全文获取类型
收费全文 | 378篇 |
免费 | 28篇 |
国内免费 | 3篇 |
专业分类
电工技术 | 3篇 |
综合类 | 1篇 |
化学工业 | 119篇 |
金属工艺 | 5篇 |
机械仪表 | 8篇 |
建筑科学 | 6篇 |
能源动力 | 12篇 |
轻工业 | 10篇 |
水利工程 | 1篇 |
石油天然气 | 4篇 |
武器工业 | 1篇 |
无线电 | 42篇 |
一般工业技术 | 151篇 |
冶金工业 | 7篇 |
原子能技术 | 4篇 |
自动化技术 | 35篇 |
出版年
2023年 | 5篇 |
2022年 | 17篇 |
2021年 | 18篇 |
2020年 | 18篇 |
2019年 | 18篇 |
2018年 | 21篇 |
2017年 | 17篇 |
2016年 | 15篇 |
2015年 | 8篇 |
2014年 | 14篇 |
2013年 | 19篇 |
2012年 | 38篇 |
2011年 | 35篇 |
2010年 | 20篇 |
2009年 | 18篇 |
2008年 | 26篇 |
2007年 | 18篇 |
2006年 | 13篇 |
2005年 | 7篇 |
2004年 | 9篇 |
2003年 | 14篇 |
2002年 | 6篇 |
2001年 | 2篇 |
2000年 | 1篇 |
1999年 | 2篇 |
1998年 | 4篇 |
1997年 | 4篇 |
1996年 | 2篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1992年 | 3篇 |
1991年 | 1篇 |
1984年 | 2篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1978年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有409条查询结果,搜索用时 15 毫秒
1.
Valentina I. Simagina Pavel A. Storozhenko Olga V. Netskina Oksana V. Komova Galina V. Odegova Yury V. Larichev Arcady V. Ishchenko Anna M. Ozerova 《Catalysis Today》2008,138(3-4):253
Catalytic hydrolysis of NaBH4 and NH3BH3 has been studied. It was shown that the nature of the support and the active component of the catalyst affect the H2 generation rate. Despite similar sizes of rhodium particles formed on the surface of different supports (γ-Al2O3, TiO2, carbon), their reactivity is different. Rh/TiO2 with low rhodium concentration (1 wt.%) is the most active catalyst both in the hydrolysis of NaBH4 and NH3BH3. The obtained results show that the rhodium chloride interaction with titania determines the reactivity of rhodium particles formed under action of NaBH4 medium. TEM, DRS UV–vis and XPS were used to characterize the catalysts. 相似文献
2.
The integral experiment on beryllium with D-T neutrons for verification of tritium breeding 总被引:1,自引:0,他引:1
Yury Verzilov Satoshi Sato Kentaro Ochiai Masayuki Wada Axel Klix Takeo Nishitani 《Fusion Engineering and Design》2007,82(1):1-9
A clean benchmark experiment on beryllium was performed with D-T neutrons at the FNS facility of the Japan Atomic Energy Agency. The main objective was to verify the integral data related to the tritium production on lithium isotopes. Tritium production rates, as well as activation reaction rates were measured inside the beryllium assembly that was shaped as a pseudo-cylindrical slab with an area-equivalent diameter of 628 mm and a thickness of 355 mm. Experimental results were analyzed with a three-dimensional Monte Carlo transport code MCNP-4C and FENDL/MC-2.0, JENDL-3.2/3.3 neutron transport libraries. Evaluation of reaction rates was based on the cross section data taken from the JENDL Dosimetry File and ENDF B-VI data libraries. Analysis shows that all calculation combinations (transport and activation cross section libraries) used for evaluation of reaction rates give data that is agreeable with measured values within 10%. 相似文献
3.
Jing Yuan Yury Stepanenko 《International Journal of Adaptive Control and Signal Processing》1992,6(2):111-126
A new adaptive controller is presented here for rigid-body robotic manipulators. It is stable and robust with respect to a class of external disturbances. The robustness of the adaptive controller is established without the ‘slow-varying’ assumption and the computationally demanding regressor matrix. The control law consists of a non-adaptive PD control part and an adaptive control part. It uses two adaptive matrices to compensate two uniformly bounded coefficient matrices derived from the original dynamics. A α σ|q?|-modified adaptive law is designed to adjust the adaptive matrices. A Lyapunov-type stability analysis indicates that the closed-loop system is uniformly ultimately bounded. The tracking error and compensation error will eventually converge into a closed region, which can be made arbitrarily small by adjusting the controller parameters. Simulation results are included to demonstrate the performance of the proposed controller. 相似文献
4.
Yury V. Kissin 《Catalysis Letters》1993,19(2-3):181-187
An experimental technique is discussed for measuring relative reactivities of alkanes in the catalytic cracking of multi-component hydrocarbon mixtures over a heterogeneous, Y-zeolitebased catalyst at 250–350 °C. With the technique, ca. 0.1 l of an alkane mixture is evaporated and contacted with a catalyst, after which the mixture of reaction products and the unreacted feed enters the chromatographic column and is immediately analyzed. The technique is used to measure relative reactivities of 21 alkanes in a single experiment. The principal results of these experiments are similar to the results of single-component cracking: alkane reactivity rapidly increases with the increase of the carbon number, and methyl-branched alkanes are more reactive than linear alkanes. However, the variations in alkane reactivities as a function of their molecular weight and skeleton structure differ very significantly between single- and multicomponent experiments. 相似文献
5.
MXene Yarn Supercapacitors: High‐Performance Biscrolled MXene/Carbon Nanotube Yarn Supercapacitors (Small 37/2018) 下载免费PDF全文
6.
We present a method to speed up the dynamic program algorithms used for solving the HMM decoding and training problems for
discrete time-independent HMMs. We discuss the application of our method to Viterbi’s decoding and training algorithms (IEEE
Trans. Inform. Theory IT-13:260–269, 1967), as well as to the forward-backward and Baum-Welch (Inequalities 3:1–8, 1972) algorithms. Our approach is based on identifying repeated substrings in the observed input sequence. Initially, we show
how to exploit repetitions of all sufficiently small substrings (this is similar to the Four Russians method). Then, we describe
four algorithms based alternatively on run length encoding (RLE), Lempel-Ziv (LZ78) parsing, grammar-based compression (SLP),
and byte pair encoding (BPE). Compared to Viterbi’s algorithm, we achieve speedups of Θ(log n) using the Four Russians method,
using RLE,
using LZ78,
using SLP, and Ω(r) using BPE, where k is the number of hidden states, n is the length of the observed sequence and r is its compression ratio (under each compression scheme). Our experimental results demonstrate that our new algorithms are
indeed faster in practice. We also discuss a parallel implementation of our algorithms.
A preliminary version of this paper appeared in Proc. 18th Annual Symposium on Combinatorial Pattern Matching (CPM), pp. 4–15,
2007.
Y. Lifshits’ research was supported by the Center for the Mathematics of Information and the Lee Center for Advanced Networking.
S. Mozes’ work conducted while visiting MIT. 相似文献
7.
Sanabria NR Peralta YM Monta?ez MK Rodríguez-Valencia N Molina R Moreno S 《Water science and technology》2012,66(8):1663-1668
The effluent from the anaerobic biological treatment of coffee wet processing wastewater (CWPW) contains a non-biodegradable compound that must be treated before it is discharged into a water source. In this paper, the wet hydrogen peroxide catalytic oxidation (WHPCO) process using Al-Ce-Fe-PILC catalysts was researched as a post-treatment system for CWPW and tested in a semi-batch reactor at atmospheric pressure and 25 °C. The Al-Ce-Fe-PILC achieved a high conversion rate of total phenolic compounds (70%) and mineralization to CO(2) (50%) after 5 h reaction time. The chemical oxygen demand (COD) of coffee processing wastewater after wet hydrogen peroxide catalytic oxidation was reduced in 66%. The combination of the two treatment methods, biological (developed by Cenicafé) and catalytic oxidation with Al-Ce-Fe-PILC, achieved a 97% reduction of COD in CWPW. Therefore, the WHPCO using Al-Ce-Fe-PILC catalysts is a viable alternative for the post-treatment of coffee processing wastewater. 相似文献
8.
Natallia V. Dubashynskaya Anton N. Bokatyi Anatoliy V. Dobrodumov Igor V. Kudryavtsev Andrey S. Trulioff Artem A. Rubinstein Arthur D. Aquino Yaroslav A. Dubrovskii Elena S. Knyazeva Elena V. Demyanova Yuliya A. Nashchekina Yury A. Skorik 《International journal of molecular sciences》2023,24(1)
The growth of microbial multidrug resistance is a problem in modern clinical medicine. Chemical modification of active pharmaceutical ingredients is an attractive strategy to improve their biopharmaceutical properties by increasing bioavailability and reducing drug toxicity. Conjugation of antimicrobial drugs with natural polysaccharides provides high efficiency of these systems due to targeted delivery, controlled drug release and reduced toxicity. This paper reports a two-step synthesis of colistin conjugates (CT) with succinyl chitosan (SucCS); first, we modified chitosan with succinyl anhydride to introduce a carboxyl function into the polymer molecule, which was then used for chemical grafting with amino groups of the peptide antibiotic CT using carbodiimide chemistry. The resulting polymeric delivery systems had a degree of substitution (DS) by CT of 3–8%, with conjugation efficiencies ranging from 54 to 100% and CT contents ranging from 130–318 μg/mg. The size of the obtained particles was 100–200 nm, and the ζ-potential varied from −22 to −28 mV. In vitro release studies at pH 7.4 demonstrated ultra-slow hydrolysis of amide bonds, with a CT release of 0.1–0.5% after 12 h; at pH 5.2, the hydrolysis rate slightly increased; however, it remained extremely low (1.5% of CT was released after 12 h). The antimicrobial activity of the conjugates depended on the DS. At DS 8%, the minimum inhibitory concentration (MIC) of the conjugate was equal to the MIC of native CT (1 µg/mL); at DS of 3 and 5%, the MIC increased 8-fold. In addition, the developed systems reduced CT nephrotoxicity by 20–60%; they also demonstrated the ability to reduce bacterial lipopolysaccharide-induced inflammation in vitro. Thus, these promising CT-SucCS conjugates are prospective for developing safe and effective nanoantibiotics. 相似文献
9.
本文从生化角度全面分析了中国沙棘乙醇提取物的体外抗氧化活性,并在评价细胞毒性的基础上,以Hep G2细胞为模型,利用流式细胞仪评估了提取物的细胞抗氧化能力。结果表明,中国沙棘乙醇提取物对ABTS自由基具有良好的清除效果,当浓度为5 mg/m L时,其清除能力与阳性对照BHT相当;中国沙棘乙醇提取物对NO自由基也有良好的清除效果,但其整体清除能力不及BHT;当浓度为5 mg/m L时,中国沙棘乙醇提取物对亚油酸脂质过氧化表现抑制,但其抑制效果低于BHT;中国沙棘乙醇提取物的总抗氧化能力随浓度的增大而增强,当浓度为5 mg/m L时,其总抗氧化能力与同浓度下的BHT接近。在浓度为0.05~5 mg/m L范围内,中国沙棘乙醇提取物对Hep G2细胞不显示毒性;当处理浓度为0.5、1、5 mg/m L时,中国沙棘乙醇提取物的阳性细胞率与阳性对照相比分别降低了75.22%、72.36%和78.2%。中国沙棘乙醇提取物不仅在体外条件下具有良好的抗氧化活性,而且在Hep G2细胞内表现出良好的抗氧化能力。 相似文献
10.
Vitaly Shubin Yury Shelygin Sergey Achkasov Oleg Sushkov Ilya Nazarov Alexey Ponomarenko Iuliia Alimova Anna Loginova Aleksey Tsukanov 《International journal of molecular sciences》2022,23(13)
The aim of this study was to determine the characteristics of Russian patients with microsatellite instability (MSI) tumors. MSI in the tumor was determined in 514 patients with colon cancer using PCR and subsequent fragment analysis for five markers (NR21, NR24, BAT25, BAT26, and NR27). In the presence of microsatellite instability, the mismatch repair (MMR) system genes were examined using the NGS and MLPA methods to establish the diagnosis of Lynch syndrome. The overall frequency of MSI tumors was 15%: at stage I—19% (9/48), at stage II—21% (44/213), at stage III—16% (26/160), and at stage IV—2% (2/93). Patients with MSI tumors differed in the age of diagnosis, tumor localization, time of cancer recurrence, and stage of the disease. The overall and disease-free survival of patients whose tumors had MSI status was higher than that of patients with microsatellite-stable status, p = 0.04 and p = 0.02, respectively. Analysis of overall and disease-free survival of patients with Lynch syndrome and patients with sporadic colon cancer, but with MSI status, did not reveal significant differences, p = 0.52 and p = 0.24, respectively. The age of patients with Lynch syndrome was significantly younger than that of patients with sporadic colon cancer whose tumors had MSI status (p < 0.001). 相似文献