端羟基聚二甲基硅氧烯改性环氧树脂

用羟基封端的聚二甲基硅氧烷改性环氧树脂，得到具有两相结构的改性树脂，其耐热性明显提高．环氧树脂／有机硅（20／80）共混物涂层有很低的表面能，主要的机械性能则变化不大，可作为一种疏水性防护徐层．     

铝质材料的摩擦学表面改性

铝质材料阳极氧化膜系均匀、规则的微观多孔质结构，利用物理、化学或电化学的方法在其中沉积或原位合成润滑性物质，在保持阳极氧化膜质硬、耐磨特性的基础上，使其具有一定的白润滑性，是近十多年来铝质材料表面改性研究的热点领域之一，本文对该研究的基本原理和国内外发展概况进行了概述，并重点介绍了我们在这一方面研究中的一些最新进展和结果，分别介绍了三种新型体系的自润滑改性阳极氧化铝材料．     

The tribological behavior of micrometer and nanometer TiO2 particle‐filled poly(phthalazine ether sulfone ketone) composites

Micrometer and nanometer TiO₂ particle‐filled poly(phthalazine ether sulfone ketone) (PPESK) composites with various filler volume fractions from 0.5 to 7.5 vol % were prepared by heating compression molding. The friction and wear behaviors of the PPESK composites were evaluated using the block‐on‐ring test rig by sliding PPESK‐based composite blocks against a mild carbon steel ring under dry friction conditions. The wear debris and the worn surfaces of the PPESK composites filled with micrometer and nanometer TiO₂ particles were investigated by using a scanning electron microscope (SEM), while the structures of PPESK composites and wear debris were analyzed with IR spectra. Experimental results show that antiwear properties of the PPESK composites can be improved greatly by filling nanometer TiO₂ particles, and the friction coefficient decreases when the filler volume fraction is below 2.5%, but when the filler volume fraction is above 2.5% the friction coefficient increases gradually with increasing filler volume fraction. In the case of micrometer TiO₂ filler, wear rates increase with increasing filler volume fractions under identical test conditions, and the friction coefficients are less sensitive to the filler volume fraction. It was also found that the wear mechanism of micrometer TiO₂ particle‐filled PPESK is mainly severe adhesion and abrasive wear, while that of nanometer TiO₂ particle‐filled PPESK is mainly slight abrasive wear. In the former case, there are no transfer film formed on the surface of the counterpart steel, and wear debris are in the form of long and large ribbon. While in the latter case, the wear debris was granule and their size was about 10 μm. In case of 1 vol % nanometer TiO₂ particle‐filled PPESK composites, the transfer film was fairly thinner and smoother, and the transfer film provided better coverage on the surface of steel ring, while that of 7.5 vol % was thicker and discrete. These account for the different friction and wear behavior of micrometer and nanometer TiO₂ particle‐filled PPESK composite. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 906–914, 2004     

聚氨酯/聚四氟乙烯耐磨防腐涂层表面结构的研究

研究了以聚氨酯和γ辐照的聚四氟乙烯组成的耐磨防腐涂层的耐磨寿命及耐水性。用付里叶红外和ESCA等分析了涂层表面的化学结构及形貌,揭示了涂层表面富集的聚四氟乙烯与聚氨酯树脂形成牢固的结合时,涂层具有良好的耐磨性及抗腐蚀性.     

The friction and wear properties of nanometre SiO2 filled polyetheretherketone

Nanometre SiO₂ filled-polyetheretherketone (PEEK) composite blocks with different filler proportions were prepared by compression moulding. Their friction and wear properties were investigated on a block-on-ring machine by running a plain carbon steel (AISI 1045 steel) ring against the composite block. The morphologies of the wear traces and the transfer film were observed by scanning electron microscopy (SEM). It was found that nanometre SiO₂ filled-PEEK exhibited considerably lower friction coefficient and wear rate in comparison with pure PEEK. The lowest wear rate was obtained with the composite containing 7.5 wt.% SiO₂. The SEM pictures of the wear traces indicated that with the frictional couple of carbon steel ring/composite block (fillec with 7.5 wt.% filler), a thin, uniform, and tenacious transfer film was formed on the ring surface. It was inferred that the transfer film contributed largely to the decreased friction coefficient and wear rate of the filled PEEK composites.     

γ射线对La0.96Tb0.01Dy0.03BO3荧光粉发光性能影响？…

采用高温固相扩散法合成了La0.96 Tb0.01 Dy0.03BO3荧光粉,用X射线粉末衍射及光电子能谱法等研究了γ射线辐照对其发光性能的影响.氧化物中的Tb3+与Dy3+离子转变成硼酸盐形态后,其4d电子结合能发生变异,Tb3+、Dy3+离子4d电子结合能趋于一致.在1.5104Gy辐照时, La0.96 Tb0.01 Dy0.03BO3荧光粉的发光强度增至最大.γ射线辐照使La0.96 Tb0.01 Dy0.03BO3晶粒细化和Tb3+、Dy3+离子4d电子结合能峰面积改变,结合能峰面积的变化与辐照剂量对发光强度的影响结果是一致的.     

凝胶丁腈共聚弹性体增韧聚甲醛的加工流变行为及力学性能

研究了聚甲醛(POM)/凝胶丁腈共聚弹性体(GNBE)共混物的熔体流动指数(MFI)、高压毛细管流变行为和力学性能。结果表明,共混物MFI随GNBE用量的增加下降较大。聚酰胺(PA)对POM/GNBE共混体系的MFI影响较小,而热塑性酚醛树脂(PFR)的影响显著。当PFR的质量份为4时,POM共混物的MFI达最小值(0.053g/min),约为未加增容剂POM共混物MFI的1/6。随着剪切速率的提高,共混物剪切黏度迅速与POM接近。这种黏度变化行为说明共混物比GNBE对剪切速率更敏感,共混物的黏度受POM的影响较大。随着剪切速率的提高,POM与GNBE的黏度比迅速减小,并接近1,说明POM和GNBE在高剪切速率下共混时,GNBE的液滴能够在POM连续相中分散达到最小。含20份GNBE的POM共混物在高剪切速率下的熔体表观黏度与POM相当;在PFR质量份为6时,POM共混物的缺口冲击强度达到21.6kJ/m2,超过了GNBE质量份为40的POM共混物。当PFR质量份为4时,共混物的缺口冲击强度为对应的不加增容剂共混物的冲击强度的2倍多,扯断伸长率提高了55.4%。     

芳纶纤维增强丁腈橡胶的摩擦性能

研究了芳纶纤维增强丁腈橡胶(NBR)复合材料的物理机械性能和摩擦性能,并用扫描电子显微镜分析了芳纶纤维增强NBR复合材料的磨损表面和磨屑形貌。结果表明,芳纶的加入提高了NBR的拉伸强度;随着芳纶用量的增大,复合材料的扯断伸长率降低;芳纶的加入降低了NBR的摩擦系数和磨损率;当芳纶用量为20份时,复合材料的综合性能最佳。加入芳纶对NBR摩擦磨损形式的改变是NBR摩擦性能提高的重要原因。     

Tribochemistry and the development of AW and EP oil additives — a review

The antiwear (AW) and extreme pressure (EP) properties of chlorine, sulphur, phosphorus-containing organic compounds and zinc dialkyldithiophosphate (ZDDP) oil additives are affected greatly by their reactive ability to the metal surface, as well as by the chemical composition, chemical state, physical and mechanical properties of the protective films formed. Over four decades, research has taken place on boundary lubrication, and a much better understanding of the AW and EP action mechanism of one additive by itself in base oil has been obtained, and much more knowledge on the relationship between wear and decomposition of additives, adsorption and reaction of the additive or its decomposed products with metal, has been gained. A series of analytical methods and a great number of modern surface analytical tools have been set up and used for research in this area. The problems and some suggestions for the future study on boundary lubrication of oil additive are proposed.     

The antiwear and extreme pressure action mechanism of CeF3 in grease

Cerium (III) fluoride as an antiwear or extreme pressure additive has been used in grease and bonded solid film lubricant, but its action mechanism has not been clarified. In this paper, the tribological characteristics of lithium grease containing CeF₃, CaF₂, SbF₃, CeO₂ and graphite fluoride ((CF)_n) were evaluated with an SRV tester. The results show that pastes containing CaF₂ and (CF)_n give good antiwear and anti-friction performance, but do not possess extreme pressure properties. Adding CeO₂ to grease offers no benefit to the antiwear and anti-friction performance of the paste. Paste containing SbF₃ has poor lubricating properties. XPS analysis shows that the good antiwear and extreme pressure properties of paste containing CeF₃ can be attributable to the formation of a physically adherent film and a chemical reaction film on the rubbing surface. Thermogravimetry shows that CeF₃ acts as an agent for the slow release of the fluorine element.