Comparative studies on thermal and toughness properties of polybenzoxazine composites with two functionalized graphene oxides

Abstract

Graphene oxide (GO) was functionalized by polyether amine (PEA) via two methods which were one-pot modification in acetone (GON) and two steps with the intermediate product of GOCO-Cl generated (GONS). There were more PEA successfully grafted onto GO for GONS than GON. The onset polymerization temperatures of the benzoxazine (Bz) composites decreased by the inclusion of 1?wt% of GO, GON or GONS. Thermal stability of the polybenzoxazine (PBz) composites was significantly improved indicated from the increase of weight loss temperature. T₁₀, T₂₀ and T₅₀ values of the composites with GONS were higher than that of the others. Toughness of PBzs may be enhanced by the incorporation of nanofillers, and GONS had stronger interfacial interaction with PBz matrix than GON.     

判断油气藏非均质性的新方法

非均质性是油气藏的基本特性,也是影响油气面采收率的重要因素.它是反映油气藏的渗透率、孔隙度、有效厚度及其连通性的综合特征参数.不同油气藏在投入开发后,其产量随时间变化的分布曲线与油气藏自身的非质均性有密切关系.利用伽马分布描述油气藏产量随时间的变化,研制了典型曲线的理论图版,通过拟会求解,可判断油气藏的非均质程度.     

灰色理论的位移传感器标定不确定度评定

硅晶元等高精度平面度测量时,为提高测量可信性,对所用位移传感器标定已成为业界常规。本研究针对用于基于逐次两点法(STPM)测量硅平面的两电容式位移传感器2804/3890 J设计了一种压电陶瓷标定系统,实现其标定间隔达到8nm/1 mV,提高了标定的精确度。建立基于灰色理论的GM(0,2)系统数学模型,确立待标定传感器测量结果的回归模型,以得到传感器特性的最佳估计,并确定其联合不确定度,得到被标传感器的测量不确定度的最佳评估。与传统回归模型比较,得出GM(0,2)模型具有很好的精度,满足要求。通过STPM测量过程的模拟,得到用此传感器实施的STPM测量的测量精度约为56 nm(λ=20 nm)。     

激光焊接对接拼缝测量的微景深方法

对于复杂微细、错边量小的激光焊接拼缝测量,现有的视觉传感器方法不能稳定、可靠地提取出拼缝的中心位置、拼缝宽度等信息。为此,提出了基于微景深的激光焊接对接拼缝测量方法,该方法采用高倍光学放大镜头、工业CCD(Charge Coupled Device)/CMOS(Complementary Metal-Oxide-Semiconductor Transistor)相机和LED(Light-Emitting Diode)外部照明装置,以光学成像光轴与被测表面法矢呈45°的方式,组成的对接拼缝的非接触测量系统,既解决了显微放大时景深很小、测量范围小的问题,又解决了狭窄拼缝高光学放大倍数拼缝检测的难题。实验结果表明,该系统可快速准确地提取出拼缝中心坐标、拼缝宽度以及拼缝局部表面法矢。拼缝宽度测量精度优于5 μm,拼缝中心测量精度优于6 μm,可识别的最小拼缝宽度为0.02 mm,完全满足激光焊接对接狭窄拼缝的检测与自动跟踪的要求。     

氢化物原子荧光光谱法测定党参中的硒含量

为建立一种操作简便,快速,高灵敏度的氢化物原子荧光光谱法测定党参中硒的分析方法。方法 采用原子荧光光谱法对测定党参中硒元素进行含量的定量分析方法。结果 硒含量在0~40 μg/L质量范围内与其荧光强度呈现良好的线性关系（R²=0.9999）,检出限为Q=0.065 ng/mL;加样回收率为113.33%,相对标准偏差（RSD）为4.97%;精密度RSD为1.65%;准确度RSD为4.58%;稳定性RSD为6.52 %。11个不同品种党参之间的硒含量稍有不同,但都在0.1 mg/kg以下。结论 在富硒党参质量控制检测中,用原子荧光光谱法测定硒含量,其操作快速、简便,能准确测定党参硒含量。     

改进直觉模糊熵和证据推理的多属性群决策方法

针对属性权重和专家权重完全未知或部分已知的直觉模糊多属性群决策问题,提出一种基于改进直觉模糊熵和证据推理的多属性群决策方法.针对现有直觉模糊熵存在的不足,进一步完善直觉模糊熵公理化定义,并构造出一类改进的直觉模糊熵公式.然后,运用改进的直觉模糊熵对直觉模糊集的不确定性进行度量,以便获取属性和专家的权重,并结合证据推理算法进行决策信息的集结,进而依据相对贴近度实现对方案的排序.最后,通过算例进行比较分析,验证提出方法的可行性和有效性.     

绩优问题生的成因分析及其教育对策初探

绩优问题生,指学业成绩优异、但心理有疾患的大学生。为增强教育的针对性,促进绩优问题生的健康成长和全面发展,本文从家庭、学校、个人三个方面对其进行成因分析,并提出相应教育对策。     

基于信令分析的伪基站侦测与追踪系统

伪基站是通过仿真移动通信无线基站,采用大功率的无线信号发射器,强迫用户手机在仿真基站上进行登记,并强行推送商业广告短信,甚至诈骗短信,给手机用户带来骚扰和损失.“伪基站侦测与追踪系统”是对海量信令数据进行深入挖掘,并且结合无线覆盖模型、GIS等技术实现对伪基站跟踪、定位的系统.     

CO变换催化剂的研究进展

介绍了国内外CO中(高)温变换催化剂、低变催化剂及耐硫变换催化剂的现状及研究进展。高效节能型变换工艺将是变换工艺的发展方向,开发低温、高活性和稳定性的变换催化剂将相应成为研究的主要目标。     

Bone Tissue Response to the Bone-like Tissue Coating on Titanium

The objective of this study was to investigate the effects of mineralized bone nodules, formed in vitro by bone marrow stromal cells(BMSCs), on the new bone formation in bone defect and on implant surface. The mineralized bone nodules were generated by culture of Lewis rats BMSCs on titanium disks in osteogenic induction medium. The gap-healing animal model was used to create the bone defect facing the disk. The titanium disks in the presence of B group or in the absence of NB group bone nodules were randomly placed into one of the rat distal femurs. This self-control design was used to compare the bone formation in defects and on titanium surface, by Micro-CT, fluorescence staining, histological and histomorphometric analysis. The new bone formation parameters in bone defect area of B group were significantly higher than those of NB group at 2 weeks, including bone volume fraction, trabecular thickness and bone area ratio. The bone nodules pre-stained with Alizarin red disappeared mostly at 2 weeks, while the red fluorescence reappeared in the newly formed bone away from the disk surface. For the bone-implant contact, B group showed lower values than NB group at 2 weeks, but no significant difference was found at 4 weeks. Our results indicate that the mineralized bone nodules can be resorbed in vivo and promote the early osteogenesis in the bone defects, and bone nodules may be applicable for new bone generation in bone defect or modification of tissue engineering scaffold.