Nano-Al doped-MoO3 high-energy composite films with excellent hydrophobicity and thermal stability

Developing the thermal stability of metal-based ceramic composites or their films has always been challenging and bottlenecks for the utilization of energy. In this paper, the novel mesh-like functional Al doped-MoO₃ nanocomposite film with even distribution and high purity was firstly fabricated by the high-efficiency electrophoretic deposition and surface modification. The optimal suspension turned out to be the mixture of isopropanol and the additives of polyethyleneimine and benzoic acid. The microtopography, crystalline structure, environmental resistance and thermal stability were analyzed by field emission scanning electron microscope (FESEM), energy dispersive X-ray (EDX), X-ray diffractometer (XRD), exposure and droplet-impacting test, DSC analysis and ignition test, respectively. The water contact angle and sliding angle of product can reach ~170° and <1°, indicating the excellent anti-wetting property. In addition, the high heat-release (~3180 J/g) of product all kept almost unchangeable after six months exposure experiments, demonstrating the outstanding thermostability. The exquisite design idea here can perfectly match microelectromechanical system (MEMS), providing the valuable reference for fabricating other metal-based high-energy composites with long lifespan for real industrial applications.     

上覆水磷浓度对沉积物孔隙水中磷垂向分布的影响

为探究上覆水磷浓度对沉积物孔隙水中磷垂向分布的影响,通过室内实验,利用薄膜扩散平衡技术(DET)对孔隙水中磷浓度进行测量,分析孔隙水磷浓度的垂向变化规律,并揭示平衡时上覆水磷浓度与孔隙水磷浓度以及上覆水-沉积物界面孔隙水磷浓度的关系。结果表明:上覆水磷浓度越高,则沉积物孔隙水中磷垂向分布达到平衡所需的时间越长,相同垂向位置处孔隙水磷浓度及其浓度梯度越大;孔隙水磷浓度及其浓度梯度随深度增加而降低,表层沉积物孔隙水中磷的扩散作用最强,下层沉积物孔隙水磷浓度受上覆水磷浓度变化影响较小;吸附平衡后,沉积物孔隙水磷浓度和上覆水-沉积物界面孔隙水磷浓度均与上覆水磷浓度呈幂函数关系,而留存在沉积物孔隙水中的磷浓度仅占2.26%～3.80%,上覆水中减少的磷大部分被沉积物吸附。     

Birman–Wenzl–Murakami algebra, topological parameter and Berry phase

In this paper, a 3?×?3-matrix representation of Birman?CWenzl?CMurakami (BWM) algebra has been presented. Based on which, unitary matrices A(??, ?? ₁, ?? ₂) and B(??, ?? ₁, ?? ₂) are generated via Yang?CBaxterization approach. A Hamiltonian is constructed from the unitary B(??, ??) matrix. Then we study Berry phase of the Yang?CBaxter system, and obtain the relationship between topological parameter and Berry phase.     

基于协同观测器的永磁同步电机无传感控制

针对传统滑模观测器使用符号函数引起的抖振问题,提出了一种基于连续函数的协同观测器方法,实现永磁同步电机(PMSM)的无传感控制。首先,研究PMSM的离散数学模型。其次,建立k+1时刻的电流偏差和k时刻的电流偏差之间的函数关系。最后,利用反正切函数计算转子位置并加入角度补偿,提高观测精度。仿真结果表明,所设计的协同观测器不仅无抖振现象,还具有更高的估算精度及良好的抗干扰性能,比传统滑模观测器可以更好地实现PMSM的无传感控制。     

Coalescence dynamics of two droplets of different viscosities in T-junction microchannel with a funnel-typed expansion chamber

The coalescence behavior of two droplets with different viscosities in the funnel-typed expansion cham-ber in T-junction microchannel was investigated experimentally and compared with droplet coalescence of the same viscosity.Four types of coalescence regimes were observed:contact non-coalescence,squeeze non-coalescence,two-droplet coalescence and pinch-off coalescence.For droplet coalescence of different viscosities,the operating range of non-coalescence becomes narrowed compared to the droplet coalescence of same viscosity,and it shrinks with increasing viscosity ratio η of two droplets,indicating that the difference in the viscosity of two droplets is conducive to coalescence,especially when 1 ＜ η＜ 6.Furthermore,the influences of viscosity ratio and droplet size on the film drainage time (Tdr) and critical capillary number (Cac) were studied systematically.It was found that the film drainage time declined with the increase of average droplet size,which abided by power-law relation with the size dif-ference and viscosity ratio of the two droplets:Tdr ～ (ld)0.25±0.04 and Tdr ～ (η)-0.1±002.For droplet coales-cence of same viscosity,the relation of critical capillary number with two-phase viscosity ratio and dimensionless droplet size is Cac =0.48λ0.26l-2.64,while for droplet coalescence of different viscosities,the scaling of critical capillary number with dimensionless average droplet size,dimensionless droplet size difference and viscosity ratio of two droplets is Cac =0.11 η-0.07ls-2.23ld0.16.     

The topological basis realization and the corresponding Heisenberg model of spin-1 chain

In this paper, it is shown that the Heisenberg model of spin-1 chain can be constructed from the Birman–Wenzl algebra generator while we have got that the Heisenberg model of spin- $\frac{1}{2}$ chain can be constructed from the Temperley–Lieb algebra generator in our previous work (Sun et al. in EPL 94:50001, 2011). Here, we investigate the topological space, we find that the number of topological basis states raise from the previous two to three, and they are also the three eigenstates of a closed four-qubit Heisenberg model of spin-1 chain. Specifically, all the topological basis states are also the spin single states and one of them is the energy single state of the system. It is worth noting that all conclusions we get in this paper are consistent with our previous work (Sun et al. in EPL 94:50001, 2011). These just indicate that the topological basis states have particular properties in the system.     

表面活性剂对聚乙烯醇水溶液黏度影响的研究

研究了阴离子十二烷基硫酸钠、阳离子十六烷基三甲基溴化铵和非离子壬基酚聚氧乙烯醚等3种不同类型的表面活性剂对聚乙烯醇溶液黏度性质的影响。结果表明,离子型表面活性剂与聚乙烯醇发生疏水链相互作用使高聚物带有电荷,体系黏度增加;非离子表面活性剂与聚乙烯醇无相互作用,体系黏度不变;盐的加入,只对聚乙烯醇/离子型表面活性剂混合体系影响大,而对聚乙烯醇/非离子型表面活性剂混合体系无影响。     

Fabrication and mechanical properties of Al<Subscript>2</Subscript>O<Subscript>3</Subscript>/TiAl composites

Al₂O₃/TiAl composites were successfully fabricated by hot-press-assisted exothermic dispersion method with elemental powder mixtures of Ti, Al TiO₂ and Nb₂O₅, and the microstructure and mechanical properties were investigated. The results indicate the fine Al₂O₃ particles tend to disperse on the grain boundaries. The grain size of TiAl matrix decreases and the hardness increases with increasing Nb₂O₅ content. The bending strength and fracture toughness reach to a maximum when Nb₂O₅ content is 6 wt%, under 642 MPa and 6.69 MPa·m^1/2, respectively. Based on the fractography and the observation of crack propagation path, it is concluded that the strengthening and toughening of such composites at room temperature can be attributed to the refinement of the TiAl matrix, the deflection behavior in the crack propagation and the dispersion of Al₂O₃ particles.     

改进Faster R-CNN的汽车仪表指针实时检测

针对产业化的汽车仪表指针人工视觉检测效果差、检测速度慢和实时性低等问题,本文提出了一种改进的Faster R-CNN汽车仪表指针实时检测算法。通过改进原始的RoI网络层结构,实现小目标高低层特征之间的完整传递;采用双线性内插算法替代两次量化操作,使得特征聚集变成连续的过程,能够有效减少计算时间;最后将工业机采集的视频数据,预处理成VOC格式数据集进行训练,调整超参数得到改进汽车仪表指针检测模型。实验结果表明:所提出的方法能够快速、准确地实现汽车仪表指针检测,单张图片的平均检测时间为0.197 s,平均检测精度可达92.7%。在不同类别仪表指针的迁移实验中,展示了良好的泛化性能。