三峡工程升船机坝段基础特点与施工期形变特征

简要分析了升船机上闸首基础岩体的特点，在施工期随上部建筑物形成的过程中沉降与水平形变随荷载变化的特征。分析认为:基础岩体形变与其受荷特点相吻合，目前建筑物总体安全状态正常，但部分坝段需引起注意，同时为验证设计、指导施工提供了依据。     

三角网格表面等残留高度刀轨生成算法

针对截平面法规划的三角网格表面的刀轨长度较长、加工表面残留高度不均匀的问题,提出一种基于改进截平面法的等残留高度刀轨生成算法.首先在估算刀触点轨迹线垂直方向曲率半径的基础上,计算刀触点轨迹投影线并对其进行修正,去除其中冗余的投影点;然后由修正后的刀触点轨迹投影线构造驱动表面,利用驱动表面和网格表面迭代计算刀触点轨迹线;最后由刀触点轨迹线计算无干涉刀轨.与截平面法生成的刀轨进行比较分析的结果表明,文中算法生成的刀轨长度较小且获得的残留高度保持均匀,适合于三角网格表面表示的复杂表面的精加工.     

Highly efficient hematite films via mid-/ex-situ Sn-doping for photoelectrochemical water oxidation

In this study, we report the facile fabrication of Sn-doped hematite film via mid-situ and ex-situ doping methods for efficient photoelectrochemical (PEC) performances. The morphology of Sn-doped Fe₂O₃ films was varied with Sn precursor in the mid-situ doping process. The addition of SnCl₂ rendered a smooth-surfaced and well-distributed nanorod morphology, but SnCl₄ gave a deformed nanorod structure covered with layered coalescence of SnO₂ particles. The former demonstrated much higher photoelectrochemical performances as photoanodes than the latter. The photocurrent can be further improved by surface modification with SnCl₄ through spin-coating method. The effects of Sn precursors on the morphology, surface characteristics and the PEC properties of the photoanodes are investigated.     

An asymmetrically substituted dithieno[3,2-b:2',3'-d]pyrrole organic small-molecule hole-transporting material for high-performance perovskite solar cells

Hole-transporting materials play a vital role in terms of the performance of perovskite solar cells (PSCs). The dithieno[3,2-b:2',3'-d]pyrrole (DTP), an S,N-heterocyclic building block, has been proved to be desirable for molecular design of hole-transporting materials in PSCs. We developed an asymmetrically substituted DTP small-molecule (JW12) and a reference compound (JW11). The asymmetrical structure of JW12 leads to different absorption properties and electron distribution. The device in a planar n-i-p architecture using JW12 shows a much higher PCE (18.07%) than that based on JW11 (15.46%), which is also better than the device based on spiro-OMeTAD (17.47%). We hope our research can provide a new perspective in molecular design of organic HTMs for perovskite solar cells.     

高速铣削加工工艺优化技术的研究

针对高速加工安全性高、切削效率佳、工艺性好等独特的编程要求,构造出了以切削时间短、加工成本低、表面质量高为优化目标的,并以满足零件尺寸精度要求为约束条件的加工工艺方案评优模型。该模型已应用于自主开发的高速铣削Superman CAMⅡ原型系统中,以指导粗精加工刀轨的生成。实验结果表明：该模型具有合理性和实用性,对工艺人员编制高速加工工艺有一定的参考价值。     

三角网格牙颌模型上的牙弓线半自动探测方法

介绍了一种在三维三角网格牙颌模型上半自动探测牙弓线的方法。首先使用三维激光测量系统对牙颌石膏模型进行测量获得数字模型;其次在网格模型上交互拾取4个参照点以确定咬合平面;接着使用顶点法矢和咬合平面作为参考,筛选出初始特征点并拟合出初始牙弓线;以初始牙弓线作为新的参考依据筛选出最终特征点,拟合最终参照点得到最终牙弓线。使用多副牙颌模型对该方法进行了测试,验证了该方法稳定、有效。     

聚甲基丙烯酸缩水甘油酯互通多孔材料选择性降低卷烟烟气中的苯酚

为选择性降低卷烟烟气中苯酚的释放量,制备了聚甲基丙烯酸缩水甘油酯互通多孔材料(PolyGMA材料),利用傅里叶变换红外光谱(FT-IR)、扫描电子显微镜(SEM)、比表面及孔径分析仪对材料进行了表征,并分别考察了添加至二元复合滤棒和涂布卷烟纸2种应用方式对选择性降低卷烟烟气中苯酚释放量的影响。结果表明:①制备的材料具备环氧基团和互通多孔的结构,其比表面积为119.5 m2/g,平均孔径为17.3 nm;②该材料以添加二元复合滤棒形式在卷烟中应用效果较佳,与对照卷烟相比,试验卷烟苯酚释放量降低28.3%,苯酚选择性降低率为23.0%,且卷烟感官质量无明显差异。     

预应力锚索对均质岩体的加固效应模拟试验研究

本文采用相似材料模型试验方法研究了单根预应力锚索对均质岩体的加固效应，给出了在三种不同长度的锚索作用下，岩体中受力变形规律，分析了锚索长度、预应力数值等对加固效应的影响，并与有限元计算结果作了对比。     

DiffServ中AF业务带宽分配公平性

通过在opnet6.0下进行计算机仿真实验及数据分析,研究Diffserv网络中AF业务类间和AF业务类里分别在欠载,过载情况下带宽分配的公平性问题,发现AF类间有较好的公平性,而在AF类里,受RTT,TCP连接数目,非响应流等因素的影响,并没有较好的带宽分配公平性。     

Dye-sensitized TiO2 film with bifunctionalized zones for photocatalytic degradation of 4-cholophenol

A new strategy to photocatalytic degradation of 4-cholophenol (4-CP) under visible light irradiation was described. The TiO₂ film deposited on an ordinary glass sheet was distributed into two zones. One zone was sensitized by N719 dye and fabricated to be a sandwich type cell with a similar structure of dye-sensitized solar cells. The other zone was inserted into pollutants solution for degradation. A highly oxidized overvoltage anode was achieved from the dye-sensitized zone. The bifunctionalized TiO₂ film and the anode could degrade 4-chlorophenol in two separate reactors with 97% and 96% removal of 4-CP after 5 h, respectively. The degradation efficiency could be improved by addition of FeSO₄. The as-prepared bifunctionalized TiO₂ film was comparably stable in the process of degradation.