A practical Equivalent Electrical Circuit model for Proton Exchange Membrane Fuel Cell (PEMFC) systems

An alternative Equivalent Electrical Circuit for Proton Exchange Membrane Fuel Cells is modelled in this study. Both I–V characteristics and H₂ consumptions corresponding to generated power under load and no-load conditions are investigated. For this purpose, H₂ consumptions and I–V characteristics of three different sized PEMFCs are tested. There is a very good harmony between the model results and measured values (relative error %0.7, %6.4 and %2.5 for FC-A, FC-B and FC-C respectively). In the proposed model current passes only on parallel resistance and not on serial resistance at no-load condition. Thus, a FC with higher parallel resistance should be preferred. Another key output of this study is that based on the proposed model, performance comparison of FCs can be performed with the parameters defined in this work. Proposals made in this study can easily be used for performance analysis of FCs under for both steady state and transient analysis.     

Group sequential crossover trial designs with strong control of the familywise error rate

Crossover designs are an extremely useful tool to investigators, and group sequential methods have proven highly proficient at improving the efficiency of parallel group trials. Yet, group sequential methods and crossover designs have rarely been paired together. One possible explanation for this could be the absence of a formal proof of how to strongly control the familywise error rate in the case when multiple comparisons will be made. Here, we provide this proof, valid for any number of initial experimental treatments and any number of stages, when results are analyzed using a linear mixed model. We then establish formulae for the expected sample size and expected number of observations of such a trial, given any choice of stopping boundaries. Finally, utilizing the four-treatment, four-period TOMADO trial as an example, we demonstrate that group sequential methods in this setting could have reduced the trials expected number of observations under the global null hypothesis by over 33%.     

Partitioning of predominant lipophilic bioactives (squalene, α-tocopherol and β-sitosterol) during olive oil processing

The partitioning of predominant lipophilic olive bioactives (squalene, β-sitosterol and α-tocopherol) in olive oil processing was studied for the first time using common integrated olive milling plant. 7% of the oil and 5% of the squalene present in the olives was lost in the last pomace. β-sitosterol and α-tocopherol, which are mainly concentrated in the seed of the olive fruit, was recovered in virgin olive oil to a lesser extent (66%, 67%) while 10% were lost in last pomace. Thus, the loss of β-sitosterol and α-tocopherol was higher than that of squalene and oil, due to nonrecovered bound forms. 19% of the α-tocopherol and 21% of the β-sitosterol loss was unaccounted for, which can be attributed to degradation of α-tocopherol and incomplete recovery of sterols from the olive and pomace matrices. This study provides a basis for process development studies.     

Optimal design of elastic beams with segmentwise constant height in the case of dynamic loading

A shape optimization method for elastic beams with segmentwise constant height is proposed. The ends of the beam are simply supported, clamped or free. Two problems are discussed; (i) a beam is loaded by lateral pressure, (ii) a beam is struck by an attached mass. External loads and volume of the beam are prescribed and the deflection in a given cross-section is to be minimized. For solving this problem, the deflections are expanded into a Fourier series by eigenfunctions. Numerical results are given for two-, three- and four-stepped beams.     

工业项目的海绵城市建设标准与技术要点

工业用地是城市建设用地的主要类型之一,是海绵城市建设的重要区域。通过梳理工业项目硬化面积高、径流污染程度高等特征,针对性提出其海绵城市建设的实施路径、建设标准和技术应用等实施建议。工业项目的海绵城市设计应遵循因地制宜的原则,应合理布局绿地并建设海绵设施,通过精细化的标高设计进行径流组织设计;对于降雨径流污染严重的三类工业项目,其海绵措施应以雨水调蓄池(应急事故池)为主,严禁设置具有渗透功能的源头控制设施。对于三类工业项目,海绵城市所提出的年径流总量控制率的目标与事故池的环保要求基本一致,建议相关部门在制定(修订)的应急事故池设计标准时,其中的径流污染控制体积可与对应区域年径流总量控制率标准协同一致。     

Polymeric absorbent for water sorption based on chemically crosslinked poly (acrylamide/2-acrylamido-2-methyl-1-propanesulfonic acid sodium salt) hydrogels

Summary Swelling equilibrium of polyelectrolyte copolymer gels containing of acrylamide (AAm) and 2-acrylamido-2-methyl-1-propanesulfonic acid sodium salt (AMPS) have been studied as a function of copolymer composition. AAm/AMPS hydrogels were prepared by free radical solution polymerization in aqueous solution of AAm with AMPS as anionic comonomer and two multifunctional crosslinkers such as ethylene glycol dimethacrylate (EGDMA) and trimethylolpropane triacrylate (TMPTA). Swelling experiments were performed in water at 25 °C, gravimetrically. The influence of AMPS content in hydrogels was examined. Swelling of AAm/AMPS hydrogels was increased up to 1018% (for containing 2% AMPS and crosslinked by EGDMA) 15246% (for containing 8% AMPS and crosslinked by TMPTA), while AAm hydrogels swelled up to 804% (crosslinked by TMPTA)–770% (crosslinked by EGDMA). The values of equilibrium water content of the hydrogels are 0.8851–0.9935. Diffusion behavior was investigated. Water diffusion into hydrogels was found to be non-Fickian in character.     

基于信道状态特征的手势动作识别技术研究

手势识别作为人和机器之间重要的交互手段,在日常生活中具有广泛的应用场景。基于无线信号特别是WiFi的手势识别由于其无接触、成本低等优点成为当前热门的方式。为解决传统基于无线信号手势识别算法没有充分利用信号相位特征的缺点,本文提出利用WiFi信道状态信息幅值和相位结合的方式进行手势识别。通过子载波降维和动作曲线提取对接收的WiFi信号进行处理,并将信号的幅值和相位结合,利用机器学习算法对数据进行训练和分类,实现了单手向前、单手向后、单手向左、单手向右、单手向上和单手向下六种手势的识别。实验结果显示,本文算法在近距离和远距离下的精确度分别为96%和92%。     

Design of Lu2O3-reinforced Cf/SiC-ZrB2-ZrC ultra-high temperature ceramic matrix composites: Wetting and interfacial reactivity by ZrSi2 based alloys

The wettability and infiltration of molten ZrSi₂ and ZrSi₂-Lu₂O₃ alloys into C_f/SiC and B₄C-infiltrated C_f/SiC composites were investigated to understand the interfacial interactions that occur during the development of C_f/SiC-ZrC and C_f/SiC-ZrB₂-ZrC-Lu₂O₃ materials. A significant evaporation of Si from the liquid affected the wetting behaviour of the alloy when tested in a vacuum at 1670 °C. The better wetting and spreading of the alloy over the surface was observed for the composites with lower overall porosity (12 %). On the other hand, the formation of an outer dense layer, followed up by the uniform infiltrated region up to ～ 1 mm was observed for the C_f/SiC with higher porosity (21 %). The infiltrated alloy reacted with SiC matrix to form ZrC or with B₄C-infiltrated SiC matrix to form ZrB₂-ZrC-SiC. The Lu₂O₃ particles were not wetted by the melt, and were pushed away of the reaction zone by the solidification front.