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排序方式: 共有197条查询结果,搜索用时 15 毫秒
1.
Ana Mafalda RibeiroJosé Miguel Loureiro 《Chemical engineering science》2002,57(9):1621-1626
The system ASC carbon filter/cyanogen chloride was studied by simulation. Three filter configurations and several models, taking into account Langmuir adsorption and second-order reaction between the adsorbed toxic vapour and the active metal on the surface, were developed.The effects of axial dispersion, number of reaction units, film mass transfer units and intraparticle mass transfer resistance on the breakthrough time were studied.Simulation results show that a complex model should be used in order to predict with reasonable accuracy the protection imparted by these filters. 相似文献
2.
Residual Stress Evolution in Repair Welds 总被引:1,自引:0,他引:1
Abstract: The aim of this paper is to study the influence of the repair procedure on the evolution of residual stress distribution in butt welds. C-Mn steel coupon plates of 11 mm thickness were prepared, subjected to stress relief heat treatment and welded with two beads, using the gas metal arc welding process. After the deposition of two weld beads, two successive repair welds were made on the middle length of the second bead. Longitudinal and transverse residual stresses were measured in the vicinity of the weld, after deposition of the two weld beads and after each repair weld. Residual stress evaluation was conducted using an X-ray diffraction method. The repair welds caused a decrease in magnitude of the initial longitudinal residual welding stresses, and an increase of the transverse residual stress magnitude, in tension at points within the repair length, and in compression at points outside the repair length. 相似文献
3.
S. M. Loureiro E. V. Antipov J. J. Capponi M. Marezio 《Materials Research Bulletin》1995,30(12):1463-1470
Samples of the [Hg1 − xCx]-Ba2CuOy system [(Hg,C)-1201] with stoichiometries within the range 0.00≤x≤1.00 were synthesized by a highpressure, high-temperature technique. The sample with X = 0.00 [HgBa2CuO4+δ] was non-superconducting with lattice parameters A = 3.8676(2) Å, C = 9.470(1) Å. At low ranges of substitution (0.10≤x≤0.30), the predominant phase was found to be Hg-1201 with identical lattice parameters to those found for X = 0.00. At X = 0.40 the Hg-1201 phase coexists in similar proportions with the phase of mixed [Hg1 − x,Cx]-1201 stoichiometry. At X = 0.50, this second phase with lattice parameters A = 3.9271(3) Å, C = 8.676(2) Å is predominant and only traces of the Hg-1201 phase were found. At X = 0.75 the [Hg1 − x,Cx]-1201 phase found for X = 0.50 coexists with the CO3Ba2CuOy phase, which is the extreme of the substitution range. This latter was predominant at X = 1.00 with lattice parameters A = 4.0044(3) Å, C = 7.909(1) Å, but at higher pressure than the previous substitutions. This system is constituted of three main phases, HgBa2CuO4 + δ, Hg1 − xCxBa2CuOy (x ≈ 0.50) and CO3Ba2CuOy, which appear in different proportions according to the percentage of substitution and the applied synthesis pressure. 相似文献
4.
Vinícius D. Silva Rafael A. Raimundo Thiago A. Simões Francisco J.A. Loureiro Duncan P. Fagg Marco A. Morales Daniel A. Macedo Eliton S. Medeiros 《International Journal of Hydrogen Energy》2021,46(5):3798-3810
The development of technologically efficient anodes for water oxidation is crucial to improve hydrogen production via water splitting. Electrodes based on metallic active sites dispersed in carbon matrices have been shown to be an attractive way to attain this goal. However, challenges remain to prevent catalyst agglomeration that otherwise can result in a decrease of performance over time.In this work, we report an alternative and efficient method to produce nickel-nickel oxide nanoparticles-embedded in carbon nanofibers (Ni–NiO/C), by the solution blow spinning (SBS) process. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analyses show the carbon nanofibrillar matrix as a robust support, with well-dispersed nickel nanoparticles on the surface. The responses of the linear scanning voltammetry, cyclic voltammetry and electrochemical impedance spectroscopy demonstrate how a small fraction of nickel on the fiber surface (≈1.2–5.3%) is enough to promote substantial improvement in performance (η = 278 and 309 mV vs RHE for 10 mA cm?2) and a significant turnover frequency (TOF) values of 1.38 (η = 278) and 1.30 s?1 (η = 309). These promising results are correlated with a large amount of Ni3+ present on the fiber surfaces, as identified by X-ray Photoelectron Spectroscopy (XPS). This work provides a low-cost and rapid preparation technique that can be extended for the manufacture of a wide variety of electrodes based on metals supported on carbon nanofibers. 相似文献
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6.
Igor de Mesquita Figueredo Francisco Murilo Tavares de Luna Célio Loureiro Cavalcante Jr Maria Alexsandra de Sousa Rios 《Journal of the American Oil Chemists' Society》2020,97(12):1355-1363
In this study, three antioxidants namely N,N′-di-sec-butyl-p-phenylenediamine (PDA), 2,4,6-Tri-tert-butylphenol/2,6-Di-tert-butylphenol (IONOL), and unsaturated cardanol (U-CDN) were added to babassu biodiesel (BB) at a concentration of 100 mg kg−1 to improve its oxidative stability. Differential Scanning Calorimetry (DSC) was used to evaluate the oxidative stability of the samples using synthetic air atmosphere and two temperatures (25 and 110 °C) instead of the conventional Rancimat method. The kinetic parameters were calculated according to Borchardt and Daniels method (ASTM E2041). All doped samples showed higher thermo-oxidative stability when compared to pure babassu biodiesel with increasing activation energies of 66.5% for PDA, 19.4% for IONOL, and 3.9% for U-CDN. At 25 °C, the babassu biodiesel showed a high oxidation reaction rate of 1.76 × 10−15 min−1. For the doped samples at the same temperature, that rate was reduced by a factor of 2, 200, and 3 × 108 times for U-CDN, IONOL, and PDA, respectively. At 110 °C, the BB and the BB + U-CDN samples showed high reaction rates, whereas the formulations with IONOL and PDA had rates reduced by 10 and 7.4 × 103 times, respectively. The thermal data showed R2 values higher than 0.99. All results confirmed the action of the antioxidants in retarding oxidation reactions in biodiesel. DSC is a promising alternative method for the determination of oxidative stability of biodiesel and its formulations with antioxidants. 相似文献
7.
8.
Joana Tavares Dr. Ali Ouaissi Dr. Paul Kong Thoo Lin Prof. Dr. Inês Loureiro Simranjeet Kaur Nilanjan Roy Dr. Anabela Cordeiro‐da‐Silva Prof. Dr. 《ChemMedChem》2010,5(1):140-147
The NAD+‐dependent deacetylases, namely sirtuins, are involved in the regulation of a variety of biological processes such as gene silencing, DNA repair, longevity, metabolism, apoptosis, and development. An enzyme from the parasite Leishmania infantum that belongs to this family, LiSIR2RP1, is a NAD+‐dependent tubulin deacetylase and an ADP‐ribosyltransferase. This enzyme's involvement in L. infantum virulence and survival underscores its potential as a drug target. Our search for selective inhibitors of LiSIR2RP1 has led, for the first time, to the identification of the antiparasitic and anticancer bisnaphthalimidopropyl (BNIP) alkyl di‐ and triamines (IC50 values in the single‐digit micromolar range for the most potent compounds). Structure–activity studies were conducted with 12 BNIP derivatives that differ in the length of the central alkyl chain, which links the two naphthalimidopropyl moieties. The most active and selective compound is the BNIP diaminononane (BNIPDanon), with IC50 values of 5.7 and 97.4 μM against the parasite and human forms (SIRT1) of the enzyme, respectively. Furthermore, this compound is an NAD+‐competitive inhibitor that interacts differently with the parasite and human enzymes, as determined by docking analysis, which might explain its selectivity toward the parasitic enzyme. 相似文献
9.
10.
I. Galvão R.M. Leal D.M. Rodrigues A. Loureiro 《Journal of Materials Processing Technology》2013,213(2):129-135
The aim of this work is to study the influence of the shoulder geometry on friction stir welding of 1 mm-thick copper-DHP plates. The welds were produced using three different shoulder geometries, flat, conical and scrolled, and varying the rotation and traverse speeds of the tool. The flat shoulder tool proved to be inadequate for performing welds, because many defects were produced for all welding conditions. In turn, the scrolled shoulder tool is more effective than the conical one in the production of defect free welds. However, both geometries required a minimum rotational speed to avoid internal defects. For the same welding parameters, greater grain refinement, higher hardness and improved strength are also achieved in the nugget of the welds, using the scrolled tool. 相似文献