Morphology and activity of nanosized NdCl3 catalyst for 1,3‐butadiene polymerization

The binary lanthanide catalyst for 1,3‐butadiene was invented for 40 years ago. However, it has not been employed in commercial application due to its poor solubility and low activity. Nanosized neodymium chloride (NdCl₃) was prepared in tetrahydrofuran (THF) medium through dissolution, chelation, and colloidal formation steps. Anhydrous NdCl₃ was dissolved in THF, and ca. 1.5 THF molecules were coordinated. In the colloidal formation step, THF was slowly replaced with the addition of cyclohexane, and pale blue nuclei, nanosize below 200 nm, were formed. The structural studies for NdCl₃ · xTHF using X‐ray powder diffraction (XRD) and scanning electron microscope (SEM) indicate that high ordered crystallinity is decreased with reduced particle size from trigonal prismatic to porous sphere structure. Nano NdCl₃, obtained as colloidal state in cyclohexane, was activated with Al(iBu)₃ and Al(iBu)₂H at room temperature and employed for 1,3‐butadiene solution polymerization. The nanosized Nd catalysts showed high activity (1.0 ～ 1.3 × 10⁵ g/Nd mol · h), which is comparable to that of the ternary neodymium catalyst Nd(neodecanoate)₃/AlEt₂Cl/Al(iBu)₃. The microstructures of polybutadiene, cis, trans, and vinyl, are about 96.0, 3.5, and 0.5%, respectively. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 1279–1283, 2005     

Video-based weathering gallery

We present a simple and effective method for constructing a gallery that consists of weathering effect elements called time-dependent appearance manifolds (TDAMs). Since TDAMs are computed from sample video clips showing dynamic weathering phenomena, they represent very smooth changes in the appearance of weathered pixels over time. Once a gallery with a variety of weathering effects is prepared, users can interactively choose and apply the predefined effects onto the surface of 3D graphic models and then finally assign the most appropriate one. This video-based weathering method can be implemented with very simple algorithms and it supports predictable, intuitive, and natural effects. Our system allows users to produce photorealistic augmented videos that include 3D graphic models weathered by our method. Moreover, users can easily enhance the realism of the augmented videos by manipulating rendering parameters such as the degree of weathering, texturing, lighting, and shadowing through user-friendly graphical user interfaces (GUIs).     

High-speed train navigation system based on multi-sensor data fusion and map matching algorithm

Navigation system for high-speed trains is necessary for increased operational safety and efficiency, new services for customers, and low maintenance cost. This paper proposes a high accuracy navigation system for high-speed trains based on a sensor fusion algorithm, with non-holonomic constraints, for multiple sensors, such as accelerometers, gyroscopes, tachometers, Doppler radar, differential GPS, and RFID, and a map matching algorithm. In the proposed system, we consider the federated Kalman filter for sensor fusion, where local filters utilize filter models developed for various sensor types. Especially, the local Kalman filter for RFID positioning, that is detected at irregular time intervals due to the varying train speed and RFID tag spacing, is developed to maintain high performance during GPS outage. In addition, an orthogonal projection map matching algorithm is developed to improve the performance of the proposed system. The performance of the proposed system is demonstrated with numerous simulations for a high-speed train in Korea. The simulation results are analyzed with respect to the existence of tunnel, RFID deployment spacing, RFID location uncertainty, and DGPS error.     

Design of optimized fuzzy cascade controllers by means of Hierarchical Fair Competition-based Genetic Algorithms

In this study, we present a design of an optimized fuzzy cascade controller based on Hierarchical Fair Competition-based Genetic Algorithms (HFCGA) for a rotary inverted pendulum system. In this system, one controls the movement of a pendulum through the adjustment of a rotating arm. The objective is to control the position of the rotating arm and to make the pendulum maintain the unstable equilibrium point at vertical position. To control the system, we design a fuzzy cascade controller scheme which consists of two fuzzy controllers arrange in a cascaded topology. The parameters of the controller are optimized by means of the HFCGA algorithm. The fuzzy cascade scheme comprises two controllers located in two loops. An inner loop controller governs the position of the rotating arm while an outer controller modifies a set point of the inner controller implied by the changes of the angle of pendulum. The HFCGA being a computationally effective scheme of the Parallel Genetic Algorithm (PGA) has been developed to eliminate an effect of premature convergence encountered in Serial Genetic Algorithms (SGA). It has emerged as an effective optimization vehicle to deal with very large search spaces. A comparative analysis involving computing simulations and practical experiment demonstrates that the proposed HFCGA based fuzzy cascade controller comes with superb performance in comparison with the conventional Linear Quadratic Regulator (LQR) controller as well as HFCGA-based PD cascade controller.     

Evaluation of Phytochemical,Polyphenol Composition and Anti-corrosion Capacity of Cucumis anguria L. Leaf Extract on Metal Surface in Sulfuric Acid Medium

Protection of Metals and Physical Chemistry of Surfaces - Cucumis anguria L. (C. anguria L.) commonly known as Indian gherkin is originally from Africa, though now seen widely in southeast,...     

Binary blends of metallocene polyethylene with conventional polyolefins: Rheological and morphological properties

The rheology and morphology of four sets of binary blends of polyethylene synthesized with metallocene catalysis (metallocene polyethylene: MCPE) with polyolefins prepared using Ziegler‐Natta catalysts have been investigated. The blend systems are MCPE with high density polyethylene (MCPE‐HDPE), polypropylene (MCPE‐PP), poly(propylene‐co‐ethylene) (MCPE‐CoPP), and poly(propylene‐co‐ethylene‐co‐1‐butylene) (MCPE‐TerPP). Cole‐Cole plots [storage melt viscosity (η′) versus loss melt viscosity (η″)], plots of the dynamic storage modulus (G′) versus the dynamic loss modulus (G″), and plots of the log melt viscosity (η*, η′, and η″) versus blend compositions were constructed. The morphology of the blends after microtoming and etching was studied. The phase morphology of MCPE‐HDPE appeared homogeneous, whereas the other three blends were heterogeneous. Rheological and morphological investigations indicated that the MCPE‐HDPE blend was miscible, but the other three blends were immiscible in the melt as well as in the solid state. These observations can be rationalized in terms of the similarity of the chemical structures of the polyolefins.     

Workflow-Based Authorization Service in the Grid

In a distributed environment, a specific right may be required while a task is controlled and processed. A user should delegate enough rights to a task for processing. Tasks cannot work correctly if delegated rights are insufficient, or security threats may occur if delegated rights are excessive. Restricted delegation is the step that delegates proper rights to a task, and that enables fine-grained authorization in the Grid. In this paper, we propose the WAS architecture as a method for supporting restricted delegation and rights management. In contrast to traditional architecture, the WAS architecture uses a workflow that describes the sequence of rights required for normal execution of a task. By using the workflow, the WAS architecture is able to check whether the task exercises allowed rights. The WAS architecture is implemented on Globus toolkit 2.0 and extended on Globus toolkit 3.0.     

Efficient Hausdorff Distance computation for freeform geometric models in close proximity

We present an interactive-speed algorithm for computing the Hausdorff Distance (HD) between two freeform geometric models represented with NURBS surfaces. The algorithm is based on an effective technique for matching a surface patch from one model to the corresponding nearby surface patch on the other model. To facilitate the matching procedure, we employ a bounding volume hierarchy (BVH) for freeform NURBS surfaces, which provides a hierarchy of Coons patches and bilinear surfaces approximating the NURBS surfaces (Kim et al., 2011 [1]). Comparing the local HD upper bound against a global HD lower bound, we can eliminate the majority of redundant surface patches from further consideration. The resulting algorithm and the associated data structures are considerably simpler than the previous BVH-based HD algorithms. As a result, we can compute the HD of two freeform geometric models efficiently and robustly even when the two models are in close proximity. We demonstrate the effectiveness of our approach using several experimental results.     

Phase formation and dielectric properties of (Pb,Ba)[(Zn1/2W1/2),Ti]O3 ceramics

PbTiO₃ and/or BaTiO₃ were systematically introduced into Pb(Zn_1/2W_1/2)O₃ and resultant phase developments in terms of perovskite formation were investigated. Ceramic powders were prepared via a B-site precursor route to further assist the perovskite formation. Weak-field dielectric properties of the sintered samples were examined. For Pb(Zn_1/2W_1/2)O₃-rich compositions, multiphase ceramics resulted and formation of monophasic perovskite turned out to be not successful even by the B-site precursor method. Values of the perovskite formation yield and the maximum dielectric constant increased with increasing fractions of the substituent species.