One step from nanofiber to functional hybrid structure: Pd doped ZnO/SnO2 heterojunction nanofibers with hexagonal ZnO columns for enhanced low-temperature hydrogen gas sensing

In this paper, a novel hybrid structure of Pd doped ZnO/SnO₂ heterojunction nanofibers with hexagonal ZnO columns was one step synthesized from electrospun precursor nanofibers. Due to the synergistic effect of hexagonal ZnO, SnO₂ and Pd, the structure exhibited excellent hydrogen (H₂) gas sensing properties. At low-temperature of 120 °C, the response (R_a/R_g) to 100 ppm H₂ gas exceeded 160, the response/recovery time was only 20 s and 6 s respectively and the limit of detection was only 0.5 ppm. Meanwhile, it also had good selectivity for H₂ gas and excellent linearity. In addition, the materials were characterized by XRD, FESEM, HRTEM, XPS, and the synthesis mechanism and gas sensing mechanism were proposed.     

Phase and microstructure evolution of Sc2O3–CeO2 –ZrO2ceramics in Na2SO4 + V2O5 molten salts

In this study, the destabilization resistance of Sc₂O₃ and CeO₂ co-stabilized ZrO₂ (SCZ) ceramics was tested in Na₂SO₄ + V₂O₅ molten salts at 750°C–1100 °C. The phase structure and microstructure evolution of the samples during the hot corrosion testing were analyzed with X-ray diffraction (XRD), Raman spectra, scanning electron microscopy (SEM), energy dispersive X-ray spectrum (EDS), and X-ray photoelectron spectroscopy (XPS). Results showed that the destabilization of SCZ ceramics at 750 °C was the result of the chemical reaction with V₂O₅ to produce m-ZrO₂ and CeVO₄, and little ScVO₄ was detected in the Sc₂O₃-rich SCZ ceramics. The primary corrosion products at 900 °C and 1100 °C were CeO₂ and m-ZrO₂ due to the mineralization effect. The Sc₂O₃-rich SCZ ceramics exhibited excellent degradation resistance and phase stability owing to the enhanced bond strength and the decreased size misfit between Zr⁴⁺ and Sc³⁺. The destabilization mechanism of SCZ ceramic under hot corrosion was also discussed.     

Recent Development of Photothermal Agents (PTAs) Based on Small Organic Molecular Dyes

Photothermal therapy (PTT) has attracted great attention due to its noninvasive and effective use against cancer. Various photothermal agents (PTAs) including organic and inorganic PTAs have been developed in the last decades. Organic PTAs based on small-molecule dyes exhibit great potential for future clinical applications considering their good biocompatibility and easy chemical modification or functionalization. In this review, we discuss the recent progress of organic PTAs based on small-molecule dyes for enhanced PTT. We summarize the strategies to improve the light penetration of PTAs, methods to enhance their photothermal conversion efficiency, how to optimize PTAs’ delivery into deep tumors, and how to resist photobleaching under repeated laser irradiation. We hope that this review can rouse the interest of researchers in the field of PTAs based on small-molecule dyes and help them to fabricate next-generation PTAs for noninvasive cancer therapy.     

定向井技术在白庙气田产能建设中的应用

东濮凹陷白庙气田构造破碎、储层相变快、储量分布不均匀。如何以较少的钻井投资，尽量多地钻遇气层层数，以较少的钻井数最大限度地控制气田地质储量，是高效开发白质气田的难点。通过气田地质研究及气藏工程论证，提出定向井设计思路，并根据不同的地质条件，研究设计出不同类型的定向井，应用于白庙气田产能建设中，效果显著。     

Synthesis and characterization of photopolymerizable hydrogels based on poly (ethylene glycol) for biomedical applications

Hydrogels are polymeric materials widely used in medicine due to their similarity with the biological components of the body. Hydrogels are biocompatible materials that have the potential to promote cell proliferation and tissue support because of their hydrophilic nature, porous structure, and elastic mechanical properties. In this work, we demonstrate the microwave-assisted synthesis of three molecular weight varieties of poly(ethylene glycol) dimethacrylate (PEGDMA) with different mechanical and thermal properties and the rapid photo of them using 1-hydroxy-cyclohexyl-phenyl-ketone (Irgacure 184) as UV photoinitiator. The effects of the poly(ethylene glycol) molecular weight and degree of acrylation on swelling, mechanical, and rheological properties of hydrogels were investigated. The biodegradability of the PEGDMA hydrogels, as well as the ability to grow and proliferate cells, was examined for its viability as a scaffold in tissue engineering. Altogether, the biomaterial hydrogel properties open the way for applications in the field of regenerative medicine for functional scaffolds and tissues.     

dsPIC33FJ256MC710疑难问题及解决方法

引言 美国微芯公司推出的dsPIC33FJ256MC710高性能16位数字信号控制器,采用了改进型的哈佛架构、C编译器优化的指令集、流水线取指令方式,具有实用、低价、指令集小、功耗低、速度高、体积小、功能强、抗干扰能力强等特点。dsPIC33FJ256MC710高性能16位数字信号控制器内含有12位的A／D转换器（500ksps）、直接存储器访问（DMA）、比较输出、捕捉输入、I^2C接口、SPI接口、CAN接口、USART接口、     

Balancing MXene Surface Termination and Interlayer Spacing Enables Superior Microwave Absorption

Surface chemistry and interlayer engineering determines the electrical properties of 2D MXene. However, it remains challenging to regulate the surface and interfacial chemistry of MXene simultaneously. Herein, simultaneous modulation of Ti₃C₂T_x MXene surface termination and layer spacing by alkali treatment are achieved. The electrical and electromagnetic properties of Ti₃C₂T_x are investigated in detail with respect to KOH and ammonia concentration dependence. A high concentration of KOH caused the Ti₃C₂T_x layer spacing to expand to 13.7 Å and the surface O/F ratio to increase to 33.84. Because of its weaker ionization effect, ammonia provides finer tuning compared to the drastic intercalation of KOH with a thorough sweeping of the F-containing groups. Ti₃C₂T_x is enriched with conductive -OH termination after ammonia treatment, which achieves an effective balance with the increased interlayer resistance. Therefore, NH₃H₂O-Ti₃C₂T_x achieves broad-band impedance matching and exhibits an efficient microwave loss of −49.1 dB at a low thickness of 1.7 mm, with an effective frequency bandwidth of 3.9 GHz. The results herein optimize the electrical properties of Ti₃C₂T_x using surface and interfacial chemistry to achieve broad microwave absorption, providing a framework for enhancing the electromagnetic wave loss of intrinsic MXene.     

融合多尺度特征的复杂手势姿态估计网络

目的 基于单幅RGB图像的手势姿态估计受手势复杂性、手指特征局部自相似性及遮挡问题的影响,导致手势姿态估计准确率低。为此,提出一种面向单目视觉手势姿态估计的多尺度特征融合网络。方法 1）采用ResNet50(50-layer residual network)模块从RGB图像提取不同分辨率特征图,通过通道变换模块显式地学习特征通道间的依赖关系,增强重要的特征通道信息,弱化次要的特征通道信息。2）在全局回归模块中,通过设计节点间的连接方式融合不同分辨率特征图,以便充分利用图像的细节与整体信息。采用局部优化模块继续提取更深层的特征信息,获得手部关节点的高斯热图,以此修正遮挡等原因造成部分关节点回归不准确的问题。3）计算经通道变换模块处理后的最小特征图,通过全局池化和多层感知机处理该特征图以获得手势类别和右手相对于左手的深度。4）综合以上结果获得最终的手势姿态。结果 采用InterHand2.6M和RHD(rendered handpose dataset)数据集训练多尺度特征融合网络,评估指标中根节点的平均误差和关节点的平均误差,均低于同类方法,且在一些复杂和遮挡的场景下鲁棒性更高。在In...     

基于AEKF滤波与H∞滤波的锂离子电池SOC联合估计

锂电池荷电状态（SOC）的准确估计对提高电池的动态性能和能量利用率至关重要。针对现有卡尔曼滤波SOC估计方法存在估计精度低、鲁棒性差等问题,采用锂离子电池的二阶电阻-电容等效电路模型,通过HPPC循环脉冲实验和动态应力测试工况放电实验,结合带可变遗忘因子的递推最小二乘法（VFFRLS）及开窗理论,对等效电路模型参数进行在线辨识,提出利用自适应扩展卡尔曼滤波（AEKF）算法和H_∞滤波算法联合估计SOC的方法。结果表明：与AEKF算法相比,在DST工况下该算法可以使电池荷电状态估计的最大绝对误差减小3.902 9%,平均绝对误差减小0.962 2%,均方根误差减小0.551 5%。与H_∞滤波算法相比,在DST工况下该算法可以使电池荷电状态估计最大绝对误差减小1.309%,平均绝对误差减小2.893 4%,均方根误差减小2.613 6%。     

基于Isight与Tosca的抗侧滚扭杆装置优化分析

基于Isight和Tosca软件对抗侧滚扭杆装置轻量化设计问题进行优化分析.采用Isight软件集成Abaqus软件对扭杆轴进行结构参数优化分析;采用Tosca软件集成Abaqus软件和fe-safe软件对扭转臂进行结构拓扑优化分析,研究扭杆轴与扭转臂的轻量化设计方法.