sn-2 MCF-sn-1(3) linoleic acid, and (iv) interesterified sn-2 MCF-sn-1(3) linoleic acid. A purified diet composed of equal amounts of the synthetic fat and cocoa butter was given to rats with
permanent lymph duct cannulation. The positional distribution of MCF in the dietary fat had no significant effect on the lymph
flow, triacylglycerol output, phospholipid output, lipid composition of chylomicrons, or the particle size. The positional
distribution of MCF in the synthetic triacylglycerol was maintained in the chylomicron triacylglycerol. These results showed
that MCF in the dietary triacylglycerol is transported into lymphatics and the positional distribution is well preserved in
chylomicron triacylglycerol. 相似文献
7.
Rodríguez J Fernández S Palacios SL Crespo RD Fernández JM Guinea A Virgós JM Olivares J 《Applied optics》1995,34(27):6172-6179
We present a theoretical method that makes it possible to analyze three-dimensional (3-D) integrated optical waveguides with arbitrary refractive-index profiles. With this method it is easy to obtain effective indexes, propagation constants, and coupling-switching properties of planar and channel optical waveguides. This theoretical approach involves one's modeling the original optical waveguide by means of an equivalent optical waveguide whose effective index is evaluated by the application of a technique that we call the asymptotic effective-index method. The numerical values show good convergence and accuracy for effective indexes, propagation constants, and coupling-switching characteristics. Theoretical and experimental results are given. 相似文献
8.
JM Olivares Diez 《Canadian Metallurgical Quarterly》1995,41(2):148-161
During the last decades, the term "anhedonia", conceptualized as a incapacity to experience pleasure, have become associated with conditions as different as schizophrenia and depression. This paper deals with the conceptual and historial frames in which anhedonia was first constructed, and shows that the sources for the current fuzziness of this concept include neglect of the fact that anhedonia is conceptually parasitical upon the notion of pleasure, that it has been rather superficially conceptualized as the reduction or abolition in a "putative" function which itself is unlikely to be unitary in nature, and that it has never been quite specified whether the mechanism concerns a deficit in brain signal or not. 相似文献
9.
Roberto Nicolsky Miguel Octavio Sonio Frota-Pessôa 《Journal of Low Temperature Physics》1985,58(1-2):11-26
We present a simple model to simulate small three-dimensional superconducting constrictions of variable thickness (VTBs) for which the cross-sectional dimensions are of the same order as the length, and both are less than (T). We study the behavior of the modulus of the order parameterf and the supercurrent densityJ
s
as a function of the various dimensions. We find that the extent to whichf is depressed in the banks depends on the ratio of width to length of the constriction. We show that even for very abrupt geometries,J
s
is not zero andf does not reach its equilibrium value immediately outside the constriction. On the basis of our results, we propose a more general expression for the effective length valid also when all dimensions are of the same order. The calculated values ofdI
c
/dT are consistent with experimental data from well-characterized VTBs. We suggest that the discrepancy between the calculated and experimental values ofI
c
R
n
may be due to the nonuniformity of the normal current density in the constriction. 相似文献
10.
Angelo Lucia Peter A. DiMaggio Meghan L. Bellows Leah M. Octavio 《Computers & Chemical Engineering》2005,29(11-12):2363
Normal alkanes show very complicated phase transition kinetics and macroscopic phase equilibrium behavior. This paper focuses on the phase stability and equilibrium of complicated mixtures like n-alkanes and on the enabling global optimization technologies needed to gather problem knowledge. The new ideas contained in this paper include:
- (1) novel level set methods for gathering encoded knowledge;
- (2) the differential geometry for uncovering pathways to more subtle knowledge;
- (3) all supporting non-linearly constrained optimization techniques;
- (4) all data handling needed to unravel complex solution structure.