The effect of temperature on the dynamic characteristics of heat-resistant thermoplastic composites

Two thermoplastic and two thermosetting fibrereinforced plastic composites were subjected to dynamic tests over a wide range of temperature, covering both cryogenic and hot environments. The thermal behaviour of each composite, as indicated by its dynamic mechanical properties, was assessed individually, and was compared collectively with that of the other composites.     

Stabilization of Cubic Zirconia with Manganese Oxide

A directionally solidified eutectic (DSE) of MnO-ZrO₂ has been investigated using a variety of electron optical techniques. It is found that considerable MnO goes into ZrO₂ to form a substitutional solid solution. About 14 wt% of MnO is soluble in ZrO₂ close to the eutectic temperature. The solubility of ZrO₂ in MnO, however, is quite low, less than 0.50 wt%. Electron diffraction experiments indicate that ZrO₂ (MnO) has the cubic fluorite structure. Diffuse scattering, similar to other cubic zirconias (e.g., CaO, MgO stabilized zirconia), is also observed in manganese-stabilized zirconia. Diffuse scattering indicates the presence of oxygen vacancies and thus confirms the defect nature of the fluorite structure. Electron energy loss spectrometry (EELS) fine structure analysis of the Mn L₂₃ edge provided clear evidence that Mn is present as Mn²⁺ in Mn-stabilized cubic ZrO₂.     

Linear Programming Formulation for Strategic Dynamic Traffic Assignment

This work introduces a novel formulation of system optimal dynamic traffic assignment that captures strategic route choice in users under demand uncertainty. We define strategic route choice to be that users choose a path prior to knowing the true travel demand which will be experienced (therefore users consider the full set of possible demand scenarios). The problem is formulated based on previous work by Ziliaskopoulos (Transp Sci 34(1):37–49, 2000). The resulting novel formulation requires substantial enhancement to account for path-based flows and scenario-based stochastic demands. Further, a numerical demonstration is presented on a network with different demand loading profiles. Finally, model complexity, implications on scalability and future research directions are discussed.     

A General Equilibrium Framework for Integrated Assessment of Transport and Economic Impacts

The use of separate transport and economic models in urban planning provides a limited view of economic impacts, restricts the testing of network design options and lengthens the planning process. Furthermore, the standard methodology for economic appraisal assumes partial economic equilibrium and cannot determine the distribution of impacts from the transport sector to households. Computable general equilibrium (CGE) models can capture general equilibrium effects and measure welfare at the household level, but mostly lack integration with transport models and do not represent all trip generators. This paper develops an integrated traffic assignment and spatial CGE model in nonlinear complementarity form, casted as a framework for economic appraisal of urban transport projects. The CGE submodel generates commuting, shopping and leisure trips as inputs into the transport submodel, which then assigns trips to the network according to user equilibrium. The resulting travel times then feed back into household prices and freight margins. Households and firms fully account for travel times in decisions on where to shop, how much labour to supply and where to source production inputs. Calibration and applications of the model are demonstrated for 14 regions and 2 industries across Sydney using GAMS/PATH on the NEOS server. The welfare of various network improvements is measured using equivalent variations. The model can be calibrated to external strategic transport models, and be extended to simulate additional trip generators and land-use.     

Analytical modeling of Transmission Control Protocol NewReno using Generalized Stochastic Petri Nets

This paper presents a novel analytical model of Transmission Control Protocol (TCP) using a generalized stochastic Petri net (GSPN). Extensive simulation work has been done for the performance evaluation of TCP NewReno protocol. In view of the limitations of the simulation technique, we present an analytical approach using GSPN. A GSPN is a useful mathematical tool that solves continuous time Markov chains for complex systems and evaluates the stationary behavior. In this paper, we analyze the slow‐but‐steady variant of TCP NewReno. The model captures the behavioral aspects of the slow start and the congestion avoidance phase together with the fast retransmit and recovery capabilities of TCP NewReno. Performance metrics such as throughput, goodput, and task completion time of the system are obtained. The effect of variation in the model parameters on the performance is studied. The results are validated using the network simulator, and their accuracy is verified by evaluating the confidence interval. The performance of the proposed model is compared with that of TCP Reno. The performance of the proposed model is also compared with one of the previous models. The numerical illustrations and comparison of the proposed technique with simulation validates the accuracy, efficiency, and competence of the GSPN technique. While GSPN modeling for TCP is investigated in depth for the TCP NewReno and TCP Reno variant in this paper, other protocols could be also analyzed similarly. Copyright © 2013 John Wiley & Sons, Ltd.     

Conjugation of curcumin with PVP capped gold nanoparticles for improving bioavailability

Curcumin, a natural polyphenolic compound, has astounding therapeutic applications but lacks in bioavailability mainly due to its poor solubility in water. Polyvinyl pyrrolidone (PVP) which is a proven drug carrier has been used to facilitate the conjugation of curcumin with gold nanoparticles and to improve the solubility of curcumin in water. In this conjugate diaryl heptanoid chromophore group of curcumin which is a much needed group in biomedical applications remains intact as observed from FTIR and UV–vis spectroscopy analysis. The work shows good promise for such conjugates as therapeutic-cum-imaging materials in biomedical field.     

Mechanical Characterization of Austempered Ductile Iron Obtained by Two Step Austempering Process

Austempered ductile iron (ADI) is known to have a good combination of mechanical properties due its unique ausferrite microstructure. The strength of ADI is mainly a function of the austempering temperature and the stability of ausferrite matrix. To increase the stability of the ausferritic matrix, two stage austempering processes was developed. During this investigation, in the Ist step, ductile iron specimens were austenitized at 900 °C for 60 min followed by quenching to 250 °C in salt bath. In the IInd step, after quenching at 250 °C, the salt bath was gradually heated to 350 °C, 400 °C and 450 °C respectively where specimen were soaked for 120 min. The tensile strength and impact strength were evaluated according to ASTM standards. The results were compared with that obtained by conventional austempering process by quenching directly into salt bath at 400 °C for 120 min. Both tensile and impact strength were found to have improved by two step austempering process. During Ist stage of austempering, martensite was observed while during IInd stage of austempering microstructures revealed acicular ferrite and carbon stabilized austenite. The fractographic examination revealed mixed type of fracture mode and intergranular fracture was seen under SEM. It was further observed that the tensile strength decreased whereas the impact strength increased with IInd stage of austempering temperature.     

Hierarchical mapping of spot defects to catastrophic faults-designand applications

This paper describes the defect to fault mapper (DEFAM), and its use in integrated circuit test quality analysis and yield prediction. DEFAM analyzes the effects of spot defects on a design during the manufacturing process, and computes the probability of circuit faults that may occur. Unlike traditional tools, DEFAM exploits the design hierarchy to reduce the required analysis effort. It also reports faults in terms of the design hierarchy, which is essential for many applications. Yield analysis results are given for CMOS designs of up to 164 K transistors. Test quality analysis results are given for an adder module     

Ultrarapid Phase Conversion in β"-Alumina Tubes

β"-Alumina, the electrolyte of choice of sodium/sulfur and sodium/metal chloride batteries and alkali-metal thermal-electric converters, was sintered from precursor phases to high β"-phase purity in less than 15 s from the onset of densification by rapid pass-through rf induction coupled plasma sintering. The maximum instantaneous shrinkage rate was 1.8%/s. The resistivity was measured to be 13.8 ± 1.4 Ω·cm. The rapid conversion found is a significant improvement over conventional processing of β"-alumina, which requires extended postsintering annealing times to obtain high β"-phase purity.