Influence of Different Additives on the Interaction of Quinolone Antibiotic Drug with Surfactant: Conductivity and Cloud Point Measurement Study

Conductometric and cloud point (CP) measurement studies have been performed to investigate the interaction of tetradecyltrimethylammonium bromide (TTAB) and Triton® X-100 (TX-100) with ciprofloxacin hydrochloride (CFH) in different solvents over the temperature range of 295.15–315.15 K. CFH is used for the treatment of various bacterial infections. The observed critical micelle concentration (CMC) values of TTAB were found to be reduced in the presence of electrolytes (Na₂SO₄/Na₃PO₄), and this reduction proceeds with the elevation of salt concentration. The order of the CMC of TTAB follows the trend: > >. The observed CMC values of TTAB were found to increase with increasing temperature and decrease with increasing concentration of CFH in aqueous medium. The values of Gibbs free energy of micellization () for the TTAB/TTAB + CFH mixture were found to be negative, implying spontaneous micellization. The estimated CP of TX-100 decreases with increasing concentration of TX-100 in aqueous medium. The CP values first decrease with increasing concentration of CFH and then increase at higher concentration of CFH almost in all cases investigated. The values of free energy of clouding were found to be positive in all cases studied implying that phase separation of TX-100 was nonspontaneous. The other thermodynamic parameters associated with the micellization of TTAB and the phase separation of TX-100 were estimated and explained.     

Kinetic analysis of magnesium aluminate spinel formation: Effect of MgO:Al2O3 ratio and titania dopant

The mechanistic pathway of MgO-Al₂O₃ reaction in solid state to form MgAl₂O₄ spinel was investigated to correlate the kinetic parameters with ratio of reactants (MgO:Al₂O₃) and with the presence of a doping agent, TiO₂. The time-temperature-expansion data of oxide compacts was analyzed using several model free analyses and model based (linear and non-linear) kinetic algorithms. These indicated that spinel formation process can be best described by single step with n-dimensional Avrami equation for every MgO:Al₂O₃ ratio, irrespective of titania dopant. The activation energy (E_a) of the process was proportional to % spinel formed in each system and validated with quantitative XRD analysis. The higher value of Avrami coefficient (n) in 90 wt% Al₂O₃ compositions has been explained with geometric considerations of powder packing. Incorporations of 1% TiO₂ in the MgO: Al₂O₃ oxide compact did not markedly affect the reaction model, frequency factor and Activation energy.     

Morphological and mechanical studies of surface treated mica reinforced high density polyethylene

Morphological studies of high density polyethylene (HDPE) reinforced by mica flakes has been investigated. The mica flakes were surface treated by silane and titanate coupling agents. Effects of these treatments on the polymer-mica interface is discussed. It is found that surface treatment, particularly silane treated composites, have better adhesion between the reinforcing agent and the polymer matrix. This effect can only be detected when the mica concentration is higher than 20 weight percent. This interfacial adhesion could not be seen across the surface of the sample but only when the measurements were made parallel to the surface.     

QoS-aware service composition for distributed video surveillance

Quality of Service (QoS) is essential for the ubiquitous access of media services in real-time distributed video surveillance applications. To have ubiquitous access of desired media with emergency officials’ handheld devices, appropriate media transcoding services are required. Currently, it is challenging to select and compose these services for each of the devices to satisfy the desired QoS demand. To compose these media services so that video stream is available for target pervasive and smart devices, a composition algorithm is required. Thus, this paper presents a QoS-aware service composition algorithm to select the best composition for the target ubiquitous client so that it can optimally provide QoS to heterogeneous users. We have implemented a video surveillance prototype to demonstrate the performance of the proposed QoS-aware composition algorithm. Results from this prototype reveal that the approach is suitable for real-time video surveillance.     

Light weight model for intra mode selection in HEVC

Multimedia Tools and Applications - The High Efficiency Video Coding (HEVC) efficiently reduces the size of the multimedia contents, but at the cost of high computation complexity. In order to make...     

Modeling and Analysis of Temperature Compensation for Multi-temperature Zone Sintering Furnace Temperature Sensing

International Journal of Control, Automation and Systems - The surface temperature of workpieces in a multi-temperature zone sintering furnace is an important parameter to characterize the...     

Synthesis and characterization of eugenol-based silicone modified waterborne polyurethane with excellent properties

A eugenol-based silicone-containing monomer 4,4′-(1,1,3,3-tetramethyldisiloxane-1,3-dipropyl)bis-2-methoxyphenol(EUSi) was synthesized from eugenol and 1,1,3,3-tetramethyldisiloxane via the hydrosilylation reaction. And waterborne polyurethane (WPU) with excellent properties was obtained by using EUSi as a type of diol chain extender. The unique combination of rigidity and flexibility in the chemical structure of EUSi greatly facilitated the mechanical properties, thermal properties, and water resistance of WPU. With only a 3% dosage of EUSi, the maximum tensile strength was increased from 6.2 to 22.4 MPa, while the water absorption was decreased from 31.3% to a surprisingly 7.6%. Our work provides a new convenient strategy for the preparation of organosilicon-modified WPU with improved performance.     

Adaptive infill sampling criterion for multi-fidelity optimization based on Gappy-POD

This paper presents a reformulation of the “Gappy Proper Orthogonal Decomposition” (Gappy-POD) multi-fidelity modeling approach and proposes an enrichment criterion associated with an adaptive infill algorithm. The latter is here applied to the study of the flight domain of the RAE-2822 transonic airfoil at two different levels of accuracy to demonstrate its ability to detect areas in a two-dimensional design space where the surrogate model needs improvement to better drive the optimization process.     

Ant-based service selection framework for a smart home monitoring environment

Selecting ambient media services in a smart home monitoring environment is challenging. Services in such an environment should be ubiquitous, adaptive, and robust with respect to access and delivery. Many different techniques exist for selecting services in smart environments, for example, dynamic programming, genetic algorithms, and fuzzy logic. However, existing approaches to service selection fail to address the dynamic nature of the services and the requirement of considering the user context and user satisfaction. We address this issue by proposing an ant-inspired service selection framework based on dynamic user preferences and satisfaction. This ant-inspired approach is robust to failures and adaptive to dynamic context. The proposed framework enables different categories of residents (e.g., elderly people, fathers with children, mothers, and so on) to access various media services in such a way that their experiences are optimized with regard to their surrounding environment. Experimental results demonstrate the viability of the proposed framework.