介孔氧化铁对正辛醇乙氧基化反应的催化性能

以十二烷基磺酸钠为模板剂、乙二胺为碱性介质,将水热法合成的氧化铁/十二烷基磺酸钠复合中孔材料在550℃、空气气氛中煅烧10h,除去模板剂,得到介孔氧化铁。通过X射线衍射、氮气吸附-脱附方法对介孔氧化铁的晶体结构和表面物性进行表征。表征结果显示,煅烧后的介孔氧化铁具有典型的六方介孔的结构特征,平均孔径为5.4nm。将介孔氧化铁用于催化正辛醇乙氧基化反应,研究结果表明,升高反应温度和初始压力、增加催化剂用量,可加快环氧乙烷的反应速率,同时产物的相对分子质量分布较窄。当平均聚合度为6.5时,正辛醇聚氧乙烯醚相对分子质量分布的选择性系数达到21.1。     

Viscoelastic properties of polyarylene ether nitriles/thermotropic liquid crystalline polymer blend

Polyarylene ether nitriles (PEN)/thermotropic liquid crystalline polymer (TLCP) blend was prepared via melt mixing. The immiscible phase morphologies, linear and nonlinear, as well as transient viscoelastic properties of the blend were studied using SEM, rheometer, and DMA. The linear dynamic viscoelastic behavior of the blend shows temperature dependence due to further evolution of the immiscible morphology and, as a result, the principle of time‐temperature superposition (TTS) is invalid. In the steady shear flow, the discrete TLCP phase is difficult to be broken up because of the high viscosity ratio of the blend systems, while is easy to be coarsened and followed by elongation, and finally, to form fibrous morphology at high TLCP content and high shear level. During this morphological evolution process, the transient stress response presents step increase and nonzero residual relaxation behavior, leading to increase of the dynamic viscoelastic responses after steady preshear. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Neural networks modeling signal responses and taxol production of cultured Taxus chinensis cells induced by bio-elicitor

Quantitatively describing the signal transduction process is important for understanding the mechanism of signal regulation in cells, and thus, poses both a challenge and an opportunity for chemical and biochemical engineers. An artificial neural network (ANN), in which we took the signal molecules as neural nodes, was constructed to simulate the generation of active oxygen species (AOS) in Taxus chinensis cells induced by a bio-elicitor. The relative contents of AOS in cells predicted by the ANN model agreed well with the experimental data and three notable stages of AOS increase were observed from the 3D figure of AOS generation. The robustness of AOS trajectories indicated that signal regulation in vivo was an integral feedback control model that ensured the adaptation of Taxus chinensis to environmental stress. The artificial neural network was able to predict taxol production as well as determine the optimal concentration of oligosaccharides needed for it.     

双黄隆反相高效液相色谱分析

本文报道用反相高效液相色谱分析双黄隆可湿性粉剂，其有效成分甲黄隆、绿黄隆含量的方法，以甲醇和１％乙酸钠水溶液作流动相，以香豆素为内标物，在２５４纳米下检测。甲黄隆、绿黄隆变异系数分别为０．３４％、０．６１％。     

浅埋薄基岩工作面覆岩活动规律三维物理相似模拟研究（研究生论坛）

针对浅埋采场在开采活动中经常出现矿压显现剧烈、顶板和地表台阶下沉等问题,以神东矿区为背景,采用三维物理模拟试验研究浅埋深薄基岩工作面覆岩活动规律。模型试验尺寸为长×宽×高=1050mm×2000mm×1130mm,几何相似比为1:100,容重相似比为1:1.67,时间相似比为1:10,应力比为1:1.67。监测模型地表位移变化和顶板位移变化规律。结果表明：浅埋薄基岩煤层开采过程中,上覆岩层只出现冒落带和裂隙带,煤层直接顶随采随冒,基本顶初次来压步距为40m,周期来压步距为20m;上覆岩层及松散层出现台阶下沉现象,裂缝贯通地表,切眼和停采线附近出现溃沙现象,地表形成塌陷坑;上覆岩层运动以垂直运动为主,随着工作面向前推进,顶板位移增加;靠近煤柱的上覆岩层出现搭桥结构,靠近煤柱的上覆岩层位移变化量较小,而远离煤柱的测点上覆岩层位移变化量较大;地表位移变化和上覆岩层位移变化整体上具有正相关性,但地表位移变化幅度较小、具有滞后性,且受到溃沙现象的影响,切眼和停采线附近地表形成塌陷坑且地表位移变化量增大。     

Reaction kinetics study of asymmetric polymer-polymer interface

In this study, the reaction kinetics of asymmetric polymer-polymer interface was experimentally and theoretically studied. A new rheological method correlating the change of rheological property of reactive system with the conversion of the in situ formed copolymers was applied to study the reaction kinetics of PBT/epoxy reactive system. Then, the new method was proved to be useful by comparing its results with that obtained from the conventional endgroup determination method. Moreover, the conversion of PBT/epoxy reactive system from rheological method could be well fitted by the numerical analysis, from which the kinetic constant and the diffusion constant of epoxy in PBT could be determined simultaneously.     

15%田草灵高效液相色谱分析

采用Ｎｏｖａ－Ｐａｋ Ｃ１８不锈钢色谱柱进行反相液相色谱分析，以甲醇：水＝６５：３５（Ｖ／Ｖ）为注动相，以邻苯二甲醇二乙酯为内标物，用内标法测定田草灵除草剂中苄嘧黄隆和异丙甲草胺的含量，结果表明，各有效成分与内标物色谱峰分离完全，杂质无干扰，测定结果，苄嘧黄隆和异丙甲草胺的变异系数分别为０．７４％和１．０７％，回收率分别为９９．４％￣１００．８％和９９．１％￣１０１．３％。     

Nonisothermal crystallization kinetics of poly(butylene terephthalate)/montmorillonite nanocomposites

The melt intercalation method was employed to prepare poly(butylene terephthalate) (PBT)/montmorillonite (MMT) nanocomposites, and the microstructures were characterized with X‐ray diffraction and transmission electron microscopy. Then, the nonisothermal crystallization behavior of the nanocomposites was studied with differential scanning calorimetry (DSC). The DSC results showed that the exothermic peaks for the nanocomposites distinctly shifted to lower temperatures at various cooling rates in comparison with that for pure PBT, and with increasing MMT content, the peak crystallization temperature of the PBT/MMT hybrids declined gradually. The nonisothermal crystallization kinetics were analyzed by the Avrami, Jeziorny, Ozawa, and Mo methods on the basis of the DSC data. The results revealed that very small amounts of clay (1 wt %) could accelerate the crystallization process, whereas higher clay loadings reduced the rate of crystallization. In addition, the activation energy for the transport of the macromolecular segments to the growing surface was determined by the Kissinger method. The results clearly indicated that the hybrids with small amounts of clay presented lower activation energy than PBT, whereas those with higher clay loadings showed higher activation energy. The MMT content and the crystallization conditions as well as the nature of the matrix itself affected the crystallization behavior of the hybrids. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3257–3265, 2006     

混杂PVA-ECC配合比优化设计及力学性能试验研究

为了降低工程用水泥基复合材料(ECC, Engineered Cementitious Composites)制造成本,使ECC能够在实际工程中大规模应用,将中国产PVA纤维和日本产PVA纤维以一定的比例混合,配制混杂PVA-ECC。基于ECC的材料设计理论,兼顾抗压强度和受拉能力,对掺有硅粉的混杂PVA-ECC中的纤维体积含量进行了优化设计。通过四点弯曲试验和轴心抗压试验,研究了混杂PVA-ECC在不同龄期下的弯曲性能和抗压性能。试验结果表明,混杂PVA-ECC试件均表现出明显的应变硬化和多缝开裂的特征,此外,其抗压强度后期增长明显。基于UM法,提出一种改进的反分析方法,可利用四点弯曲试验结果推导ECC的极限拉伸应变,并与试验结果进行了比较,结果表明,通过建议的反分析方法得到的预测值与试验值吻合较好。     

ZL201曲面薄壁件挤压铸造工艺及模具设计

根据厂家提出的要求、结合帽盖零件产品结构特点和加工难度,确定了用ZL201合金挤压铸造成形工艺制坯,替代LY12合金棒料生产曲面薄壁帽盖零件,设计并制造了两套帽盖零件毛坯挤压铸造模具.两套模具的区别主要在凹模部分,其中一套属于间接加压,凹模带有溢料槽,另一套属于直接加压,凹模为组合式.