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The condensation heat transfer efficiencies of superhydrophobic surfaces that have ∼160° contact angle under atmospheric conditions were investigated experimentally. The departing diameter and the contact angle hysteresis of droplets were measured by capturing front and tilted side views of condensation phenomena with a high speed camera and an endoscope, respectively. Condensation behaviors on the surface were observed at the micro-scale using an Environmental scanning electron microscope (ESEM). Apparently-spherical droplets formed at very low heat flux q″ ∼20 kW/m2 but hemispherical droplets formed at high q″ ∼440 kW/m2. At high q″, heat transfer coefficients were lower on the superhydrophobic surface than on a hydrophobic surface although the superhydrophobic surface is water repellent so droplets roll off. The results of contact angle hysteresis and ESEM image revealed that the reduced heat transfer of the surface can be attributed to the large size of departing droplets caused by adhesive condensed droplets at nucleation sites. The results suggest that the effect of q″ or degree of sub-cooling of a condensation wall determine the droplet shape, which is closely related to removal rates of condensates and finally to the heat transfer coefficient.

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