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1.
Pyrolysis experiments were performed in high vacuum and under reduced air pressure (100 Pa). The volatile products of pure cellulose and cellulose containing various amounts of flame retardant 2,2′-oxybis (5,5-dimethyl-1,3,2-dioxaphosphorinane-2,2′-disulfide), i.e., Sandoflam 5060 of Sandoz AG, were studied by means of gas chromatography in combination with mass spectroscopy. The volatile products were characterized with infrared spectroscopy. The studied revealed that the incorporation of the flame retardant enhanced the water release and shifted the onset of this reaction to lower temperature. On the basis of these findings an explanation for the mechanism of flame retardancy in generated cellulose fibers modified with this particular flame retardant is attempted. From experiments with different residual air pressure the influence of oxygen on the primary processes of the pyrolytic degradation of cellulose is being discussed. 相似文献
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Electrochemical impedance measurements have been used to characterize zinc selenide films prepared by electrochemical co-deposition at a platinum rotating disk electrode. Estimations of capacitance and polarization resistance of variously prepared electrodeposits have been carried out to determine charge carrier density and corrosion rates. 相似文献
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The paper describes the synthesis of N-2/4-toluyl methacrylatoethyl carbamates using 2/4-toluyl isocyanate and 2-hydroxyethyl methacrylate. Homopolymerisation and copolymerisation of these novel monomers with methyl methacrylate was carried out using benzoyl peroxide as an initiator and tetrahydrofuran as solvent. Photopolymerisation of N-4-toluyl methacrylatoethyl carbamate could be carried out without the use of photosensitiser. Structural characterisation of copolymers was done using 1H-NMR. Thermal stability of copolymers was evaluated in a nitrogen atmosphere by dynamic thermogravimetry. 相似文献
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1,3,5‐Triglyceratetriazine [first tier (G1)] and tri(1,3,5‐triglycerate) triazine [second tier (G2)] dendrimers were prepared with 1,3,5‐trichlorotriazine and sodium glycerate in a 1 : 3 mass ratio in an ethanolic medium.G1 and G2 were amorphous, white, solid substances. Their structures were elucidated with IR, 1H‐NMR, and 13C‐NMR, and their thermal stability was studied with thermogravimetric analysis. The activation energy was calculated with the Freeman–Carroll model. Densities, viscosities, and surface tensions for 0.01–0.08 mol/kg aqueous solutions increased at 0.01 mol/kg for sodium glycerate, 1,3,5‐trichlorotriazine, 1,3,5‐triazine triglycerate chloride, G1, and G2. These values were measured at 298.15 K. The apparent molal volume, reduced viscosity, and inherent viscosity were calculated from the densities and viscosities, respectively. The data were regressed for the limiting densities, limiting apparent molal volumes, intrinsic viscosities, limiting inherent viscosities, and limiting surface tensions for solute–solvent interactions. The positive limiting apparent molal volume values were noted in the order of G2 > 1,3,5‐triazine triglycerate chloride > G1 > 1,3,5‐trichlorotriazine > sodium glycerate, with weaker hydrophilic intermolecular interactions of G2. The higher intrinsic viscosity and limiting inherent viscosity values for G2 implied stronger G2–H2O hydrophilic interactions, and the higher limiting apparent molal volume of G2 indicated slightly higher dynamic conformational changes in comparison with G1, with stronger structural activities. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
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Distributed active storage architectures are designed to offload user-level processing to the peripheral from the host servers.
In this paper, we report preliminary investigation on performance and fault recovery designs, as impacted by emerging storage
interconnect protocols and state-of-the-art storage devices. Empirical results obtained using validated device-level and interconnect
data demonstrate the significance of the said parameters on the overall system performance and reliability. 相似文献