Phase Relations in the System Fe2O3–Fe3O4–YFeO3 in Air

Measurements were made of temperature and ternary composition for coexisting liquid and crystalline phases on the air isobar in the system Fe₂O₃-Fe₃O₄-YFeO₃ with particular regard to the stability range and compositional limits of yttrium iron garnet. Phase equilibrium relations were determined by conventional quenching techniques combined with measurements of loss in weight at the reaction temperature to locate true ternary compositions. The intersection of the air isobar with the ternary univariant boundary curve for coexisting magnetite, garnet, and liquid phases results in a eutectic-type situation at the composition Y_0.27Fe_1.73 O_2.87 and 1469°± 2°C. A similar intersection of the isobar with the boundary curve for coexisting garnet, orthoferrite, and liquid phases gives rise to a peritectic-type reaction at 1555° 3°C. and Y_0.44Fe_1.56 O_2.89 The yttrium iron garnet crystallizing from liquids within these temperature and composition limits contains up to 0.5 mole % iron oxide in excess of the stoichiometric formula in terms of the starting composition 37.5 mole % Y₂O₃, 62.5 mole % Fe₂O₃. At 1470° C. the garnet phase in equilibrium with oxide liquid contains 2 mole % FeO in solid solution. The small solubility of excess of iron oxide and partial reduction of the garnet phase in air are unavoidable during equilibrium growth from the melt.     

铝合金激光双光点焊接工艺特性

对铝合金薄板激光单光点和双光点焊接(包括不填丝和填丝)的焊缝成形、对接间隙和准直度容许裕度以及气孔状况进行了比较,并分析了双光点能量分布的激光对铝合金焊接的影响.结果表明,与激光单光点焊接相比,激光双光点焊接铝合金所得焊缝表面质量更好,焊缝熔宽更大,对接间隙和准直度容许裕度明显放宽.激光双光点焊接铝合金可以显著减少焊缝中大气孔的数量,但对焊缝中小气孔数量的影响不明显.此外,填加焊丝可以进一步改善焊缝表面质量并放宽对接间隙和准直度容许裕度,但将增大焊缝产生大气孔的倾向,采用激光双光点焊接仍可使焊缝中大气孔的数量明显减少.     

FROZEN STORAGE QUALITY CHANGES IN WHOLE JONAH CRABS

The Jonah crab is an underutilized species in the mid-Atlantic region, and use of the whole, frozen crab would broaden marketing options for this seafood product. We monitored quality changes in whole cooked crabs held in a blast freezer for up to 50 weeks. A sensory evaluation panel determined the point at which detectable differences appeared in the product. Microbiological testing was conducted at selected intervals to assess bacterial content. In a triangle test, frozen experimental samples of leg meat were first differentiated from frozen controls at approximately 24 weeks. No significant difference was defected in body meat for up to 33 weeks’ storage. Microbial quality was acceptable throughout the experiment.     

Automatic analysis of multiparty meetings

This paper is about the recognition and interpretation of multiparty meetings captured as audio, video and other signals. This is a challenging task since the meetings consist of spontaneous and conversational interactions between a number of participants: it is a multimodal, multiparty, multistream problem. We discuss the capture and annotation of the Augmented Multiparty Interaction (AMI) meeting corpus, the development of a meeting speech recognition system, and systems for the automatic segmentation, summarization and social processing of meetings, together with some example applications based on these systems.     

Composition and synthesis of raphide crystals and druse crystals in berries of Vitis vinifera L. cv. Cabernet Sauvignon: Ascorbic acid as precursor for both oxalic and tartaric acids as revealed by radiolabelling studies

Biomineralisation in the fleshy pericarp of berries of Vitis vinifera L. gives rise to crystals of two distinct forms, viz. raphides and druses, which are found in exocarp and endocarp cells respectively. Druses have generally been considered as crystalline aggregates of calcium oxalate. However, the organic moiety of raphide crystals has been commonly accepted as tartrate, although we have found no analytical data to support that assumption. We now present TEM and X-ray powder diffraction analysis data showing that raphide crystals of V. vinifera berries are composed of calcium oxalate monohydrate. This work also established ascorbic acid as the biosynthetic precursor of both oxalic and tartaric acids. When ascorbic acid labelled with ¹⁴C at position 1 was introduced into berries via the rachis, 21% and 52% of the added radiolabel was recovered as oxalic and tartaric acids respectively. Purified crystals from the radiolabelled grape berries contained approximately 20% of the original radioactivity, further confirming the role of ascorbic acid in oxalic acid biosynthesis. To our knowledge, this is the first evidence to be published on the formation of oxalic and tartaric acids from ascorbic acid via two distinct pathways operating within the same physiological entity (organ).     

HISTAMINE PRODUCTION BY FOOD-BORNE BACTERIAL SPECIES12

A total of 112 bacterial strains representing 38 species were tested for their potential to elicit food poisoning outbreaks via histamine formation in foods. Proteus morganii and Enterobacter aerogenes displayed a quantitative superiority in terms of histamine production on a trypticase-soy broth-histidine (TSBH) medium and a tuna fish infusion broth (TFIB). When bacteria were incubated under standardized conditions in TSBH medium, histamine accumulated to levels exceeding 50 nmoles/ml of media with a total of 23 strains, including 13 of 15 P. morganii strains, 3 of 3 E. aerogenes strains, 3 of 12 Hafnia alvei strains, 1 of 4 Providencia alcalifaciens strains, 1 of 5 Enterobacter cloacae strains, 1 of 1 Proteus rettgeri strains, and 1 of 1 Citrobacter diversus strains. However, only 8 of the 15 P. morganii strains and the 3 E. aerogenes strains were capable of generating histamine in excess of 200 nmoles/ml in the TSBH medium. Of the 23 strains capable of appreciable histamine production in TSBH medium, P. morganii and E. aerogenes were, by far, the most prolific histamine producers in TFIB. Of the organisms tested, only P. morganii and E. aerogenes would appear to have the capability of forming sufficient histamine in scombroid fish products to elicit food poisoning outbreaks.     

Phase Relations in the Garnet Region of the System Y2O3–Fe2O3–FeO–Al2O3

Liquidus equilibrium relations for the air isobaric section of the system Y₂O₃–Fe₂O₃–FeO–Al₂O₃ are presented. A Complete solid-solution series is found between yttrium iron garnet and yttrium aluminum garnet as well as extensive solid solutions in the spinel, hematite, orthoferrite, and corundum phases. Minimum melting temperatures are raised progressively with the addition of alumina from 1469°C in the system Y–Fe–O to a quaternary isobaric peritectic at 1547°C and composition Y _0.22 Fe _1.08 Al _0.70 O _2.83* Liquidus temperatures increase rapidly with alumina substitutions beyond this point. The thermal stability of the garnet phase is increased with alumina substitution to the extent that above composition Y _0.75 Fe _0.65 Al _0.60 O ₃ garnet melts directly to oxide liquid without the intrusion of the orthoferrite phase. Garnet solid solutions between Y _0.75 Fe _1.25 O ₃ and Y _0.75 Fe _0.32- Al _0.93 O ₃ can be crystallized from oxide liquids at minimum temperatures ranging from 1469° to 1547°C, respectively. During equilibrium crystallization of the garnet phase, large changes in composition occur through reaction with the liquid. Unless care is taken to minimize temperature fluctuations and unless growth proceeds very slowly, the crystals may show extensive compositional variation from core to exterior.     

上海房产展的空间游戏

空间的形式是人定义的。正因为是人定义的，所以形式就有可能因为创造者或使用者的想法不同而改变。可是事实通常并非如此，我们今天所看见的所有空间形式差不多都被制式化了。所以，所谓的有理想的空间创造者穷其一生都在努力想要改变既有的形式事实，但是，事实却很困难。因此，大多数设计师过了四十不惑的年纪，碍于残酷现实的考量，不是转行或变成管理者，就是任它去了，业主想要什么就给什么了。我认识的设计师实在是没几个人像我这过了半百的老设计师，还这么自以为是地坚守自己设计的信仰侦操。我自以为自己是少数的特例，从创造来说，我应该才起步吧。