A Flower-like In2O3 Catalyst Derived via Metal–Organic Frameworks for Photocatalytic Applications

The most pressing concerns in environmental remediation are the design and development of catalysts with benign, low-cost, and efficient photocatalytic activity. The present study effectively generated a flower-like indium oxide (In₂O₃-MF) catalyst employing a convenient MOF-based solvothermal self-assembly technique. The In₂O₃-MF photocatalyst exhibits a flower-like structure, according to morphology and structural analysis. The enhanced photocatalytic activity of the In₂O₃-MF catalyst for 4-nitrophenol (4-NP) and methylene blue (MB) is likely due to its unique 3D structure, which includes a large surface area (486.95 m² g⁻¹), a wide spectrum response, and the prevention of electron–hole recombination compared to In₂O₃-MR (indium oxide-micro rod) and In₂O₃-MD (indium oxide-micro disc). In the presence of NaBH₄ and visible light, the catalytic performances of the In₂O₃-MF, In₂O₃-MR, and In₂O₃-MD catalysts for the reduction of 4-NP and MB degradation were investigated. Using In₂O₃-MF as a catalyst, we were able to achieve a 99.32 percent reduction of 4-NP in 20 min and 99.2 percent degradation of MB in 3 min. Interestingly, the conversion rates of catalytic 4-NP and MB were still larger than 95 and 96 percent after five consecutive cycles of catalytic tests, suggesting that the In₂O₃-MF catalyst has outstanding catalytic performance and a high reutilization rate.     

Adsorptive interaction of bisphenol A with mesoporous titanosilicate/reduced graphene oxide nanocomposite materials: FT-IR and Raman analyses

Nanocomposite materials containing graphene oxide have attracted tremendous interest as catalysts and adsorbents for water purification. In this study, mesoporous titanosilicate/reduced graphene oxide composite materials with different Ti contents were employed as adsorbents for removing bisphenol A (BPA) from water systems. The adsorptive interaction between BPA and adsorption sites on the composite materials was investigated by Fourier transform infrared (FT-IR) and Raman spectroscopy. Adsorption capacities of BPA at equilibrium, q _e (mg/g), decreased with increasing Ti contents, proportional to the surface area of the composite materials. FT-IR observations for fresh and spent adsorbents indicated that BPA adsorbed onto the composite materials by the electrostatic interaction between OH functional groups contained in BPA and on the adsorbents. The electrostatic adsorption sites on the adsorbents were categorized into three hydroxyl groups: Si-OH, Ti-OH, and graphene-OH. In Raman spectra, the intensity ratios of D to G band were decreased after the adsorption of BPA, implying adsorptive interaction of benzene rings of BPA with the sp² hybrid structure of the reduced graphene oxide.     

Efficient Hybrid Modulation/Demodulation Scheme Using Differential Encoding/Decoding for UWB-IR

An efficient hybrid modulation/demodulation scheme using a short duration pulse in the time-domain for ultra wideband-impulse radio (UWB-IR) systems is proposed. The proposed modulation scheme is pulse position modulation (PPM) of the UWB-IR standard modulation combined with differential encoding, and non-coherent energy detection (ED) adopting differential decoding is proposed for demodulation. Differential encoding makes a pulse that can transfer additive information bit into bits assigned in one symbol without increasing the symbol period. The BER performance is evaluated for 2-PPM, 4-PPM and the proposed HD-2PPM (which has the same symbol duration as BPPM and includes two information bits per symbol). The error performance indicates that the proposed scheme is an outstanding 0.5 dB over existing schemes of UWB-IR, and the data-rate performance shows that the proposed method has higher spectral efficiency than conventional methods that occupy the same duration as the proposed scheme.

     

Altered Task-Evoked Corticolimbic Responsivity in Generalized Anxiety Disorder

Generalized anxiety disorder (GAD) is marked by uncontrollable, persistent worry and exaggerated response to uncertainty. Here, we review and summarize the findings from the GAD literature that employs functional neuroimaging methods. In particular, the present review focuses on task-based blood oxygen level-dependent (BOLD) functional magnetic resonance imaging (fMRI) studies. We find that select brain regions often regarded as a part of a corticolimbic circuit (e.g., amygdala, anterior cingulate cortex, prefrontal cortex) are consistently targeted for a priori hypothesis-driven analyses, which, in turn, shows varying degrees of abnormal BOLD responsivity in GAD. Data-driven whole-brain analyses show the insula and the hippocampus, among other regions, to be affected by GAD, depending on the task used in each individual study. Overall, while the heterogeneity of the tasks and sample size limits the generalizability of the findings thus far, some promising convergence can be observed in the form of the altered BOLD responsivity of the corticolimbic circuitry in GAD.     

SO2 permeability and proton conductivity of sPEEK membranes for SO2-depolarized electrolyzer

The SO₂ transport properties of Nafion^® and sPEEK membranes were measured using an electrochemical reaction cell to investigate their application in the electrochemical hybrid sulfur process. The permeability of SO₂ in the membranes was determined from a combined theory based on Faraday's law and Fick's law where the electrochemical reaction rate of SO₂ in the downstream membrane is the same as its diffusion flux through the membrane. Both Nafion^® and sPEEK membranes show higher SO₂ diffusion coefficients at higher temperatures. For sPEEK membranes, increasing the degree of sulfonation resulted in increasing permeability, as more water was imbibed in the membranes with higher degrees of sulfonation. Activation energy was extracted from the temperature-dependence of the diffusion coefficients for both membranes. The sPEEK membranes exhibited similar diffusion coefficients to those of Nafion^®, even at high sulfonation degrees of 70%. Besides SO₂ permeability, proton conductivity and mechanical properties were measured for comparison between the 2 polymer membranes. Although the proton conductivity of the sPEEK was slightly lower than the Nafion^® membrane, it was very competitive considering its higher mechanical strength and much lower cost.     

Single-Cell Nanoencapsulation: From Passive to Active Shells

Single-cell nanoencapsulation is an emerging field in cell-surface engineering, emphasizing the protection of living cells against external harmful stresses in vitro and in vivo. Inspired by the cryptobiotic state found in nature, cell-in-shell structures are formed, which are called artificial spores and which show suppression or retardation in cell growth and division and enhanced cell survival under harsh conditions. The property requirements of the shells suggested for realization of artificial spores, such as durability, permselectivity, degradability, and functionalizability, are demonstrated with various cytocompatible materials and processes. The first-generation shells in single-cell nanoencapsulation are passive in the operation mode, and do not biochemically regulate the cellular metabolism or activities. Recent advances indicate that the field has shifted further toward the formation of active shells. Such shells are intimately involved in the regulation and manipulation of biological processes. Not only endowing the cells with new properties that they do not possess in their native forms, active shells also regulate cellular metabolism and/or rewire biological pathways. Recent developments in shell formation for microbial and mammalian cells are discussed and an outlook on the field is given.     

Effects of geometrical parameters of an oil-water separator on the oil-recovery rate

As the economical and environmental damages due to the accidental oil-spills in marine environment increase gradually, more active countermeasure needs to be developed. In this respect, in the present study, we propose a new design of oil-water separation system and investigate the effects of several geometrical features on the oil-recovery rate, based on a two-dimensional numerical simulation. The working mechanism of current separator is to utilize the density difference between the oil and water, which is strengthened by adding momentum to the oil-water mixture flow through a “U-shaped” passage. Along the flow passage, we locate additional parts such as baffle plate, weir plate, and water outlet. While optimizing the conditions of these to maximize the oil recovery, it is found that the formation and stable retention of water layer between the water outlet and weir plate is critical to separate and store the above-layered oil. Finally, these findings are further confirmed with a basic experimental test with a three-dimensional oil-water separator model.

     

Antecedents and consequences of three dimensions of burnout in psychotherapists: A meta-analysis.

The present study aimed to identify the antecedents of burnout and its consequences for psychotherapists. The meta-analysis showed that, among antecedents, the over-involvement variable had the most significant positive correlation with emotional exhaustion, while the control variable had the most significant negative correlations with depersonalization and personal accomplishment. On the other hand, among consequences, the job satisfaction variable had the most significant positive correlations with emotional exhaustion, depersonalization, and personal accomplishment. Based on these results, we found resources that can assist with developing burnout prevention interventions for psychotherapists. (PsycINFO Database Record (c) 2011 APA, all rights reserved)