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1.
Ravan A. Rahimov Gulnara A. Ahmadova Seyid-Zeynab F. Hashimzade Elmar Imanov Hajibala G. Khasiyev Nazani K. Karimova Fedor I. Zubkov 《Journal of surfactants and detergents》2021,24(3):433-444
Two new classes of gemini cationic surfactants—hexanediyl-1,6-bis[(isopropylol) alkylammonium] dibromide {in the abbreviation form: CnC6Cn[iPr-OH] and CnC6Cn[iPr-OH]2; alkyl: CnH2n + 1 with n = 9, 10, 12 and 14}—have been synthesized by interaction of alkyl bromides with N,N′-di-(isopropylol)-1,6-diaminohexane and N,N,N′,N′-tetra-(isopropylol)-1,6-diaminohexane. The surface tension, electrical conductivity, and dynamic light scattering (DLS) techniques were used to investigate the aggregation properties of the gemini cationic surfactants in aqueous solution. The formation of critical aggregates at two concentrations in an aqueous solution from obtained gemini cationic surfactants were determined via the tensiometric method. Thus, these gemini cationic surfactants start to form aggregates at concentrations well below their critical micelle concentrations (CMC). The surface properties and the binding degree (β) of the opposite ion were tested against the length of the surfactant hydrocarbon chain and the number of the isopropylol groups in the head group. By applying the DLS technique, it was explored that how the number of isopropylol groups in gemini cationic surfactants with C12H25 chain affects the sizes of micelles at concentrations greater than CMC. It was discovered that the obtained gemini cationic surfactants have a biocidal character. 相似文献
2.
Ziyafaddin H. Asadov Ravan A. Rahimov Gulnara A. Ahmadova Khuraman A. Mammadova 《Journal of surfactants and detergents》2012,15(6):721-727
Reactions of octanol, nonanol, decanol, and dodecanol with epichlorohydrin were carried out in the presence of sodium hydroxide as a catalyst. The synthesized non-ionic surfactants were modified with triethanolamine. Surface activity at the water-air interface and electrical conductivity of the resulting surfactants at 10, 20, 30 and 40?°C were determined and thermodynamic parameters of micellization and adsorption were calculated. It was established that the synthesized quaternary ammonium salts have the ability to localize thin crude oil films on the water surface formed due to spill. 相似文献
3.
Ziyafaddin H. Asadov Ravan A. Rahimov Khuraman A. Mammadova Atash V. Gurbanov Gulnara A. Ahmadova 《Journal of surfactants and detergents》2016,19(1):145-153
Dodecyl isopropylolamine has been synthesized on the basis of dodecylamine and propylene oxide. The structure of dodecyl isopropanolamine has been determined by X‐ray diffraction, elemental analysis, IR‐ and NMR‐spectroscopic methods. Ionic surfactants have been synthesized by interaction of dodecyl isopropylolamine with various acids (HCl, HBr, acetic and propionic) and alkyl halides (methyl iodide, ethyl bromide and n‐propyl bromide). Colloidal‐chemical parameters, petroleum‐collecting and petroleum dispersing capacities of the synthesized cationic surfactants have been studied. 相似文献
4.
Guseynov R. R. Tanriverdiyev V. A. Belenky G. L. Kipshidze G. Aliyeva Y. N. Aliguliyeva Kh. V. Alizade E. G. Ahmadova Kh. N. Abdullayev N. A. Mamedov N. T. Zverev V. N. 《Semiconductors》2019,53(7):906-910
Semiconductors - The electrical and galvanomagnetic properties of unrelaxed heteroepitaxial InAs1 –xSbx structures (x = 0.43 and 0.38) in a wide temperature range of 5–300 K and... 相似文献
5.
Synthesis and Properties of Quaternary Ammonium Surfactants Based on Alkylamine,Propylene Oxide,and 2‐Chloroethanol 下载免费PDF全文
Ziyafaddin H. Asadov Gulnara A. Ahmadova Ravan A. Rahimov Aygul Z. Abilova Sevda H. Zargarova Fedor I. Zubkov 《Journal of surfactants and detergents》2018,21(2):247-254
New quaternary ammonium salts are synthesized by octylamine, nonylamine, dodecylamine, and hexadecylamine reacting with propylene oxide at a mole ratio of 1:2, followed by reaction with 2‐chloroethanol. By tensiometric measurements of aqueous solutions, their surface activity has been determined. Using the results of these measurements and electroconductometric studies, important parameters such as critical micelle concentration (CMC), efficiency of surfactant adsorption, surface pressure at the CMC, changes of Gibbs free energies for micelle formation, and adsorption were estimated. By application of the Gibbs adsorption isotherm, indices such as maximum surface excess concentration and minimum surface area/molecule at the air–water interface were also calculated. Petroleum‐collecting properties of these surfactants were investigated. Among these quaternary ammonium surfactants, the surfactant based on dodecylamine, propylene oxide, and 2‐chloroethanol exhibits the highest petroleum‐collecting capacity. 相似文献
6.
Imen Hadji-Sfaxi Shady El-Ghaish Aynur Ahmadova Batjargal Batdorj Gwenaëlle Le Blay-Laliberté Georges Barbier Thomas Haertlé Jean-Marc Chobert 《Food Control》2011,22(12):2020-2027
Screening of lactic acid bacteria strains isolated from Mongolian yogurt (Tarag) led to the isolation of Enterococcus faecium PC4.1 with a bacteriocin-like activity against Listeria genus and fungi. The antimicrobial substances in cell free supernatant were sensitive to proteolytic enzymes, while neither acidic conditions nor high temperature affected their activities. These antimicrobial substances were active after storage at 4 °C, ?20 °C and ?80 °C for over one month. The mode of action was determined as bactericidal. In the aim of further use of E. faecium PC4.1 as a biopreservative, the isolate was tested for resistance against antibiotics and for harboring virulence determinants. E. faecium PC4.1 was characterized as free from virulence factors, has low resistance to gentamicin and ampicillin but is susceptible to vancomycin. 相似文献
7.
Aynur?Ahmadova Svetoslav?Dimov Iskra?Ivanova Yvan?Choiset Jean-Marc?Chobert Akif?Kuliev Thomas?HaertléEmail author 《European Food Research and Technology》2011,233(1):131-140
A collection of 147 isolates obtained from 23 samples of traditional Azerbaijani dairy products was screened for the presence
of proteolytic enzymes. Six Enterococcus faecalis strains obtained from three cheese samples have been identified as proteinase-producing strains, according to their ability
to hydrolyze caseins. RAPD–PCR profiles of their total DNA showed different patterns for strains isolated from different cheese
samples. The proteolytic activities of these strains were studied during their growth in milk and in non-proliferative cells
system. Isolated strains were able to hydrolyze αS1-, αS2-, β-caseins and BLG albeit to different extents, at optimal pH in the range 6.0–7.2 and optimal temperature in the range
37–45 °C, depending on the strain. Proteolysis was strongly inhibited in the presence of EDTA—specific inhibitor of metalloproteases—but
the presence of other types of proteases cannot be excluded. The potential pathogenicity of the strains was evaluated investigating
the presence of the genes coding different virulence factors and their resistance to antibiotics. The obtained results yield
new information about technological characteristics and safety of studied Enterococci strains from Azerbaijani artisanal dairy products. Many from the isolated strains contribute certainly to the differences
in flavor, texture, and taste of Azerbaijani traditional cheeses and could represent new adjunct cultures for the dairy industry. 相似文献
8.
Ziyafaddin H. Asadov Gulnara A. Ahmadova Saida M. Huseynova Akif D. Guliyev Bekir M. Aliyev 《Chemical Engineering Communications》2019,206(7):861-870
New cocogem surfactants were synthesized by interaction of dodecylisopropylol amine with dicarboxylic (oxalic, succinic, adipic, sebacic, tartaric, maleic, fumaric, isophthalic) acids. By tensiometric method, the surface activity of aqueous solutions of the synthesized cocogem surfactants at the border with air was studied and, by conductometric method, the specific electrical conductivity of these solutions was determined. The degree of counterion binding (β), critical micelle concentration (CMC), effectiveness of surface tension reduction (πCMC), surface excess concentration (Γmax), area per molecule at the interface (Amin), changes of Gibbs free energies of adsorption (ΔGad) and micellization (ΔGmic) have been calculated. The character of change of the colloidal-chemical indices depending on spacer-group nature and length has been clarified. So, with an elongation of the spacer group and when passing from cis-form to trans-form, the value of CMC decreases. The obtained cocogem surfactants exhibit a considerable bactericidal effectiveness against sulfate-reducing bacteria. The bactericide properties of the cocogem surfactants containing in the spacer chain a saturated hydrocarbon fragment and benzene ring are stronger than for the others. 相似文献
9.
Ziyafaddin H. Asadov Ravan A. Rahimov Shafiga M. Nasibova Gulnara A. Ahmadova 《Journal of surfactants and detergents》2010,13(4):459-464
The surface-active properties of ionic-liquid type salts synthesized by the interaction of ethanolamines and decyl bromide
have been studied. Surface tension as a function of concentration of the surfactant in aqueous solution was measured at 10,
20, 30 and 40 °C using a drop volume stalagmometer. From these measurements, the maximum surface excess concentration and
the minimum area per molecule at the aqueous solution/air interface, the critical micelle concentration (CMC), the surface
pressure at the CMC, and the standard thermodynamic parameters of adsorption and micellization were calculated. The structural
effects on adsorption, micellization, and the effectiveness of surface tension reduction are discussed in terms of these parameters. 相似文献
10.
Imen Hadji Sfaxi Shady El-Ghaish Aynur Ahmadova Hanitra Rabesona Thomas Haertlé Jean-Marc Chobert 《European Food Research and Technology》2012,235(3):447-455
The proteolytic activity of thirty-three LAB isolates from Mongolian tarag was tested on skimmed milk. The strain displaying the highest proteolytic activity was purified and presented by 16S rDNA sequencing 99.9?% homology with Lactobacillus paracasei 1-4-2A. It was named L. paracasei I-N-10. Proteases of L. paracasei I-N-10 hydrolyze predominately ??-casein and in some level ??S2-casein; hydrolysis of ??S1-casein was not observed. Proteolytic activity was optimal at 42?°C and neutral pH. Proteases of L. paracasei I-N-10 were inhibited by serine- and metalloproteases inhibitors. PCR amplification revealed the presence of prtP gene, which was identical to prtP gene of L. paracasei genus. Mass spectrometry analysis of ??-casein hydrolysate allowed to characterize 7 peptides resulting from proteolysis by L. paracasei I-N-10. The isolated strain was able to cleave ??-casein in different sites including 2 of the major linear epitopes implicated in its allergenicity. Being sensitive to main antibiotics classes, L. paracasei I-N-10 could be considered as safe and used as starter culture with a potential role in decreasing ??-casein immuno-reactivity. 相似文献