Gallium gradients in Cu(In,Ga)Se2 thin‐film solar cells

The gallium gradient in Cu(In,Ga)Se₂ (CIGS) layers, which forms during the two industrially relevant deposition routes, the sequential and co‐evaporation processes, plays a key role in the device performance of CIGS thin‐film modules. In this contribution, we present a comprehensive study on the formation, nature, and consequences of gallium gradients in CIGS solar cells. The formation of gallium gradients is analyzed in real time during a rapid selenization process by in situ X‐ray measurements. In addition, the gallium grading of a CIGS layer grown with an in‐line co‐evaporation process is analyzed by means of depth profiling with mass spectrometry. This gallium gradient of a real solar cell served as input data for device simulations. Depth‐dependent occurrence of lateral inhomogeneities on the µm scale in CIGS deposited by the co‐evaporation process was investigated by highly spatially resolved luminescence measurements on etched CIGS samples, which revealed a dependence of the optical bandgap, the quasi‐Fermi level splitting, transition levels, and the vertical gallium gradient. Transmission electron microscopy analyses of CIGS cross‐sections point to a difference in gallium content in the near surface region of neighboring grains. Migration barriers for a copper‐vacancy‐mediated indium and gallium diffusion in CuInSe₂ and CuGaSe₂ were calculated using density functional theory. The migration barrier for the In_Cu antisite in CuGaSe₂ is significantly lower compared with the Ga_Cu antisite in CuInSe₂, which is in accordance with the experimentally observed Ga gradients in CIGS layers grown by co‐evaporation and selenization processes. Copyright © 2014 John Wiley & Sons, Ltd.     

布鲁塞尔弗拉基文场

圣克洛克斯广场、弗拉基广场和湖区是一个充满活力的多样化城市公共空间.弗拉基广场作为其中历史悠久的中心区域,具有至关重要的地位.因此设计需要将弗拉基广场与整个城市氛围相融合,并且为行人创造一处连续的人性场所.     

Engineering metal-impurity nanodefects for low-cost solar cells

As the demand for high-quality solar-cell feedstock exceeds supply and drives prices upwards, cheaper but dirtier alternative feedstock materials are being developed. Successful use of these alternative feedstocks requires that one rigorously control the deleterious effects of the more abundant metallic impurities. In this study, we demonstrate how metal nanodefect engineering can be used to reduce the electrical activity of metallic impurities, resulting in dramatic enhancements of performance even in heavily contaminated solar-cell material. Highly sensitive synchrotron-based measurements directly confirm that the spatial and size distributions of metal nanodefects regulate the minority-carrier diffusion length, a key parameter for determining the actual performance of solar-cell devices. By engineering the distributions of metal-impurity nanodefects in a controlled fashion, the minority-carrier diffusion length can be increased by up to a factor of four, indicating that the use of lower-quality feedstocks with proper controls may be a viable alternative to producing cost-effective solar cells.     

Sichtbarmachung von Strömungen in Luft

Zusammenfassung Die Sichtbarmachung von Luftstr?mungen h?ngt von Gewicht, Schwebef?higkeit und Leuchkraft des beigemengten Stoffes ab. Als solcher hat sich in neuerer Zeit durch Erhitzen in Flockenform überführtes Metaldehyd recht brauchbar erwiesen. Nachstehend wird über von Str?mungen um K?rper berichtet; die hierbei gewonnenen photographischen Aufanhamen werden gezeigt. VDI VDI     

废弃场地的质变

本文论述了如何将废弃的景观,如工业设施、铁路、污水管等转变成公共空间,花园和公园。这种质变手法引发了新的美学和历史观。本文所阐述的理念也在努力实现生态的原则。这些项目既是全自然的又是全人工的。     

Electrical characteristics of low temperature-Al0.3Ga0.7As

In this work, we present electrical characterizations of n⁺ GaAs/low temperature (LT)-Al_0.3Ga_0.7As/n⁺ GaAs resistor structures in which the LT layers are grown at nominal substrate temperatures of 250 and 300°C. The resistivity and V_tfl parameters of these LT-Al_0.3Ga_0.7As layers are compared with those of LT-GaAs and Al_0.3Ga_0.7As grown at a normal growth temperature of 720°C. Low-temperature Al_0.3Ga_0.7As layers exhibit resistivities as high as 10¹² ohm-cm, nearly four orders of magnitude higher than that of LT-GaAs, and V_tfl values as high as 45 V, over twice that of LT-GaAs. We also find that the LT-Al_0.3Ga_0.7As materials grown at 250 and 300°C appear to show opposite and contradictory trends with respect to resistivity and V_tfl. We propose that this result can be explained by residual hopping conduction in the 250°C material. Temperature dependent conductivity measurements confirm the presence of a hopping mechanism in LT-Al_0.3Ga_0.7As grown at 250°C and yield activation energies of 0.77 and 0.95 eV for LT-GaAs and LT-Al_0.3Ga_0.7As, respectively.     

布鲁塞尔弗拉基广场

圣克洛克斯广场、弗拉基广场和湖区是一个充满活力的多样化城市公共空间。弗拉基广场作为其中历史悠久的中心区域,具有至关重要的地位。因此设计需要将弗拉基广场与整个城市氛围相融合,并且为行人创造一处连续的人性场所。改造后,被街     

Vezatin, a ubiquitous protein of adherens cell-cell junctions, is exclusively expressed in germ cells in mouse testis

In the male reproductive organs of mammals, the formation of spermatozoa takes place during two successive phases: differentiation (in the testis) and maturation (in the epididymis). The first phase, spermiogenesis, relies on a unique adherens junction, the apical ectoplasmic specialization linking the epithelial Sertoli cells to immature differentiating spermatids. Vezatin is a transmembrane protein associated with adherens junctions and the actin cytoskeleton in most epithelial cells. We report here the expression profile of vezatin during spermatogenesis. Vezatin is exclusively expressed in haploid germ cells. Immunocytochemical and ultrastructural analyses showed that vezatin intimately coincides, temporally and spatially, with acrosome formation. While vezatin is a transmembrane protein associated with adherens junctions in many epithelial cells, it is not seen at the ectoplasmic specializations, neither at the basal nor at the apical sites, in the seminiferous epithelium. In particular, vezatin does not colocalize with espin and myosin VIIa, two molecular markers of the ectoplasmic specialization. In differentiating spermatids, ultrastructural data indicate that vezatin localizes in the acrosome. In epididymal sperm, vezatin localizes also to the outer acrosomal membrane. Considering its developmental and molecular characteristics, vezatin may be involved in the assembly/stability of this spermatic membrane.     

Impact of grey energy on optimal wall insulation thickness

For decades efforts have been made to reduce the greenhouse gases emissions of buildings by reducing their energy demand with governmental regulations in Europe, pushing towards very low thermal transmittances (U-values) with ever thicker insulation layers for new buildings. However, there is no linear relationship between the insulation thickness and the heat losses. Therefore, above a certain thickness the consumption of buildings does not decrease significantly. Hereafter a life cycle analysis, including emissions before the building becomes operational is applied to evaluate the impact of the increasing thickness of components on the overall emissions. Publicly available product data sheets are used to compare four insulation materials under three scenarios. These analyses yield interesting results showing that energy-intensive insulation materials lead to a negative impact in the overall energy balance after a certain thickness. Even though there is not always a pronounced optimum insulation thickness, it is logical that further reductions in U-value for new buildings should hence be carefully evaluated. The results show that the optimal thickness is around 20 cm for most materials, while the important major savings come from the first 10 cm.