Strength Improvement in Transformation-Toughened Alumina by Selective Phase Transformation

A1₂O₃-15 vol% ZrO₂ bar-shaped ceramic specimens were fabricated in the green state in such a way that the near surface regions consisted of A1₂O₃ and unstabilized ZrO₂ while the bulk consisted of A1₂O₃ and partially stabilized ZrO₂. After sintering, specimens had macroscopic residual compressive surface stresses and balancing interior tensile stresses due to the tetragonal-to-monoclinic phase transformation in the outer layers which occurs during cooling. The depth of the surface region was controlled during green forming. Residual surface compressive stresses at room temperature varied between 100 and 400 MPa depending on the outer-layer thickness. The increased strengths of the three-layer specimens were obtained in the as-fired unground condition, demonstrating that the stresses introduced are the result of transformation of tetragonal zirconia into monoclinic polymorph which occurred upon cooling from the sintering temperature. Specimens with residual surface compressive stresses were 200 MPa stronger at 750°C than monolithic specimens, demonstrating the viability of this approach for improving elevated-temperature mechanical properties.     

Sol–gel deposited ceria thin films as gate dielectric for CMOS technology

In this work, cerium oxide thin films were prepared using cerium chloride heptahydrate, ethanol and citric acid as an additive by sol–gel spin-coating technique and further characterized to study the various properties. Chemical composition of deposited films has been analysed by FTIR which shows existence of CeO₂. The samples have been optically characterized using ellipsometry to find refractive index of 2·18 and physical thickness which is measured to be 5·56 nm. MOS capacitors were fabricated by depositing aluminum (Al) metal using the thermal evaporation technique on the top of CeO₂ thin films. Capacitance–voltage measurement was carried out to calculate the dielectric constant, flat-band voltage shift of 18·92, 0·3–0·5 V, respectively and conductance–voltage study was carried out to determine the D_it of 1·40 × 10¹³ eV^???1 cm^???2 at 1 MHz.     

Strength-Grain Size Relations in Polycrystalline Ceramics

A model is presented to explain the strength-grain size behavior of ceramics exhibiting duplex microstructures and of ceramics with uniform coarse-grained microstructures. Using an energy balance analysis, the model shows that in most ceramics an hitiipl flaw contained within a single large grain will initially propagate and then arrest after entering the region of increased fracture-surface energy. The arrested flaw will subsequently propagate to failure at the value OF the critical stress intensity factor. Using the data in the literature, a strength-(grain size)^−1/2 plot for MgAl₂O₄ was generated.     

Surface finish prediction models for fine turning

Surface finish data were generated for aluminium alloy 390, ductile cast iron, medium carbon leaded steel 10L45, medium carbon alloy steel 4130, and inconel 718 for a wide range of machining conditions defined by cutting speed, feed and tool nose radius. These data were used to develop surface finish prediction models, as a function of cutting speed, feed, and tool nose radius, for each individual metal. A general purpose surface finish prediction model is also proposed for ductile cast iron, medium carbon leaded steel, and alloy steel. Statistical analysis of experimental data indicated that surface finish is strongly influenced by the type of metal, speed and feed of cut, and tool nose radius. While the effects of feed and tool nose radius on surface finish were generally consistent for all materials, the effect of cutting speed was not. The surface finish improved with speed for ductile cast iron, medium carbon leaded steel, medium carbon alloy steel, and aluminium alloy, but it deteriorated with speed for inconel. Apparently, speed effect on surface finish is not always positive. For all metals, the surface finish improved with the tool nose radius while it deteriorated with speed.     

Integrated safety assessment of Indian nuclear power plants for extreme events: Reducing impact on public mind

Nuclear energy professionals need to understand and address the catastrophe syndrome that of late seems to be increasingly at work in public mind in the context of nuclear energy. Classically the nuclear power reactor design and system evolution has been based on the logic of minimization of risk to an acceptable level and its quantification based on a deterministic approach and backed up by a further assessment based on the probabilistic methodology. However, in spite of minimization of risk, the reasons for anxiety and trauma in public mind that still prevails in the context of severe accidents needs to be understood and addressed. Margins between maximum credible accidents factored in the design and the ultimate load withstanding capacities of relevant systems need to be enhanced and guaranteed with a view to minimize release of radioactivity and avoid serious impact in public domain. A more realistic basis for management of an accident in public domain also needs to be quantified for this purpose. Assurance to public on limiting the consequences to a level that does not lead to a trauma is something that we need to be able to credibly demonstrate and confirm. The findings from Chernobyl reports point to significant psychological effects and related health disorders due to large scale emergency relocation of people that could have been possibly reduced by an order of magnitude without significant additional safety detriment. A combination of probabilistic and deterministic approaches should be evolved further to minimize consequences in public domain through enhancing safety margins and adding greater precision to quantitatively predicting accident progression and its management. The paper presents the case studies of the extreme external event such as tsunami and its impact on the coastal nuclear plants in India, the containment integrity assessment under the extreme internal event of over-pressurization and aircraft impact along with hydrogen deflagration/detonation-induced loadings. These are at the moment extremely burning issues due to the severe accidents of Fukushima, Chernobyl and Three Mile Island reactors. In the present day context identifying the extreme loadings in a separate category and the corresponding margin assessment is necessary in addition to the implementation of the mitigation and upgraded safety measures. Further, the paper attempts to address the question of public trauma in the event of a serious nuclear reactor accident, a need that has been felt in view of the recent Fukushima and earlier Chernobyl accidents and the resulting large scale relocation due to the present deficient policies and the inherent limitations of Linear No Threshold (LNT) principle.     

Detection of H2S gas at lower operating temperature using sprayed nanostructured In2O3 thin films

Nanostructured indium oxide (In₂O₃) thin films were prepared by spray pyrolysis (SP) technique. X-ray diffraction (XRD) was used to investigate the structural properties and field emission scanning electron microscopy (FESEM) was used to confirm surface morphology of In₂O₃ films. Measurement of electrical conductivity and gas sensing performance were conducted using static gas sensing system. Gas sensing performance was studied at different operating temperature in the range of 25–150 °C for the gas concentration of 500 ppm. The maximum sensitivity (S = 79%) to H ₂ S was found at lower temperature of 50 °C. The quick response (4 s) and fast recovery (8 s) are the main features of this film.     

Studies on the skin uptake and efflux kinetics of N-phenyl-p-phenylenediamine: an aromatic amine intermediate

N-phenyl-p-phenylenediamine (N-PPDA), an industrial intermediate and hair dye ingredient, has been implicated in a variety of toxic symptoms including cutaneous manifestations. However, the role of physiological factors that may determine and modify its absorption and transport within and through the skin is not fully understood. The present study reveals that N-PPDA binds readily to skin showing saturation kinetics with K m and V_max of 2.54 × 10⁻⁴ M and 4.76 μmol g⁻¹ skin, respectively. The uptake was dependent upon the area of skin, concentration of the amine, exposure time, temperature and pH of the vehicle. Heat treatment facilitated the binding but temperatures abouv 50° caused significant lowering of the uptake, indicating the possible involvement of collagen matrix. Skin lipids also contributed in the binding of N-PPDA. Bioinhibitors such as KCN, sodium arsenate, NaF, N-ethylmaleimide, cycloheximide, iodoacetic acid and 2,4-dinitrophenol had no effect on the uptake potential, suggesting it to be a non-energy dependent process. Most of the skin-bound N-PPDA was effluxed through serum proteins reaching the target organs via systemic circulation.     

Some Kinetic Considerations Regarding the Double-Torsion Specimen

In the double-torsion specimen, crack velocity is a function of the shear wave velocity. At a constant load above the critical load required for crack propagation, crack velocity asymptotically approaches a constant value which is proportional to the shear wave velocity and is dependent on specimen geometry and load. The maximum possible crack velocity under a constant load is proportional to the shear wave velocity multiplied by the ratio of the specimen thickness to its width. For the case of constant deflection with an initial load greater than the critical load, crack velocity goes through a maximum and arrests, for a sufficiently long specimen. Testing-machine compliance increases the length that such a crack will attain before arrest. The load required for rapid crack propagation is only slightly greater than the critical load; stable crack growth in the absence of stress corrosion guarantees an accurate determination of the fracture energy.