Compressive properties of pristine and SiC-Te-added MgB2 powders,green compacts and spark-plasma-sintered bulks

Pristine and (SiC+Te)-added MgB₂ powders, green and spark plasma sintered (SPS) compacts were investigated from the viewpoint of quasi-static and dynamic (Split-Hopkinson Pressure Bar, SHPB) compressive mechanical properties The amount of the additive (SiC+Te) was selected to be the optimum one for maximization of the superconducting functional parameters. Pristine and added MgB₂ show very similar compressive parameters (tan δ, fracture strength, Vickers hardness, others) and fragment size in the SHPB test. However, for the bulk SPSed samples the ratio of intergranular to transgranular fracturing changes, the first one being stronger in the added sample. This is reflected in the quasi-static K_IC that is higher for the added sample. Despite this result, sintered samples are brittle and have roughly similar fragmentation behavior as for brittle engineering ceramics. In the fragmentation process, the composite nature of our samples should be considered with a special focus on MgB₂ blocks (colonies) that show the major contribution to fracturing. The Glenn-Chudnovsky model of fracturing under dynamic load provides the closest values to our experimental fragment size data.     

Tree-Based Concurrency Control in Distributed Groupware

We present a novel algorithm, called dARB, forsolving the concurrency control problem indistributed collaborative applications. Themain issue of concurrency control is resolvingthe conflicts resulting from simultaneousactions of multiple users. The algorithmreduces the need for manual conflict resolutionby using a distributed arbitration scheme. Themain advantages of our approach are thesimplicity of use and good responsiveness, asthere are no lock mechanisms. Our algorithmrequires the applications to use a tree as theinternal data structure. This makes itapplication independent and suitable forgeneral collaborative applications. The treerequirement is reasonable since many newapplications use XML (extensible MarkupLanguage) for data representation and exchange,and parsing XML documents results in treestructures. Example applications of thealgorithm, a group text editor and acollaborative 3D virtual environment calledcWorld, are implemented and evaluated in theDISCIPLE collaboration framework. We alsointroduce awareness widgets that users avoidgenerating the conflicting events and help inmanual conflict resolution.     

Evidence of flexoelectricity in polymer-dispersed liquid crystals

The linear electro-optic response of polymer-dispersed liquid crystal films has been studied. Micrometer-sized droplets of a cyanobiphenyl mixture (E7) were formed in a Norland Optical Adhesive 65 photopolymer by photopolymerization-induced phase separation. Samples with various average nematic droplet sizes were systematically investigated. The temperature dependence of the first-harmonic electro-optic spectra was obtained. Peculiar peaks and double peaks in the phase spectra were found at temperatures close to the clearing point. Samples with narrow distributions of droplet sizes were characterized by a double peak of the amplitude spectra in the low-frequency range. A flexoelectric origin of the first-harmonic spectra in confined nematic systems is discussed.     

Self-ignition and mechanisms of interaction of coal with oxygen at low temperatures. 1. Changes in the composition of coal heated at constant rate to 250 °C in air

The changes in weight, in elementary composition, in content of oxygen functional groups and in spin concentration of lignite, brown and black coal samples heated in a stream of humid air at a rate of 1 °C/min to various temperatures have been determined I.r. spectra of oxidized and non-oxidized brown coal are recorded and the yields of CO, CO₂ and H₂O were measured. The mixtures of low-molecular-weight hydrocarbons evolved before self-ignition were analysed by gas chromatography, and the temperatures of self-ignition were determined in an oxygen stream using a Leitz microscope. A region of coal oxidation was identified where the hydrogen content remained invariable or increased, indicating an interaction of coal with water in the presence of oxygen. For the next region the atomic ratio H/C of the overall gaseous product was found to be high (6 to 10). Self-ignition was found to occur in this region. The results permit coal oxidation to be considered as a redox process. The aromatic part of coal is believed to act as an oxidizing agent in the region where hydrogen is less affected by molecular oxygen.     

Interface between electroless amorphous Ni–Cu–P coatings and Al substrate

The initial phase arising at the interface with aluminum substrate during electroless deposition of amorphous high phosphorus (16–19 at.%) Ni–Cu–P alloy with alloyed copper 1.7–3.4 at.% is studied. Stripped deposit foils are inspected by Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy coupled with energy dispersive X-ray analysis (TEM-EDX). Depending on the plating conditions, various particles, some of them crystalline, are revealed at the foils sides formerly adhering to the substrate. EDX analysis of the crystallites shows diverse copper contents of about 34–64 at.%, without any phosphorus. Electron diffraction analysis indicates a lattice structure very close to that of Cu. The presence of a phase without phosphorus and enriched in copper at the interface with the Al substrate is also confirmed by Auger electron spectroscopy. This initially arising crystalline phase might exert a limited effect on the main properties of bulk Ni–Cu–P deposits: the composition uniformity through the thickness, amorphous structure and paramagnetic behavior. A modification of the plating process is recommended, which is decreasing the probability of inhomogeneities formation.     

Laser-Printed Plasmonic Metasurface Supporting Bound States in the Continuum Enhances and Shapes Infrared Spontaneous Emission of Coupled HgTe Quantum Dots

In order to advance the development of quantum emitter-based devices, it is essential to enhance light-matter interactions through coupling between semiconductor quantum dots with high quality factor resonators. Here, efficient tuning of the emission properties of HgTe quantum dots in the infrared spectral region is demonstrated by coupling them to a plasmonic metasurface that supports bound states in the continuum. The plasmonic metasurface, composed of an array of gold nanobumps, is fabricated using single-step direct laser printing, opening up new opportunities for creating exclusive 3D plasmonic nanostructures and advanced photonic devices in the infrared region. A 12-fold enhancement of the photoluminescence in the 900–1700 nm range is observed under optimal coupling conditions. By tuning the geometry of the plasmonic arrays, controllable shaping of the emission spectra is achieved, selectively enhancing specific wavelength ranges across the emission spectrum. The observed enhancement and shaping of the emission are attributed to the Purcell effect, as corroborated by systematic measurements of radiative lifetimes and optical simulations based on the numerical solution of Maxwell's equations. Moreover, coupling of the HgTe photoluminescence to high quality factor modes of the metasurface improves emission directivity, concentrating output within an ≈20° angle.     

Modeling the effect of node synchronization times in ultra-wideband wireless networks

Ultra-wideband wireless (UWB) can provide the physical layer for high-throughput personal area networks. When UWB is used for communication between many nodes, relatively long acquisition times are needed when dropping and re-establishing wireless links between the nodes. This paper describes the development and use of mathematical and simulation models to investigate the impact of dropping and reacquiring links between nodes on average packet delay; we also consider the performance of the alternative strategy of forwarding packets through intermediate nodes without breaking the established wireless links. The work presented here assumes that no specific MAC layer protocol, such as WiMedia UWB MAC, is in operation. The paper describes the models, explains the selection of modeling parameters used, compares the average packet delay for a network of three simple UWB nodes and for a ring of ten UWB nodes and explains the use of these results for network design engineers.     

Clustering in ordered dissimilarity data

This paper presents a new technique for clustering either object or relational data. First, the data are represented as a matrix D of dissimilarity values. D is reordered to D * using a visual assessment of cluster tendency algorithm. If the data contain clusters, they are suggested by visually apparent dark squares arrayed along the main diagonal of an image I( D *) of D *. The suggested clusters in the object set underlying the reordered relational data are found by defining an objective function that recognizes this blocky structure in the reordered data. The objective function is optimized when the boundaries in I( D *) are matched by those in an aligned partition of the objects. The objective function combines measures of contrast and edginess and is optimized by particle swarm optimization. We prove that the set of aligned partitions is exponentially smaller than the set of partitions that needs to be searched if clusters are sought in D . Six numerical examples are given to illustrate various facets of the algorithm. © 2009 Wiley Periodicals, Inc.     

The structure of glasses in the TeO2-P2O5 system

The co-effects of two glass-formers in the TeO₂-P₂O₅ system are studied on the basis of neutron diffraction data. The curves for the radial distribution function (RDF) obtained show a high extent of destruction of the short-range order in the tellurite matrix, while the basic co-ordination PO₄ polyhedron remains unchanged. The co-ordination number (cn) of the Te atom changes from 4 to 3+1 and marked tendency towards elongation of the Te-O distances over 2.3 Å is observed. The considerably higher stability of the PO₄ polyhedra and their strong influence on the TeO₄ polyhedra is established. The observed smearing effect of the Te-Te, Te-second O and O-second O distances in the range of 3.8 to 3.9 Å in other tellurite glasses is also characteristic of this system. A structural interpretation of the liquid-liquid immiscibility on the short-range order level in the system is given. A critical composition with 26±5% of the second glass-former is established, above which concentration a stable immiscibility in the tellurite systems is observed. An attempt is made to construct two adequate structural models (microhomogeneous and microheterogeneous) for the short-range order in the glasses studied.