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1.
Temperature and pH‐responsive interpenetrating polymer network (IPN) hydrogels, constructed with poly(methacrylic acid) (PMAA) and poly(vinyl alcohol) (PVA), by a sequential IPN method, were studied. The characterization of IPN hydrogels was investigated by Fourier‐transform infrared spectroscopy, differential scanning calorimetry (DSC) and swelling under various conditions. The IPN hydrogels exhibited relatively high swelling ratios, in the range 230–380 %, at 25 °C. The swelling ratios of the PMAA/PVA IPN hydrogels were pH and temperature dependent. DSC was used for the quantitative determination of the amounts of freezing and non‐freezing water. The amount of free water increased with increasing PMAA content in the IPN hydrogels. Copyright © 2004 Society of Chemical Industry 相似文献
2.
Daniel Won‐Kyu Hong Choong Seon Hong 《International Journal of Network Management》2003,13(2):115-127
This paper proposes a high‐performance connection management architecture to design a common QoS framework applied to an ATM network based on the Open Distributed Processing (ODP) concept. We design the QoS framework in accordance from the RM‐ODP information and computational viewpoints. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
3.
Owing to its well-known high complexing power toward Al3+ ion, fluoride ion is able to increase the solubility of alumina in alkali chloride melts. To determine the extent of this effect, the formation of aluminium(III) fluoro-complexes was studied potentiometrically in LiCl-KCl eutectic at 470°. But the sodium fluoride addition appeared to produce not only the complexation effect but also a mineralization effect on alumina. So, the thermodynamical stability of alumina formed in this melt by precipitation from aluminium chloride with carbonate ion (oxide anion donor) depends on the fluoride ion concentration. These two effects explain the solubility variation of alumina in the LiCl-KCl eutectic + NaF mixtures. A pF? - pO2? diagram, which represents the stability area of the various aluminium (III) species is established, and leads to some conclusions concerning the electrowinning of aluminium from molten chloride melts.The cumulative formation constants of the aluminium(lII) fluoro-complexes (AlF3?ii) have been obtained, whose values are the following: 2.5 ± 0.4, 4.7 ± 0.6, 5.7 ± 0.5, 7.5 ± 0.4, 8.0 ± 0.5, 9.0 ± 0.6, respectively for i = 1, 2, 3, 4, 5 and 6. It has been shown that oxyfluoride species such as AlOF1?ji does not exist. The solubility products of gamma and alpha-alumina have been determined and are equal to 10?42.9 and 10?44.0 respectively (all the constants are given in the molality scale). They differ widely from the solubility product of the alumina obtained in the absence of fluoride ion, ie 10?27.4. 相似文献
4.
Seon Jeong Kim Seoung Gil Yoon Young Moo Lee Kay Hyeok An Sun I. Kim 《应用聚合物科学杂志》2003,90(5):1389-1392
Temperature‐responsive interpenetrating polymer network (IPN) hydrogels constructed with poly(vinyl alcohol) and poly(diallyldimethylammonium chloride) using the sequential IPN method were studied. The characteristics of IPN hydrogels were investigated using the dynamic vapor sorption system. IPN hydrogels exhibited a relatively high sorption ratio, 180–360% at room temperature. The sorption ratio of hydrogels depended on temperature. Diffusion coefficients were calculated according to the Fickian Law at several temperatures. The apparent activation energy was 5.43 kJ mol?1, which corresponds to typical diffusion processes. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1389–1392, 2003 相似文献
5.
Solid circulation characteristics in an internally circulating fluidized bed with orifice-type draft tube 总被引:1,自引:0,他引:1
Sang Done Kim Yo Han Kim Seon Ah Roh Dong Hyun Lee 《Korean Journal of Chemical Engineering》2002,19(5):911-916
Effects of superficial gas velocities to a draft tube, to an annulus section and particle size on the solid circulation rate
(G,) have been determined in an internally circulating fluidized bed (0.28 m I.D. × 2m high) with an orifice type draft tube.
The solid circulation rate from the draft tube to an annulus section increases with increasing gas velocities to the draft
tube(U
d
) and annulus section (Ua) and consequent increase in pressure drop across the orifice (ΔPor). However, the values ofG
s
decrease by 7–21% with increasing particle size from 86 to 288 μm. The pressure drop across the orifice increases with increasingU
d
andU
a
. However, ΔPor decreases by 5–23% with increasing particle size. To predictG
s
in an internally circulating fluidized bed, a correlation is proposed as a function of ΔPor
This paper is dedicated to Professor Dong Sup Doh on the occasion of his retirement Korea University. 相似文献
6.
A simple strategy was developed based on a new reactive function‐ and a salt‐containing new monomer, 4‐vinylbenzyl dimethyl 2‐(dimethylphosphino)ethyl phosphonium chloride (VDEPC), to obtain stable humidity‐sensitive membranes. The major ingredient of a humid membrane is crosslinked polyelectrolytes obtained from copolymers of VDEPC/2‐ethylhexyl acrylate (2‐EHA) = 1/0, 4/1, and 2/1. Isothermal humidity absorption experiments were performed for the estimation of humidity‐sensing materials. The crosslinked copolymers prepared from the reaction of VDEPC/2‐EHA = 4/1 with 1,4‐dichlorobutane showed an average impedance of 595, 39.1, and 3.9 KΩ at 30, 60, and 90% RH, respectively. Their hysteresis, temperature dependence, frequency dependence, and response time were measured. The reliability including water resistance and a long‐term stability were estimated for the application of the common humidity sensor. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1062–1070, 2003 相似文献
7.
Interpenetrating polymer network (IPN) hydrogels based on poly(ethylene oxide) and poly(methyl methacrylate) were prepared by radical polymerization using 2,2‐dimethyl‐2‐phenylacetophenone and ethylene glycol dimethacrylate as initiators and crosslinkers, respectively. The IPN hydrogels were analyzed for sorption behavior at 25°C and at a relative humidity of 95% using dynamic vapor sorption. The IPN hydrogels exhibited a relatively high equilibrium water content in the range of 13–68%. The state of water in the swollen IPN hydrogels was investigated using differential scanning calorimetry. The free water in the hydrogels increased as the hydrophilic content increased. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 258–262, 2003 相似文献
8.
A composite coating of aluminide-yttrium has shown excellent corrosion resistance in a cyclic high-temperature hot-corrosion environment. To understand the effect of yttrium on the stability of the composite coating, the specimens were prepared with various coating parameters of Y thickness, sequence of post heat treatment and surface condition before Y-ion plating. Performance of the composite coating was evaluated by isothermal oxidation and cyclic high-temperature hot corrosion. Isothermal-oxidation-test results show that the Y in the composite coating helps to form a thick and dense Al2O3 scale which is ductile and resistant to thermal stress. The Y in Al2O3 may act as a donor which leads to an increase in concentration of interstitial oxygen and, thus, increases in oxidation rate. The presence of Y2O3 and (Y, Al) O-type compounds in grain boundaries of Al2O3 and boundaries between the Al2O3 and NiAl effectively prohibits the fast diffusion of oxidants (such as O and S) and Al along grain boundaries. Consequently, it may induce slow diffusion through the matrix, and thus the corrosion resistance of the composite coating under cyclic hot corrosion increases substantially. 相似文献
9.
We are witnessing a significant growth in the number of smartphone users and advances in phone hardware and sensor technology. In conjunction with the popularity of video applications such as YouTube, an unprecedented number of user-generated videos (UGVs) are being generated and consumed by the public, which leads to a Big Data challenge in social media. In a very large video repository, it is difficult to index and search videos in their unstructured form. However, due to recent development, videos can be geo-tagged (e.g., locations from GPS receiver and viewing directions from digital compass) at the acquisition time, which can provide potential for efficient management of video data. Ideally, each video frame can be tagged by the spatial extent of its coverage area, termed Field-Of-View (FOV). This effectively converts a challenging video management problem into a spatial database problem. This paper attacks the challenges of large-scale video data management using spatial indexing and querying of FOVs, especially maximally harnessing the geographical properties of FOVs. Since FOVs are shaped similar to slices of pie and contain both location and orientation information, conventional spatial indexes, such as R-tree, cannot index them efficiently. The distribution of UGVs’ locations is non-uniform (e.g., more FOVs in popular locations). Consequently, even multilevel grid-based indexes, which can handle both location and orientation, have limitations in managing the skewed distribution. Additionally, since UGVs are usually captured in a casual way with diverse setups and movements, no a priori assumption can be made to condense them in an index structure. To overcome the challenges, we propose a class of new R-tree-based index structures that effectively harness FOVs’ camera locations, orientations and view-distances, in tandem, for both filtering and optimization. We also present novel search strategies and algorithms for efficient range and directional queries on our indexes. Our experiments using both real-world and large synthetic video datasets (over 30 years’ worth of videos) demonstrate the scalability and efficiency of our proposed indexes and search algorithms. 相似文献
10.