Simulation and Modeling-implementing GaAs device models with SPICE

A method for evaluating the accuracy of a device model and its tendency toward convergence problems before implementing it as a SPICE primitive is presented. Two different GaAs MESFET models suitable for analyzing nonlinear analog and microwave circuits are implemented using generic SPICE primitives. It is shown that no modification to the SPICE program is required. Controlled sources are extensively used in implementing the models using this method     

Vinyl acetate monomer—a pilot plant study

The kinetics of the reaction of acetic acid and acetylene over zinc acetate-activated carbon catalyst was investigated over a wide range of process variables in a pilot reactor. Although various catalytic reaction mechanisms were postulated, the rate of reaction was most satisfactorily correlated by a mechanism of surface reaction between charged adsorbed acetic acid and acetylene, which assumes that the rate controlling step was the irreversible charged adsorption of acetylene and acetic acid.     

NMR studies of poly(2-hydroxy ethyl methacrylate-co-2-vinyl pyridine)

Copolymers of 2-hydroxy ethyl methacrylate-2-vinyl pyridine (H/V) of different composition were synthesized by free radical bulk polymerization using azobisisobutyronitrile (AIBN) as an initiator under nitrogen atmosphere. The copolymer compositions were calculated from ¹H NMR spectra. The reactivity ratios for H/V copolymers obtained from a linear Kelen-Tudos method (KT) and nonlinear error-in-variables method (EVM) are r_H = 0.50 ± 0.10, r_V = 1.04 ± 0.08 and r_H = 0.55, r_V = 1.06 respectively. The complete spectral assignment of methine, methylene, methyl, carbonyl, and aromatic carbon regions in term of compositional and configurational sequences of H/V copolymers were done with the help of ¹³C{¹H} NMR, distortionless enhancement by polarization transfer (DEPT), two-dimensional heteronuclear single quantum coherence (HSQC) along with total correlated spectroscopy (TOCSY). © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Application of orthogonal collocations to some transport phenomena problems in co-axial cylinders and spheres

Collocation methods are developed for the solution of some differential equation models for transport phenomena problems in one-and two-dimensions in co-axial annuli of spherical and cylindrical shapes. General formulae are developed to obtain orthogonal polynomials over an arbitrary interval using two types of weighting functions. The convergence and accuracy of the methods are demonstrated using two test problems, i.e., calculation of effectiveness factors in (a) a spherical pellet with peripherally deposited catalyst and (b) a Raschig ring type cylindrical catalyst pellet. Comparisons of results obtained from the present methods with analytic solutions for the first-order reactions indicate good agreement. Numerical solutions are also obtained for the second-and the third-order reactions for which analytic solutions are not available. Results obtained in terms of a new Thiele modulus involving the ratio of volume of peripherally deposited part of catalyst to exterior surface area indicate that this normalization brings effectiveness factor versus Thiele modulus curves close together for co-axial spherical and long cylindrical pellets, as it does for these geometries without the inner co-axial portion.     

Condition Monitoring Parameters for Fault Diagnosis of Fixed Axis Gearbox: A Review

Condition monitoring of gearboxes which is considered as a key element of rotating machines ensures to continuously reduce and eliminate cost, unscheduled downtime and unexpected breakdowns. Although, a lot of work on condition monitoring and fault diagnosis of fixed-axis gearbox has been reported in the literature, however only a few have found their way to industrial applications. The ability of condition statistical indicators is to provide accurate and precise information about the health of various components at different levels of damage. In this paper, frequently used condition indicators are addressed domain-wise and their characteristics are stated. This paper presents the review of work to provide a wide and good reference for researchers to be utilized. The structure of a fixed-axis gearbox in addition to the unique behaviors and fault characteristics of fixed-axis gearbox has been recognized and represented. By extensively reviewing and categorizing important papers and articles, this paper is able to summarize the conditional monitoring indicators on basis of adopted methodologies. Lastly, open problems are stated and further research prospects pointed out.     

Electron Transfer in a Bio-Photoelectrode Based on Photosystem I Multilayer Immobilized on the Conducting Glass

A film of ~40 layers of partially oriented photosystem I (PSI) complexes isolated from the red alga Cyanidioschyzon merolae formed on the conducting glass through electrodeposition was investigated by time-resolved absorption spectroscopy and chronoamperometry. The experiments were performed at a range of electric potentials applied to the film and at different compositions of electrolyte solution being in contact with the film. The amount of immobilized proteins supporting light-induced charge separation (active PSI) ranged from ~10%, in the absence of any reducing agents (redox compounds or low potential), to ~20% when ascorbate and 2,6-dichlorophenolindophenol were added, and to ~35% when the high negative potential was additionally applied. The origin of the large fraction of permanently inactive PSI (65–90%) was unclear. Both reducing agents increased the subpopulation of active PSI complexes, with the neutral P700 primary electron donor, by reducing significant fractions of the photo-oxidized P700 species. The efficiencies of light-induced charge separation in the PSI film (10–35%) did not translate into an equally effective generation of photocurrent, whose internal quantum efficiency reached the maximal value of 0.47% at the lowest potentials. This mismatch indicates that the vast majority of the charge-separated states in multilayered PSI complexes underwent charge recombination.     

Generalized guaranteed rate scheduling algorithms: a framework

In this paper, we define a class of generalized guaranteed rate (GR) scheduling algorithms that includes algorithms which allocate a variable rate to the packets of a flow. We define work-conserving generalized virtual clock, packet-by-packet generalized processor sharing, and self-clocked fair queueing scheduling algorithms that can allocate a variable rate to the packets of a flow. We also define scheduling algorithms suitable for servers where packet fragmentation may occur. We demonstrate that if a class of rate controllers is employed for a flow in conjunction with any scheduling algorithm in GR, then the resulting non-work-conserving algorithm also belongs to GR. This leads to the definition of several non-work-conserving algorithms. We then present a method for deriving the delay guarantee of a network of servers when: (1) different rates are allocated to packets of a flow at different servers along the path and the bottleneck server for each packet may be different, and (2) packet fragmentation and/or reassembly may occur. This delay guarantee enables a network to provide various service guarantees to flows conforming to any specification. We illustrate this by utilizing delay guarantee to derive delay bounds for flows conforming to leaky bucket, exponentially bounded burstiness, and flow specification. Our method for determining these bounds is valid in internetworks and leads to tighter results     

An Efficient Data Delivery Scheme in WBAN to Deal with Shadow Effect due to Postural Mobility

The body movement and change in posture exhibit high mobility in sensor nodes which causes shadowing in the Wireless Body Area Network (WBAN). Due to this, the connectivity between the nodes in WBAN is affected which further causes failure in data delivery. This article presents a MAC protocol in WBAN to deal with the problem of data delivery due to body movement and postural mobility. It uses an Improved Initial Centroid K-means clustering technique for classification of various human body postures followed by back propagation neural network as a classifier to recognize human body posture. This article proposes a posture aware dynamic data delivery (PA-DDD) protocol to deliver data dynamically. The PA-DDD protocol can be used under varying speed walking scenario. The simulation results show that it prolongs the network lifetime and is energy efficient.

     

Self‐Assembly of Nanostructured,Complex, Multication Films via Spontaneous Phase Separation and Strain‐Driven Ordering

Spontaneous self‐assembly of a multication nanophase in another multication matrix phase is a promising bottom‐up approach to fabricate novel, nanocomposite structures for a range of applications. In an effort to understand the mechanisms for such self‐assembly, complimentary experimental and theoretical studies are reported to first understand and then control or guide the self‐assembly of insulating BaZrO₃ (BZO) nanodots within REBa₂Cu₃O_7–δ (RE = rare earth elements including Y, REBCO) superconducting films. The strain field developed around BZO nanodots embedded in the REBCO matrix is a key driving force dictating the self‐assembly of BZO nanodots along REBCO c‐axis. The size selection and spatial ordering of BZO self‐assembly are simulated using thermodynamic and kinetic models. The BZO self‐assembly is controllable by tuning the interphase strain field. REBCO superconducting films with BZO defect arrays self‐assembled to align in both vertical (REBCO c‐axis) and horizontal (REBCO ab‐planes) directions result in the maximized pinning and J_c performance for all field angles with smaller angular J_c anisotropy. The work has broad implications for the fabrication of controlled self‐assembled nanostructures for a range of applications via strain‐tuning.