Hydrolysis of Fe(OH)SO4 in the presence of metallic iron

Hydrolysis of Fe(OH)SO₄ was carried out in the presence of metallic iron in order to prevent the formation of iron(III) oxides with strongly bonded sulphate. Under the conditions of the experiment, the products were found to be mixtures of ?-Fe₂O₃ and α-FeOOH. The occluded sulphate, if any, could be easily washed out with water. The hydrolysis reaction passes through an equilibrium state before coming to completion. The entropy with enthalpy of the hydrolysis corresponding to the equilibrium state were found to be 4 e.u. and 0·5 kJ/mol, respectively. The activation energy of the hydrolysis reaction was found to be 21 kJ/mol.     

A geodesic constant method for computing high-frequency mutual coupling between antennas on general quadric cylinders

Contents A Geodesic Constant Method (GCM) is outlined which provides a common approach to ray tracing on quadric cylinders in general, and yields all the surface ray-geometric parameters required in the UTD mutual coupling analysis of conformal antenna arrays in the closed form. The approach permits the incorporation of a shaping parameter which permits the modeling of quadric cylindrical surfaces of desired sharpness/flatness with a common set of equations. The mutual admittance between the slots on a general parabolic cylinder is obtained as an illustration of the applicability of the GCM.

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Eine geodätische Konstanten-Methode zur Berechnung hochfrequenter wechselseitiger Kopplung zwischen Antennen auf allgemeinen Flächen zweiter Ordnung

Übersicht Dargelegt wird eine geodätische Konstanten-Methode (GKM), die einen gemeinsamen Zugang zur Strahlverfolgung auf allgemeinen Zylindern zweiter Ordnung bietet. Sie liefert sämtliche strahlengeometrischen oberflächenbezogenen Parameter, die in der Uniformen Geometrischen Beugungstheorie (UTD) für die wechselseitige Kopplungsanalyse konformer Antennenarrays benötigt werden, in geschlossener Form. Der Zugang gestattet die Einbeziehung eines Formparameters, der die Modellierung von Zylinderflächen zweiter Ordnung mit gewünschter Spitzigkeit/Flachheit durch ein und dasselbe Gleichungssystem zuläßt. Die erhaltene wechselseitige Admittanz zwischen Schlitzen auf einem allgemeinen parabolischen Zylinder dient zur Veranschaulichung der Anwendbarkeit der GKM.

     

A balanced solution of a fuzzy soft set based decision making problem in medical science

The purpose of this paper is two folded. Firstly, the concept of mean potentiality approach (MPA) has been developed and an algorithm based on this new approach has been proposed to get a balanced solution of a fuzzy soft set based decision making problem. Secondly, a parameter reduction procedure based on relational algebra with the help of the balanced algorithm of mean potentiality approach has been used to reduce the choice parameter set in the parlance of fuzzy soft set theory and it is justified to the problems of diagnosis of a disease from the myriad of symptoms from medical science. Moreover the feasibility of this proposed method is demonstrated by comparing with Analytical Hierarchy Process (AHP), Naive Bayes classification method and Feng's method.     

Time temperature equivalence in plasticized PVC

The viscoelastic response of plasticized PVC was determined from stress-relaxation data over a wide range of time at different temperatures. The relaxation modulus as a function of time was determined from these data. The relaxation curves were then shifted horizontally to obtain a master curve at a reference temperature. The amount of shift was evaluated using the WLF equation. The coefficients C and C used in the equation for the PVC were determined according to the method of reduced variables.     

Oxidation Behavior of Rh–30Ni–18Nb Refractory Superalloy

The isothermal-oxidation behavior of Rh–30Ni–18Nb refractory alloy was investigated up to a period of 312 hours in air from 1000 to 1350°C. A comparison of the oxidation behavior of this alloy with a conventional Ni-base superalloy (Inconel 713 C) shows an order-of-magnitude higher oxidation resistance. This experimental alloy oxidizes by forming alternate layers of Nb₂O₅ and RhO while NiO is on the surface in contact with air. Optical and scanning-electron microscopy (SEM) was used to study the microstructure and morphology for the characterization of the oxides. Thermal stability of the alloy for extended periods of exposure to air at 1400°C was studied using transmission-electron microscopy (TEM).     

Pyramid coding based rate control for constant bit rate video streaming

In this paper, a novel pyramid coding based rate control scheme is proposed for video streaming applications constrained by a constant channel bandwidth. To achieve the target bit rate with the best quality, the initial quantization parameter (QP) is determined by the average spatio-temporal complexity of the sequence, its resolution and the target bit rate. Simple linear estimation models are then used to predict the number of bits that would be necessary to encode a frame for a given complexity and QP. The experimental results demonstrate that the proposed rate control scheme significantly outperforms the existing rate control scheme in the Joint Model (JM) reference software in terms of Peak Signal to Noise Ratio (PSNR) and consistent perceptual visual quality while achieving the target bit rate. Finally, the proposed scheme is validated through experimental evaluation over a miniature test-bed.

     

NodeWiz: Fault-tolerant grid information service

Large scale grid computing systems may provide multitudinous services, from different providers, whose quality of service will vary. Moreover, services are deployed and undeployed in the grid with no central coordination. Thus, to find out the most suitable service to fulfill their needs, or to find the most suitable set of resources on which to deploy their services, grid users must resort to a Grid Information Service (GIS). This service allows users to submit rich queries that are normally composed of multiple attributes and range operations. The ability to efficiently execute complex searches in a scalable and reliable way is a key challenge for current GIS designs. Scalability issues are normally dealt with by using peer-to-peer technologies. However, the more reliable peer-to-peer approaches do not cater for rich queries in a natural way. On the other hand, approaches that can easily support these rich queries are less robust in the presence of failures. In this paper we present the design of NodeWiz, a GIS that allows multi-attribute range queries to be performed efficiently in a distributed manner, while maintaining load balance and resilience to failures.     

Test Case Prioritization in Unit and Integration Testing: A Shuffled-Frog-Leaping Approach

Both unit and integration testing are incredibly crucial for almost any software application because each of them operates a distinct process to examine the product. Due to resource constraints, when software is subjected to modifications, the drastic increase in the count of test cases forces the testers to opt for a test optimization strategy. One such strategy is test case prioritization (TCP). Existing works have propounded various methodologies that re-order the system-level test cases intending to boost either the fault detection capabilities or the coverage efficacy at the earliest. Nonetheless, singularity in objective functions and the lack of dissimilitude among the re-ordered test sequences have degraded the cogency of their approaches. Considering such gaps and scenarios when the meteoric and continuous updations in the software make the intensive unit and integration testing process more fragile, this study has introduced a memetics-inspired methodology for TCP. The proposed structure is first embedded with diverse parameters, and then traditional steps of the shuffled-frog-leaping approach (SFLA) are followed to prioritize the test cases at unit and integration levels. On 5 standard test functions, a comparative analysis is conducted between the established algorithms and the proposed approach, where the latter enhances the coverage rate and fault detection of re-ordered test sets. Investigation results related to the mean average percentage of fault detection (APFD) confirmed that the proposed approach exceeds the memetic, basic multi-walk, PSO, and optimized multi-walk by 21.7%, 13.99%, 12.24%, and 11.51%, respectively.