The yttrium effect on the corrosion resistance of CO2-laser processed MCrAlY coatings

To improve the corrosion resistance and to study the effect of yttrium in the behavior of coatings produced by thermal spraying MCrAlY (M=Ni, Co) powders, CO₂ laser processing was conducted. Three methods were used: (1) a combination of gas flame and plasma spraying in air followed by laser glazing in argon, (2) low-pressure plasma spraying (LPPS) and laser glazing in argon, and (3) LPPS and laser-gas (O₂) alloying. Laser glazing in argon of the MCrAlY coatings sprayed in air promoted formation of weakly adherent agglomerates of Al–Y oxides and an alumina-chromia solid solution. Glazing in argon atmosphere of LPPS CoNiCrAlY and NiCrAlY coatings caused the formation of nickel aluminides besides the formation of Y–Al compounds. Gas (O₂)-alloying of these coatings produces continuous and adherent (yttrium-containing) alumina and chromia layers. The effects of yttrium on the characteristics of the oxides formed in the coatings during laser glazing, laser-gas alloying, and high-temperature oxidation is discussed. This work also investigated the oxidation resistance of the laser-processed MCrAlY coatings in air and in the presence of 85 mol/o V₂O₅–Na₂SO₄ fused salt at 900°C.     

Modified distributed arithmetic based architecture for discrete wavelet transforms

A highly area-efficient multiplier-less filterbank architecture for one-and two-dimensional discrete wavelet transforms (DWT) is presented. The look-up table (LUT) structure in traditional distributed arithmetic (DA)-based filter structures has been dissolved to implement a LUT-less DA-DWT with dual filterbanks, which permits the reuse of the same circuitry for both highpass and lowpass filters.     

Four-Dimensional Gallant–Lambert–Vanstone Scalar Multiplication

The GLV method of Gallant, Lambert, and Vanstone (CRYPTO 2001) computes any multiple kP of a point P of prime order n lying on an elliptic curve with a low-degree endomorphism Φ (called GLV curve) over $\mathbb{F}_{p}$ as $$kP = k_1P + k_2\varPhi(P) \quad\text{with } \max \bigl\{ |k_1|,|k_2| \bigr\} \leq C_1\sqrt{n} $$ for some explicit constant C ₁>0. Recently, Galbraith, Lin, and Scott (EUROCRYPT 2009) extended this method to all curves over $\mathbb{F}_{p^{2}}$ which are twists of curves defined over $\mathbb{F}_{p}$ . We show in this work how to merge the two approaches in order to get, for twists of any GLV curve over $\mathbb{F}_{p^{2}}$ , a four-dimensional decomposition together with fast endomorphisms Φ,Ψ over $\mathbb{F}_{p^{2}}$ acting on the group generated by a point P of prime order n, resulting in a proven decomposition for any scalar k∈[1,n] given by $$kP=k_1P+ k_2\varPhi(P)+ k_3\varPsi(P) + k_4\varPsi\varPhi(P) \quad \text{with } \max_i \bigl(|k_i| \bigr)< C_2\, n^{1/4} $$ for some explicit C ₂>0. Remarkably, taking the best C ₁,C ₂, we obtain C ₂/C ₁<412, independently of the curve, ensuring in theory an almost constant relative speedup. In practice, our experiments reveal that the use of the merged GLV–GLS approach supports a scalar multiplication that runs up to 1.5 times faster than the original GLV method. We then improve this performance even further by exploiting the Twisted Edwards model and show that curves originally slower may become extremely efficient on this model. In addition, we analyze the performance of the method on a multicore setting and describe how to efficiently protect GLV-based scalar multiplication against several side-channel attacks. Our implementations improve the state-of-the-art performance of scalar multiplication on elliptic curves over large prime characteristic fields for a variety of scenarios including side-channel protected and unprotected cases with sequential and multicore execution.     

Fe-heme conformations in ferric myoglobin

X-ray absorption near-edge structure (XANES) spectra of ferric myoglobin from horse heart have been acquired as a function of pH (between 5.3 and 11.3). At pH = 11.3 temperature-dependent spectra (between 20 and 293 K) have been collected as well. Experimental data solve three main conformations of the Fe-heme: the first, at low pH, is related to high-spin aquomet-myoglobin (Mb+OH2). The other two, at pH 11.3, are related to hydroxymet-myoglobin (Mb+OH-), and are in thermal equilibrium, corresponding to high- and low-spin Mb+OH-. The structure of the three Fe-heme conformations has been assigned according to spin-resolved multiple scattering simulations and fitting of the XANES data. The chemical transition between Mb+OH2 and high-spin Mb+OH-, and the spin transition of Mb+OH-, are accompanied by changes of the Fe coordination sphere due to its movement toward the heme plane, coupled to an increase of the axial asymmetry.